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Performance Enhancement of SnS Solar Cell with Tungsten Disulfide Electron Transport Layer and Molybdenum Trioxide Hole Transport Layer 利用二硫化钨电子传输层和三氧化钼空穴传输层提高 SnS 太阳能电池的性能
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-17 DOI: 10.1002/pssa.202400547
Ayasha Siddeka, Tanvir Mahtab Khan, Md. Raton Ali, Adnan Hosen, Md. Ferdous Rahman, Sheikh Rashel Al Ahmed
Herein, a new heterojunction photovoltaic (PV) device is designed by incorporating molybdenum trioxide (MoO3) as a hole transport layer (HTL), tin sulfide (SnS) as an absorber, and tungsten disulfide (WS2) as an electron transport layer (ETL). The PV outputs of the proposed thin‐film solar cell (TFSC) of Ni/MoO3/SnS/WS2/FTO/Al are investigated using the widely used solar cell simulator (SCAPS‐1D). It is found that the SnS TFSC with suitable band alignments at both the SnS/WS2 and MoO3/SnS interfaces gives better photoconversion efficiency than the conventional one. To optimize the material properties, the performance parameters, including open‐circuit voltage (Voc), short‐circuit current density (Jsc), fill factor (FF), and efficiency, have been calculated by varying the influences of the material's thickness, doping concentration, bulk and interface defect densities, operational temperature, and work function of back‐contact. At optimized thicknesses of 0.1 μm for MoO3 HTL and 1.0 μm for SnS absorber, the efficiency is estimated to be 30.42% with Voc of 1.02 V, Jsc of 34.38 mA cm−2, and FF of 87.04% for the suggested TFSC. These outcomes imply that the nontoxic MoO3 and WS2 materials can be applied as HTL and ETL into the inexpensive, highly efficient, and environmentally friendly SnS‐based PV cell.
本文设计了一种新型异质结光伏(PV)器件,将三氧化钼(MoO3)作为空穴传输层(HTL),硫化锡(SnS)作为吸收层,二硫化钨(WS2)作为电子传输层(ETL)。利用广泛使用的太阳能电池模拟器(SCAPS-1D)研究了所提出的 Ni/MoO3/SnS/WS2/FTO/Al 薄膜太阳能电池(TFSC)的光伏输出。研究发现,SnS TFSC 在 SnS/WS2 和 MoO3/SnS 界面均具有合适的带排列,其光电转换效率优于传统的 TFSC。为了优化材料特性,我们通过改变材料厚度、掺杂浓度、块状和界面缺陷密度、工作温度和背触点功函数等影响因素,计算了开路电压(Voc)、短路电流密度(Jsc)、填充因子(FF)和效率等性能参数。当 MoO3 HTL 的优化厚度为 0.1 μm 和 SnS 吸收体的优化厚度为 1.0 μm 时,所建议的 TFSC 的效率估计为 30.42%,Voc 为 1.02 V,Jsc 为 34.38 mA cm-2,FF 为 87.04%。这些结果表明,无毒的 MoO3 和 WS2 材料可作为 HTL 和 ETL 应用于廉价、高效和环保的 SnS 基光伏电池。
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引用次数: 0
Plasma‐Assisted Preparation and Properties of Chitosan‐Based Magnetic Hydrogels 等离子体辅助制备壳聚糖磁性水凝胶及其特性
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-17 DOI: 10.1002/pssa.202400218
Running Liang, Cheng Yang, Weiwei Zhang, Dan Zhang, Lusi A, Wenzhuo Hu, Qinxiu Gao, Shaohuang Bian, Haoyu Qi, Junwei Guo, Wenping Lu, Feng Huang
Chitosan‐based magnetic hydrogel has become a research hotspot in the field of material science due to the driven deformation or movement under the action of magnetic field. The unique properties make it show great application potential in medicine, biosensing, environmental protection, and other fields. Herein, the chitosan‐based nanomagnetic composite hydrogels are prepared by plasma assistance. The surface morphology, infrared spectra, mechanical properties, swelling ratio, water absorption, porosity, and degradation of the prepared hydrogels are investigated. The results prove the superiority of plasma‐assisted preparation of magnetic chitosan hydrogels and provide a new method for the design of smart hydrogels.
