光电应用中掺杂 Dy3+ 离子的 NaBaB9O15 磷光体的发光特性研究

IF 2.6 4区 化学 Q2 BIOCHEMICAL RESEARCH METHODS Journal of Fluorescence Pub Date : 2024-07-24 DOI:10.1007/s10895-024-03870-y
V Parthibaraj, R Vijayakumar, Ranjib Kumar Padhi, K Ramachandran, K Maheshvaran
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引用次数: 0

摘要

通过固态反应合成了一系列掺杂不同浓度 Dy3+ 离子的 NaBaB9O15 荧光粉。通过 X 射线衍射分析检测了相纯度,并借助傅立叶变换红外光谱分析研究了所制备荧光粉中存在的官能团。在 386 nm 的激发下,光致发光光谱显示出 482 nm、574 nm 和 664 nm 附近的三个发射带,这分别是由于 4F9/2→6HJ/2 (J = 15、13、11)跃迁引起的。Dy3+ 离子的最佳掺杂浓度为 5 摩尔%。根据发射光谱估算色坐标,以检查主要的发射色,所研究的荧光粉的色坐标位于 CIE 1931 图的白色区域。衰减曲线分析是为了确定 Dy3+ 离子激发态的寿命,无论 Dy3+ 离子的浓度如何,衰减曲线都表现出双指数行为。所有这些测量都是在室温下进行的,并对这些研究得出的结果进行了详细讨论,以确定它们在发光器件中的应用。
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Investigation on Luminescence Properties of Dy3+ Ions Doped NaBaB9O15 Phosphors for Optoelectronic Applications.

A series of Dy3+ ions doped NaBaB9O15 phosphors with different dopant concentration was synthesized by solid state reaction. The phase purity was checked by X-ray diffraction analysis and the functional groups present in as prepared phosphors was investigated with the help of FTIR spectral analysis. Under 386 nm excitation, the photoluminescence spectra exhibit three emission bands around 482 nm, 574 nm and 664 nm due to 4F9/26HJ/2 (J = 15, 13, 11) transions respectively. The optimum doping concentration of Dy3+ ions was found to be 5 mol%. The color coordinates are estimated from the emission spectra to check the dominant emission color and the color coordinates of the studied phosphors are fall on white region of CIE 1931 diagram. The decay curve analysis was made to determine the lifetime of excited state of Dy3+ ions and the decay curves are exhibited bi-exponential behavior irrespective of Dy3+ ion concentration. All these measurents are done in room temperature and the results obtained from these studies are discussed in detail to claim their usage in light emitting devices.

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来源期刊
Journal of Fluorescence
Journal of Fluorescence 化学-分析化学
CiteScore
4.60
自引率
7.40%
发文量
203
审稿时长
5.4 months
期刊介绍: Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.
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