CdS 负载对 MoS2 纳米片特性和光催化活性的影响。

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY BMC Chemistry Pub Date : 2024-07-24 DOI:10.1186/s13065-024-01250-y
Ashmalina Rahman, Fazlurrahman Khan, James Robert Jennings, Ai Ling Tan, Young-Mog Kim, Mohammad Mansoob Khan
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引用次数: 0

摘要

成功合成了硫化钼(MoS2)和含有不同比例 CdS(10%、30% 和 50% CdS@MoS2)的改性 MoS2,并对其进行了表征。通过在可见光照射下降解艳绿(BG)、亚甲基蓝(MB)和罗丹明 B(RhB)染料,评估了 MoS2 和 CdS@MoS2 的光催化性能。在合成的光催化剂中,50% CdS@MoS2 的光催化活性最高,在 5 小时内分别降解了 97.6%、90.3% 和 75.5%的艳绿、亚甲基蓝和罗丹明 B 染料。所有捕集剂对 BG 和 MB 降解的抑制程度相似,表明所有探究的活性物种在 BG 和 MB 降解过程中都发挥了重要作用。相反,在光催化降解 RhB 的过程中,h+ 和 O2- 是主要的活性物种。提出了利用 CdS@MoS2 光催化降解染料的潜在机制。这项工作凸显了 CdS@MoS2 作为光催化剂在更高效的水修复应用中的潜力。
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Effect of CdS loading on the properties and photocatalytic activity of MoS2 nanosheets

Molybdenum sulfide (MoS2) and modified MoS2 with different percentages of CdS (10%, 30%, and 50% CdS@MoS2) were successfully synthesized and characterized. The photocatalytic performance of the MoS2 and CdS@MoS2 was evaluated by degrading brilliant green (BG), methylene blue (MB), and rhodamine B (RhB) dyes under visible light irradiation. Amongst the synthesized photocatalysts, 50% CdS@MoS2 exhibited the highest photocatalytic activity, degrading 97.6%, 90.3%, and 75.5% of BG, MB, and RhB dyes, respectively within 5 h. The active species involved in the degradation processes were investigated. All trapping agents inhibited BG and MB degradation to a similar extent, indicating that all of the probed active species play an important role in the degradation of BG and MB. In contrast, h+ and O2•− were found to be the main reactive species in the photocatalytic RhB degradation. A potential mechanism for the photocatalytic degradation of dyes using CdS@MoS2 has been proposed. This work highlights the potential of CdS@MoS2 as a photocatalyst for more efficient water remediation applications.

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来源期刊
BMC Chemistry
BMC Chemistry Chemistry-General Chemistry
CiteScore
5.30
自引率
2.20%
发文量
92
审稿时长
27 weeks
期刊介绍: BMC Chemistry, formerly known as Chemistry Central Journal, is now part of the BMC series journals family. Chemistry Central Journal has served the chemistry community as a trusted open access resource for more than 10 years – and we are delighted to announce the next step on its journey. In January 2019 the journal has been renamed BMC Chemistry and now strengthens the BMC series footprint in the physical sciences by publishing quality articles and by pushing the boundaries of open chemistry.
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