壳聚糖磁性水凝胶在磁场作用下会发生形变或运动,因而成为材料科学领域的研究热点。其独特的性能使其在医学、生物传感、环境保护等领域具有巨大的应用潜力。本文通过等离子体辅助制备了壳聚糖基纳米磁性复合水凝胶。研究了所制备水凝胶的表面形貌、红外光谱、力学性能、溶胀率、吸水性、孔隙率和降解情况。结果证明了等离子体辅助制备磁性壳聚糖水凝胶的优越性,并为设计智能水凝胶提供了一种新方法。
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引用次数: 0
Advancements in Piezoelectric‐Enabled Devices for Optical Communication 用于光通信的压电器件的进展
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-12 DOI: 10.1002/pssa.202400298
Agata Roszkiewicz, Magdalena Garlińska, Agnieszka Pregowska
The ability of piezoelectric materials to convert mechanical energy into electric energy and vice versa has made them desirable in the wide range of applications that oscillate from medicine to the energetics industry. Their implementation in optical communication is often connected with the modulation or other manipulations of the light signals. In this article, the recent advancements in the field of piezoelectrics‐based devices and their promising benefits in optical communication are explored. The application of piezoelectrics‐based devices in optical communication allows dynamic control, modulation, and manipulation of optical signals that lead to a more reliable transmission. It turns out that a combination of artificial‐intelligence‐based algorithms with piezoelectrics can enhance the performance of these devices, including optimization of piezoelectric modulation, adaptive signal processing, control of optical components, and increase the level of energy efficiency. It can enhance signal quality, mitigate interference, and reduce noise‐connected issues. Moreover, this technological fusion can increase the security of optical communication systems. Finally, the potential future research lines are determined.
压电材料能够将机械能转化为电能,反之亦然,这使得它们在从医药到能源工业的广泛应用中备受青睐。压电材料在光通信中的应用通常与光信号的调制或其他操作有关。本文将探讨压电器件领域的最新进展及其在光通信中的应用前景。在光通信中应用压电器件可以对光信号进行动态控制、调制和操纵,从而实现更可靠的传输。事实证明,将基于人工智能的算法与压电技术相结合,可以提高这些设备的性能,包括优化压电调制、自适应信号处理、控制光学元件,以及提高能效水平。它可以提高信号质量,减轻干扰,减少与噪声有关的问题。此外,这种技术融合还能提高光通信系统的安全性。最后,确定了未来可能的研究方向。
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引用次数: 0
Annealing Time Dependence on Creation of SiV, GeV, and SnV in Diamond by Atmospheric Annealing at 1800 °C 1800 °C 大气退火对金刚石中 SiV、GeV 和 SnV 生成的退火时间依赖性
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1002/pssa.202400303
Tomoya Baba, Masatomi Iizawa, Kouta Takenaka, Kosuke Kimura, Airi Kawasaki, Takashi Taniguchi, Masashi Miyakawa, Hiroyuki Okazaki, Osamu Hanaizumi, Shinobu Onoda
The creation of SiV, GeV, and SnV are presented by the atmospheric annealing in the argon flow. Compared to high‐pressure annealing, in which gas cannot flow, atmospheric annealing with an inert gas flow not only causes less degradation of the sample surface but also has the advantage of reducing equipment cost and preparation time. Excessive annealing time has been shown to reduce the amount of centers created. The optimal annealing time that maximizes formations depends on the type of diamond sample and the implanted ions. Furthermore, inspired by the split‐vacancy structure of the group IV–V centers, atmospheric pre‐annealing at 600 °C to increase the amount of di‐vacancy is demonstrated, followed by annealing at 1800 °C for 1 min. A shorter duration of high‐temperature annealing is expected to qualitatively reduce stress and deterioration of the crystallinity of the diamond sample.
