探索聚合物材料热稳定性的氧热成像技术：一种新颖的分析方法

IF 1 4区化学 Q4 CHEMISTRY, ANALYTICAL Journal of Analytical Chemistry Pub Date : 2024-07-23 DOI:10.1134/s106193482470031x

B. K. Zuev, A. E. Zaitseva, A. S. Korotkov, V. G. Filonenko, I. V. Rogovaya

{"title":"探索聚合物材料热稳定性的氧热成像技术：一种新颖的分析方法","authors":"B. K. Zuev, A. E. Zaitseva, A. S. Korotkov, V. G. Filonenko, I. V. Rogovaya","doi":"10.1134/s106193482470031x","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The control of oxygen and carbon dioxide concentrations in an airflow released from a reactor, in which a sample is heated, can be used to investigate the thermal stability of polymer materials. This approach, known as oxithermography, involves analyzing experimental data (oxithermograms), representing the variation in oxygen concentration decrease and carbon dioxide appearance in an airflow with changing temperature conditions. This method allows for monitoring the effect of fillers introduced into polymer compositions on their thermal stability. The application of oxithermography to studying oxidative thermostability is demonstrated using pure polypropylene and polypropylene with titanium dioxide admixtures as examples.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":"17 1","pages":""},"PeriodicalIF":1.0000,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Oxythermography for Exploring the Thermal Stability of Polymer Materials: A Novel Analytical Approach\",\"authors\":\"B. K. Zuev, A. E. Zaitseva, A. S. Korotkov, V. G. Filonenko, I. V. Rogovaya\",\"doi\":\"10.1134/s106193482470031x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>The control of oxygen and carbon dioxide concentrations in an airflow released from a reactor, in which a sample is heated, can be used to investigate the thermal stability of polymer materials. This approach, known as oxithermography, involves analyzing experimental data (oxithermograms), representing the variation in oxygen concentration decrease and carbon dioxide appearance in an airflow with changing temperature conditions. This method allows for monitoring the effect of fillers introduced into polymer compositions on their thermal stability. The application of oxithermography to studying oxidative thermostability is demonstrated using pure polypropylene and polypropylene with titanium dioxide admixtures as examples.</p>\",\"PeriodicalId\":606,\"journal\":{\"name\":\"Journal of Analytical Chemistry\",\"volume\":\"17 1\",\"pages\":\"\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2024-07-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Analytical Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1134/s106193482470031x\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Analytical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s106193482470031x","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}

引用次数: 0

摘要

摘要控制从反应器中释放出来的气流中氧气和二氧化碳的浓度，并在其中对样品进行加热，可用于研究聚合物材料的热稳定性。这种方法被称为氧化热图法（oxithermography），包括分析实验数据（氧化热图），即气流中氧气浓度下降和二氧化碳出现随温度条件变化而变化的情况。这种方法可以监测聚合物成分中引入的填料对其热稳定性的影响。以纯聚丙烯和添加二氧化钛的聚丙烯为例，展示了氧化热成像仪在研究氧化热稳定性方面的应用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

摘要图片

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Oxythermography for Exploring the Thermal Stability of Polymer Materials: A Novel Analytical Approach

Abstract

The control of oxygen and carbon dioxide concentrations in an airflow released from a reactor, in which a sample is heated, can be used to investigate the thermal stability of polymer materials. This approach, known as oxithermography, involves analyzing experimental data (oxithermograms), representing the variation in oxygen concentration decrease and carbon dioxide appearance in an airflow with changing temperature conditions. This method allows for monitoring the effect of fillers introduced into polymer compositions on their thermal stability. The application of oxithermography to studying oxidative thermostability is demonstrated using pure polypropylene and polypropylene with titanium dioxide admixtures as examples.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Analytical Chemistry 化学-分析化学

CiteScore

2.10

自引率

9.10%

发文量

146

审稿时长

13 months

期刊介绍： The Journal of Analytical Chemistry is an international peer reviewed journal that covers theoretical and applied aspects of analytical chemistry; it informs the reader about new achievements in analytical methods, instruments and reagents. Ample space is devoted to problems arising in the analysis of vital media such as water and air. Consideration is given to the detection and determination of metal ions, anions, and various organic substances. The journal welcomes manuscripts from all countries in the English or Russian language.