V Parthibaraj, R Vijayakumar, Ranjib Kumar Padhi, K Ramachandran, K Maheshvaran
{"title":"光电应用中掺杂 Dy3+ 离子的 NaBaB9O15 磷光体的发光特性研究","authors":"V Parthibaraj, R Vijayakumar, Ranjib Kumar Padhi, K Ramachandran, K Maheshvaran","doi":"10.1007/s10895-024-03870-y","DOIUrl":null,"url":null,"abstract":"<p><p>A series of Dy<sup>3+</sup> ions doped NaBaB<sub>9</sub>O<sub>15</sub> phosphors with different dopant concentration was synthesized by solid state reaction. The phase purity was checked by X-ray diffraction analysis and the functional groups present in as prepared phosphors was investigated with the help of FTIR spectral analysis. Under 386 nm excitation, the photoluminescence spectra exhibit three emission bands around 482 nm, 574 nm and 664 nm due to <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>J/2</sub> (J = 15, 13, 11) transions respectively. The optimum doping concentration of Dy<sup>3+</sup> ions was found to be 5 mol%. The color coordinates are estimated from the emission spectra to check the dominant emission color and the color coordinates of the studied phosphors are fall on white region of CIE 1931 diagram. The decay curve analysis was made to determine the lifetime of excited state of Dy<sup>3+</sup> ions and the decay curves are exhibited bi-exponential behavior irrespective of Dy<sup>3+</sup> ion concentration. All these measurents are done in room temperature and the results obtained from these studies are discussed in detail to claim their usage in light emitting devices.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":null,"pages":null},"PeriodicalIF":2.6000,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation on Luminescence Properties of Dy<sup>3+</sup> Ions Doped NaBaB<sub>9</sub>O<sub>15</sub> Phosphors for Optoelectronic Applications.\",\"authors\":\"V Parthibaraj, R Vijayakumar, Ranjib Kumar Padhi, K Ramachandran, K Maheshvaran\",\"doi\":\"10.1007/s10895-024-03870-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>A series of Dy<sup>3+</sup> ions doped NaBaB<sub>9</sub>O<sub>15</sub> phosphors with different dopant concentration was synthesized by solid state reaction. The phase purity was checked by X-ray diffraction analysis and the functional groups present in as prepared phosphors was investigated with the help of FTIR spectral analysis. Under 386 nm excitation, the photoluminescence spectra exhibit three emission bands around 482 nm, 574 nm and 664 nm due to <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>J/2</sub> (J = 15, 13, 11) transions respectively. The optimum doping concentration of Dy<sup>3+</sup> ions was found to be 5 mol%. The color coordinates are estimated from the emission spectra to check the dominant emission color and the color coordinates of the studied phosphors are fall on white region of CIE 1931 diagram. The decay curve analysis was made to determine the lifetime of excited state of Dy<sup>3+</sup> ions and the decay curves are exhibited bi-exponential behavior irrespective of Dy<sup>3+</sup> ion concentration. All these measurents are done in room temperature and the results obtained from these studies are discussed in detail to claim their usage in light emitting devices.</p>\",\"PeriodicalId\":15800,\"journal\":{\"name\":\"Journal of Fluorescence\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-07-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Fluorescence\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s10895-024-03870-y\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"BIOCHEMICAL RESEARCH METHODS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Fluorescence","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10895-024-03870-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"BIOCHEMICAL RESEARCH METHODS","Score":null,"Total":0}
Investigation on Luminescence Properties of Dy3+ Ions Doped NaBaB9O15 Phosphors for Optoelectronic Applications.
A series of Dy3+ ions doped NaBaB9O15 phosphors with different dopant concentration was synthesized by solid state reaction. The phase purity was checked by X-ray diffraction analysis and the functional groups present in as prepared phosphors was investigated with the help of FTIR spectral analysis. Under 386 nm excitation, the photoluminescence spectra exhibit three emission bands around 482 nm, 574 nm and 664 nm due to 4F9/2→6HJ/2 (J = 15, 13, 11) transions respectively. The optimum doping concentration of Dy3+ ions was found to be 5 mol%. The color coordinates are estimated from the emission spectra to check the dominant emission color and the color coordinates of the studied phosphors are fall on white region of CIE 1931 diagram. The decay curve analysis was made to determine the lifetime of excited state of Dy3+ ions and the decay curves are exhibited bi-exponential behavior irrespective of Dy3+ ion concentration. All these measurents are done in room temperature and the results obtained from these studies are discussed in detail to claim their usage in light emitting devices.
期刊介绍:
Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.