在氩气流中进行的大气退火可产生 SiV-、GeV- 和 SnV-。与气体无法流动的高压退火相比,惰性气体流动的大气退火不仅能减少样品表面的退化,还具有降低设备成本和减少制备时间的优势。事实证明,过长的退火时间会减少中心的生成量。能最大限度形成中心的最佳退火时间取决于金刚石样品的类型和植入的离子。此外,受 IV-V 族中心分裂空位结构的启发,在 600 °C 下进行大气预退火以增加二空位的数量,然后在 1800 °C 下退火 1 分钟。较短的高温退火时间有望从质量上减少金刚石样品的应力和结晶度劣化。
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引用次数: 0
Structural Distortions and Short‐Range Magnetism in a Honeycomb Iridate Cu3ZnIr2O6 蜂窝状铱酸盐 Cu3ZnIr2O6 中的结构畸变和短程磁性
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1002/pssa.202400426
Mykola Abramchuk, Ihor Z. Hlova, Yaroslav Mudryk, Anis Biswas, Rajiv K. Chouhan, Vitalij K. Pecharsky
Layered honeycomb iridates receive significant attention in the materials chemistry and physics fields due to the relevance of their crystal structures to the Kitaev model of a quantum spin liquid (QSL). In quest of liquid‐like magnetic ground state signatures, first‐generation alkali metal iridates A2IrO3 ≡ A3[AIr2]O6 (A = Li, Na) and second‐generation iridates T3[AIr2]O6 (T = Cu, Ag, H) are developed. T3[AIr2]O6 is synthesized from A3[AIr2]O6 via metathesis reactions replacing alkali ions located between honeycomb layers. Herein, the next level of chemical and structural complexity is introduced by synthesizing the honeycomb iridate, Cu3ZnIr2O6, in which alkali ions between and within the honeycomb layers are both selectively exchanged with two different transition metals. Analysis of powder X‐Ray diffraction data reveals corrugation of the honeycomb layers in Cu3ZnIr2O6 that hinders complete magnetic frustration and results in a spin glass behavior observed from magnetization and specific heat data. Thus, Cu3ZnIr2O6 represents yet another model, which broadens understanding of intricate relationships between intralayer distortions and magnetism of prospective Kitaev QSL compounds.
层状蜂窝状铱酸盐因其晶体结构与量子自旋液体(QSL)的基塔耶夫模型相关而受到材料化学和物理学领域的极大关注。为了寻找类似液体的磁基态特征,我们开发了第一代碱金属铱酸盐 A2IrO3 ≡ A3[AIr2]O6 (A = Li、Na)和第二代铱酸盐 T3[AIr2]O6 (T = Cu、Ag、H)。T3[AIr2]O6 由 A3[AIr2]O6 通过偏析反应合成,取代了位于蜂窝层之间的碱离子。通过合成蜂窝状铱化物 Cu3ZnIr2O6,蜂窝层之间和内部的碱离子被两种不同的过渡金属选择性地交换,从而将化学和结构的复杂性提高到了一个新的水平。对粉末 X 射线衍射数据的分析表明,Cu3ZnIr2O6 中蜂窝层的波纹阻碍了磁性的完全衰减,并导致了从磁化和比热数据中观察到的自旋玻璃行为。因此,Cu3ZnIr2O6 代表了另一种模型,它拓宽了人们对未来 Kitaev QSL 化合物层内畸变与磁性之间错综复杂关系的理解。
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引用次数: 0
The Impact of Bromine Surface Doping on the Structural, Optical, and Morphological Properties of Bismuth‐Based Perovskite Film as a Light‐Absorber in Perovskite Solar Cells 溴表面掺杂对作为包晶石太阳能电池光吸收剂的铋基包晶石薄膜的结构、光学和形态学特性的影响
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1002/pssa.202400512
Hojjat Amrollahi Bioki, Enayatullah Erfani, Mohammad Ismail Ihsas
Bismuth‐based perovskite materials have concerned significant attention due to their low‐toxic and stable properties. However, achieving smooth and dense thin films for the preferential growth of bismuth‐based perovskite along the c‐axis, which is conducive to the preparation of solar cells, is challenging. Therefore, using halogen atoms to partially replace iodine atoms and constrain anisotropic growth has been shown to be an effective method for obtaining high‐quality perovskite films. Herein, Br doping with varying concentrations is used to treat bismuth‐based perovskite films with larger and denser grains compared to those without doping. When a small amount of Br ions is doped, the surface of the perovskite layer becomes more uniform, significantly improving the compactness of the perovskite film. Additionally, proper Br doping can reduce internal defects in the films, effectively inhibiting nonradiative recombination, enhancing light absorption, and increasing carrier lifetime. The optimal power conversion efficiency of Br‐doped bismuth halide perovskite solar cells is found to be 0.136%, compared to 0.087% for pristine devices.
