Yaxuan Wang, Junzhan Zhang, Jianying Gao, Zhaopeng Yang
{"title":"不同添加剂对烧结莫来石液相和微观结构的改变","authors":"Yaxuan Wang, Junzhan Zhang, Jianying Gao, Zhaopeng Yang","doi":"10.1111/ijac.14860","DOIUrl":null,"url":null,"abstract":"In the field of ceramics, mullite has drawn plenty of attention due to its low thermal expansion and thermal conductivity as well as its high chemical stability and creep resistance. This work reported the mineral phase, liquid phase, and microstructure evolution of the sintered mullite, using coal‐series kaolin as the raw material and potash feldspar as well as phosphorus pentoxide as additives. The effects of K<jats:sub>2</jats:sub>O and P<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub> on the content and viscosity of the liquid phase in mullite were calculated using FactSage 8.1. The results showed that the introduction of K<jats:sub>2</jats:sub>O could inhibit the formation of cristobalite effectively. Adding K<jats:sub>2</jats:sub>O and P<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub> improved the content of the liquid phase formed during the calcination process. After introducing K<jats:sub>2</jats:sub>O and P<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub>, mullite developed acicular and columnar structures, with average lengths of 9.76 and 7.97 µm, respectively. Furthermore, introducing K<jats:sub>2</jats:sub>O and P<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub> improved the physical properties of mullite significantly.","PeriodicalId":13903,"journal":{"name":"International Journal of Applied Ceramic Technology","volume":"33 1","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Modification of liquid phase and microstructure of sintered mullite by different additives\",\"authors\":\"Yaxuan Wang, Junzhan Zhang, Jianying Gao, Zhaopeng Yang\",\"doi\":\"10.1111/ijac.14860\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In the field of ceramics, mullite has drawn plenty of attention due to its low thermal expansion and thermal conductivity as well as its high chemical stability and creep resistance. This work reported the mineral phase, liquid phase, and microstructure evolution of the sintered mullite, using coal‐series kaolin as the raw material and potash feldspar as well as phosphorus pentoxide as additives. The effects of K<jats:sub>2</jats:sub>O and P<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub> on the content and viscosity of the liquid phase in mullite were calculated using FactSage 8.1. The results showed that the introduction of K<jats:sub>2</jats:sub>O could inhibit the formation of cristobalite effectively. Adding K<jats:sub>2</jats:sub>O and P<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub> improved the content of the liquid phase formed during the calcination process. After introducing K<jats:sub>2</jats:sub>O and P<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub>, mullite developed acicular and columnar structures, with average lengths of 9.76 and 7.97 µm, respectively. Furthermore, introducing K<jats:sub>2</jats:sub>O and P<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub> improved the physical properties of mullite significantly.\",\"PeriodicalId\":13903,\"journal\":{\"name\":\"International Journal of Applied Ceramic Technology\",\"volume\":\"33 1\",\"pages\":\"\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-07-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Applied Ceramic Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1111/ijac.14860\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Applied Ceramic Technology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1111/ijac.14860","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Modification of liquid phase and microstructure of sintered mullite by different additives
In the field of ceramics, mullite has drawn plenty of attention due to its low thermal expansion and thermal conductivity as well as its high chemical stability and creep resistance. This work reported the mineral phase, liquid phase, and microstructure evolution of the sintered mullite, using coal‐series kaolin as the raw material and potash feldspar as well as phosphorus pentoxide as additives. The effects of K2O and P2O5 on the content and viscosity of the liquid phase in mullite were calculated using FactSage 8.1. The results showed that the introduction of K2O could inhibit the formation of cristobalite effectively. Adding K2O and P2O5 improved the content of the liquid phase formed during the calcination process. After introducing K2O and P2O5, mullite developed acicular and columnar structures, with average lengths of 9.76 and 7.97 µm, respectively. Furthermore, introducing K2O and P2O5 improved the physical properties of mullite significantly.
期刊介绍:
The International Journal of Applied Ceramic Technology publishes cutting edge applied research and development work focused on commercialization of engineered ceramics, products and processes. The publication also explores the barriers to commercialization, design and testing, environmental health issues, international standardization activities, databases, and cost models. Designed to get high quality information to end-users quickly, the peer process is led by an editorial board of experts from industry, government, and universities. Each issue focuses on a high-interest, high-impact topic plus includes a range of papers detailing applications of ceramics. Papers on all aspects of applied ceramics are welcome including those in the following areas:
Nanotechnology applications;
Ceramic Armor;
Ceramic and Technology for Energy Applications (e.g., Fuel Cells, Batteries, Solar, Thermoelectric, and HT Superconductors);
Ceramic Matrix Composites;
Functional Materials;
Thermal and Environmental Barrier Coatings;
Bioceramic Applications;
Green Manufacturing;
Ceramic Processing;
Glass Technology;
Fiber optics;
Ceramics in Environmental Applications;
Ceramics in Electronic, Photonic and Magnetic Applications;