Miriam M. Nicolás‐Marín, Jesús Roberto González‐Castillo, Maykel Courel‐Piedrahita, Inés Riech‐Méndez, Pedro Antonio Mijangos‐Alonzo, Osvaldo Vigil‐Galán
{"title":"用于高效太阳能电池的 Sby(S1-x,Sex)3 三元吸收器的最佳成分","authors":"Miriam M. Nicolás‐Marín, Jesús Roberto González‐Castillo, Maykel Courel‐Piedrahita, Inés Riech‐Méndez, Pedro Antonio Mijangos‐Alonzo, Osvaldo Vigil‐Galán","doi":"10.1002/pssa.202400288","DOIUrl":null,"url":null,"abstract":"Solar cells based on Sb<jats:sub>2</jats:sub>(S<jats:sub>1−<jats:italic>x</jats:italic></jats:sub>,Se<jats:sub><jats:italic>x</jats:italic></jats:sub>)<jats:sub>3</jats:sub> ternary compounds have shown the highest reported efficiency value compared to their Sb<jats:sub>2</jats:sub>Se<jats:sub>3</jats:sub> and Sb<jats:sub>2</jats:sub>S<jats:sub>3</jats:sub> counterparts in antimony chalcogenide technology. However, the reported record efficiencies for these new emergent solar cells are still well below the theoretical values according to their bandgap value or for the traditional solar cells in the thin film technology. This article presents an analysis regarding the optimal composition that guarantees an increase in efficiency in the manufacture of Sb<jats:sub><jats:italic>y</jats:italic></jats:sub>(S<jats:sub>1−<jats:italic>x</jats:italic></jats:sub>,Se<jats:sub><jats:italic>x</jats:italic></jats:sub>)<jats:sub>3</jats:sub> solar cells, as well as the proposal of a new synthesis method that allows obtaining the ternary compound with the calculated optimal composition. From theoretical considerations, a composition of Sb<jats:sub>1.85</jats:sub>(S<jats:sub>0.63</jats:sub>,Se<jats:sub>0.42</jats:sub>)<jats:sub>3</jats:sub> is obtained. This composition is equivalent to optimal values Se/(S + Se) = 0.4 and Sb/(S + Se) = 0.88. The results of the new proposed synthesis method are presented and discussed.","PeriodicalId":20074,"journal":{"name":"Physica Status Solidi A-applications and Materials Science","volume":"85 1","pages":""},"PeriodicalIF":1.9000,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Optimal Composition of the Sby(S1−x,Sex)3 Ternary Absorber for High Efficiency Solar Cells\",\"authors\":\"Miriam M. Nicolás‐Marín, Jesús Roberto González‐Castillo, Maykel Courel‐Piedrahita, Inés Riech‐Méndez, Pedro Antonio Mijangos‐Alonzo, Osvaldo Vigil‐Galán\",\"doi\":\"10.1002/pssa.202400288\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Solar cells based on Sb<jats:sub>2</jats:sub>(S<jats:sub>1−<jats:italic>x</jats:italic></jats:sub>,Se<jats:sub><jats:italic>x</jats:italic></jats:sub>)<jats:sub>3</jats:sub> ternary compounds have shown the highest reported efficiency value compared to their Sb<jats:sub>2</jats:sub>Se<jats:sub>3</jats:sub> and Sb<jats:sub>2</jats:sub>S<jats:sub>3</jats:sub> counterparts in antimony chalcogenide technology. However, the reported record efficiencies for these new emergent solar cells are still well below the theoretical values according to their bandgap value or for the traditional solar cells in the thin film technology. This article presents an analysis regarding the optimal composition that guarantees an increase in efficiency in the manufacture of Sb<jats:sub><jats:italic>y</jats:italic></jats:sub>(S<jats:sub>1−<jats:italic>x</jats:italic></jats:sub>,Se<jats:sub><jats:italic>x</jats:italic></jats:sub>)<jats:sub>3</jats:sub> solar cells, as well as the proposal of a new synthesis method that allows obtaining the ternary compound with the calculated optimal composition. From theoretical considerations, a composition of Sb<jats:sub>1.85</jats:sub>(S<jats:sub>0.63</jats:sub>,Se<jats:sub>0.42</jats:sub>)<jats:sub>3</jats:sub> is obtained. This composition is equivalent to optimal values Se/(S + Se) = 0.4 and Sb/(S + Se) = 0.88. The results of the new proposed synthesis method are presented and discussed.\",\"PeriodicalId\":20074,\"journal\":{\"name\":\"Physica Status Solidi A-applications and Materials Science\",\"volume\":\"85 1\",\"pages\":\"\"},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2024-07-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physica Status Solidi A-applications and Materials Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/pssa.202400288\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physica Status Solidi A-applications and Materials Science","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/pssa.202400288","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Optimal Composition of the Sby(S1−x,Sex)3 Ternary Absorber for High Efficiency Solar Cells
Solar cells based on Sb2(S1−x,Sex)3 ternary compounds have shown the highest reported efficiency value compared to their Sb2Se3 and Sb2S3 counterparts in antimony chalcogenide technology. However, the reported record efficiencies for these new emergent solar cells are still well below the theoretical values according to their bandgap value or for the traditional solar cells in the thin film technology. This article presents an analysis regarding the optimal composition that guarantees an increase in efficiency in the manufacture of Sby(S1−x,Sex)3 solar cells, as well as the proposal of a new synthesis method that allows obtaining the ternary compound with the calculated optimal composition. From theoretical considerations, a composition of Sb1.85(S0.63,Se0.42)3 is obtained. This composition is equivalent to optimal values Se/(S + Se) = 0.4 and Sb/(S + Se) = 0.88. The results of the new proposed synthesis method are presented and discussed.
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The physica status solidi (pss) journal group is devoted to the thorough peer review and the rapid publication of new and important results in all fields of solid state and materials physics, from basic science to applications and devices. Among the largest and most established international publications, the pss journals publish reviews, letters and original articles, as regular content as well as in special issues and topical sections.
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