铋基包晶石材料因其低毒、稳定的特性而备受关注。然而,要使铋基包晶石沿 c 轴优先生长并形成光滑致密的薄膜,从而有利于太阳能电池的制备,却是一项挑战。因此,使用卤素原子部分取代碘原子并限制各向异性生长已被证明是获得高质量透辉石薄膜的有效方法。在此,我们使用不同浓度的掺杂溴来处理铋基包晶石薄膜,与未掺杂的薄膜相比,铋基包晶石薄膜的晶粒更大、更致密。当掺入少量 Br 离子时,包晶石层的表面会变得更加均匀,从而显著提高包晶石薄膜的致密性。此外,适当的 Br 掺杂可以减少薄膜的内部缺陷,有效抑制非辐射重组,增强光吸收,延长载流子寿命。研究发现,掺杂 Br 的卤化铋包晶太阳能电池的最佳功率转换效率为 0.136%,而原始器件的最佳功率转换效率为 0.087%。
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引用次数: 0
Enhancing Reliability and Regeneration of Single Passivated Emitter Rear Contact Solar Cell Modules through Alternating Current Power Application to Mitigate Light and Elevated Temperature‐Induced Degradation 通过交流电应用提高单钝化发射极后触点太阳能电池组件的可靠性和再生能力,缓解光照和高温引起的退化
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1002/pssa.202400453
Jaljalalul Abedin Jony, Hasnain Yousuf, Muhammad Aleem Zahid, Muhammad Quddamah Khokhar, Polgampola Chamani Madara, Rafi Ur Rahman, Youngkuk Kim, Maha Nur Aida, Simpy Sanyal, Sangheon Park, Suresh Kumar Dhungel, Junsin Yi
The study explores a novel method to combat the Light and Elevated Temperature‐Induced Degradation (LeTID) in solar cell modules, which significantly reduces their efficiency and lifespan. This method involves applying alternating current (AC) of various waveforms (triangular, sinusoidal, and square) and frequencies (5 and 100 kHz) to boron‐doped p‐type passivated emitter rear contact (p‐PERC) solar cell modules. This approach effectively lowers the series resistance at the critical junction between the silver (Ag) contact and the silicon emitter layer of the PERC solar cell, thereby reducing charge recombination hindered by high resistance, especially at elevated temperatures. As a result, there is an improved flow of electrical charges, leading to decreased energy loss and increased solar cell efficiency. The study's findings indicate that a slow, smooth sinusoidal AC waveform at 100 kHz is particularly effective, restoring about 100% of the original performance of the panel. Moreover, oscillations at 5 kHz also show considerable efficacy, recovering more than 96% of the performance. The sinusoidal waveform is noted to surpass both triangular and square waveforms in recovery efficiency. This research highlights the use of high‐frequency AC electricity as a viable strategy to extend the lifespan and enhance the performance of solar panels.
太阳能电池组件的光照和高温诱导衰减(LeTID)会显著降低其效率和寿命,本研究探索了一种新型方法来解决这一问题。这种方法是在掺硼 p 型钝化发射极后触点(p-PERC)太阳能电池组件上施加不同波形(三角波、正弦波和方波)和频率(5 kHz 和 100 kHz)的交流电。这种方法有效降低了 PERC 太阳能电池银(Ag)触点和硅发射极层之间临界结的串联电阻,从而减少了因高电阻而阻碍的电荷重组,尤其是在高温条件下。因此,电荷流动得到改善,从而减少了能量损失,提高了太阳能电池的效率。研究结果表明,100 千赫的缓慢、平滑的正弦交流波形特别有效,能使电池板的性能恢复到原来的 100%。此外,5 千赫的振荡也显示出相当大的功效,可恢复 96% 以上的性能。正弦波在恢复效率方面超过了三角波和方波。这项研究强调,使用高频交流电是延长太阳能电池板寿命和提高其性能的可行策略。
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引用次数: 0
Control of Skyrmions in Confined Devices for Multistate Memory Application 控制密闭器件中的 Skyrmions 以实现多态存储器应用
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-05 DOI: 10.1002/pssa.202400489
Warda Al Saidi, Rachid Sbiaa, Suleiman Al Risi, Fatma Al Shanfari, Yannick Dusch, Nicolas Tiercelin
The dynamics and stability of magnetic skyrmions within a nano‐track with multiple confinements are investigated. The motion of a single skyrmion under a polarized electric current is studied. By adjusting the current magnitude and pulse width, the study reveals the possibility of pinning the skyrmion in each confinement. The depinning of the skyrmion from the top confinement requires two pulses with adjustable time delay while a single pulse is enough to depin it for the case of bottom confinement. The study is extended to two skyrmions and it is found that once a skyrmion is pinned in one confinement, the second one stabilizes in the nearest available empty state. The results show that a multistate device could be obtained with the existence of only one skyrmion per state. This scheme offers an accurate way of controlling the resistance of the devices and thus could be used for multistate memory devices.
研究了具有多重约束的纳米轨道内磁性天幕的动力学和稳定性。研究了在极化电流作用下单个星芒的运动。通过调整电流大小和脉冲宽度,研究揭示了在每个束缚中钉化天融子的可能性。从顶部禁锢中剥离天电离子需要两个时间延迟可调的脉冲,而在底部禁锢的情况下,一个脉冲就足以剥离天电离子。研究扩展到两个天离子,发现一旦一个天离子被固定在一个约束中,第二个天离子就会稳定在最近的空态。结果表明,在每个状态只存在一个skyrmion的情况下,可以获得多态装置。这种方案提供了控制器件电阻的精确方法,因此可用于多态存储器件。
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引用次数: 0
Combined Confocal‐Atomic‐Force Microscope Setup for Quantum Sensing Applications with Sub‐diffractional Spatial Resolution 用于量子传感应用的具有亚衍射空间分辨率的共焦-原子力显微镜组合装置
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-05 DOI: 10.1002/pssa.202400541
Sergei Tofimov, Boris Naydenov
Quantum sensors find applications ranging from material science to biophysics. Nitrogen‐vacancy (NV) center in diamond has been successfully implemented for measuring various types of signals. Optical NV center readout, routinely used in confocal microscopes, allows achieving high spatial resolution down to the diffraction limit. This work describes in detail the combined confocal‐atomic‐force microscope (confocal‐AFM), which takes advantage of sharp AFM cantilevers, and shows its possible applications for nanoscale resolution. It demonstrates the sub‐diffractional localization of NV centers with platinum‐coated cantilevers and the ability to separately address optically unresolved sensors using cantilevers with ferromagnetic coating. The presented setup exhibits a lateral resolution of 13 nm, providing a tool for nanoscale quantum sensing.
量子传感器的应用范围从材料科学到生物物理学。金刚石中的氮空位(NV)中心已成功用于测量各种类型的信号。在共聚焦显微镜中常规使用的光学 NV 中心读出可实现低至衍射极限的高空间分辨率。这项研究详细描述了共焦-原子力显微镜(confocal-AFM)组合,它利用了尖锐的原子力显微镜悬臂,并展示了其在纳米级分辨率方面的可能应用。它展示了利用铂涂层悬臂对 NV 中心的亚衍射定位,以及利用铁磁涂层悬臂单独处理光学未分辨传感器的能力。该装置的横向分辨率为 13 纳米,为纳米级量子传感提供了一种工具。
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引用次数: 0
Gold Nanoparticle‐Based Sensing of Pesticides and Fertilizers in Aqueous System: A Review 基于金纳米粒子的水体系农药和化肥传感:综述
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-04 DOI: 10.1002/pssa.202400439
Natasya Salsabiila, Marlia Morsin, Nur Liyana Razali, Suratun Nafisah, Farhanahani Mahmud, Chin Fhong Soon, Rahmat Sanudin, Radin Maya Saphira Radin Mohamed, Muhammad Hanif Hasbullah
The extensive use of pesticides and fertilizers in agriculture has led to significant environmental pollution, particularly in aqueous systems. This review provides an inclusive overview of the advancements in the application of gold nanoparticles (GNPs), specifically for the sensing of pesticides and fertilizers on surface water. The novelty of this work lies in its focused analysis of the unique localized surface plasmon resonance properties of GNPs that enable highly sensitive and selective detection of contaminants on surface water. Various synthesis methods and detection mechanisms are discussed, emphasizing the integration of GNP‐based sensors with modern analytical techniques to enhance detection limits and response time. The review also highlights the significance of monitoring agricultural chemicals in water systems from an environmental perspective. In addition, this review also reveals the potential of GNPs contribution toward sustainable agricultural practices by providing reliable, rapid, and cost‐effective sensing solutions. Future perspectives on the development of GNP‐based sensors, including the fundamental challenges in designing GNP sensors, such as incorporation with other materials, miniaturized and portable sensing devices, and field‐testing validation are also presented.
农药和化肥在农业中的广泛使用导致了严重的环境污染,尤其是在水系统中。本综述全面概述了金纳米粒子(GNPs)在地表水农药和化肥传感方面的应用进展。这项工作的新颖之处在于重点分析了金纳米粒子独特的局部表面等离子体共振特性,这种特性使其能够高灵敏度、高选择性地检测地表水中的污染物。文章讨论了各种合成方法和检测机制,强调将基于 GNP 的传感器与现代分析技术相结合,以提高检测极限和响应时间。综述还强调了从环境角度监测水系统中农业化学品的重要性。此外,本综述还揭示了 GNP 通过提供可靠、快速和具有成本效益的传感解决方案,为可持续农业实践做出贡献的潜力。本综述还介绍了基于 GNP 的传感器的未来发展前景,包括设计 GNP 传感器所面临的基本挑战,如与其他材料的结合、微型化和便携式传感设备以及现场测试验证。
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引用次数: 0
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