砂和柴油影响下砂-膨润土混合物衬垫膨胀的时间效应和演变机理

IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Frontiers in Materials Pub Date : 2024-07-24 DOI:10.3389/fmats.2024.1447496
Ye-yang Chun, Zhengquan Liu, Yong He, He Wei, Dongpo Su
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引用次数: 0

摘要

为了阐明垃圾填埋场砂-膨润土混合物衬里在有机污染物作用下随时间变化的膨胀行为,对不同砂和柴油含量的混合物进行了无负荷膨胀比试验。研究了膨胀时间曲线形态的演变特征。探讨了膨胀时间效应演变的微观机制。结果表明,砂和柴油的相互作用显著改变了混合物的膨胀时间曲线形态特征。随着含沙量的增加,稳定状态下的膨胀系数降低。然而,在快速膨胀阶段,柴油污染混合土壤的膨胀系数并没有表现出未受污染混合土壤的先增后减模式。缓慢膨胀阶段的持续时间和达到稳定状态的时间都更长。机理分析表明,阳离子交换容量不足以有效分析膨胀时间曲线的演变特征。相反,膨润土的初始溶胀势才是衡量混合物溶胀特性的真正指标。在快速膨胀阶段,粒度分布会影响膨胀系数的变化,但柴油会改变粒度分布,从而减轻其影响。团聚内孔隙和团聚间孔隙中的油封效应不仅削弱了混合物各阶段的膨胀特性,还增加了抗渗透性,从而缩短了快速膨胀阶段的持续时间,延长了缓慢膨胀阶段和稳定膨胀阶段的持续时间。
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Temporal effect and evolution mechanism of sand-bentonite mixture liner swelling under the influence of sand and diesel
To elucidate the time-dependent swelling behavior of landfill sand-bentonite mixture liners under the effect of organic pollutants, an no loading swelling ratio test was conducted on mixtures with varying sand and diesel content. The evolution characteristics of the swelling time curve morphology were investigated. The micro-mechanisms underlying the swelling time effect evolution were explored. The results indicated that the sand-diesel interaction significantly altered the swelling time curve morphological characteristics of the mixture. As the sand content increased, the swelling coefficient at the stable state decreased. However, during the rapid swell phase, diesel-contaminated mixed soil does not exhibit the increase-then-decrease pattern in swell coefficient seen in unpolluted mixed soil. The duration of both the slow swelling phase and the time to reach a stable state were longer. Mechanistic analysis revealed that cation exchange capacity is insufficient to effectively analyze the evolution characteristics of the swelling time curve. Instead, the initial swelling potential of bentonite is the true indicator of the mixture’s swelling properties. The particle size distribution influences the changes in the swelling coefficient during the rapid swelling phase, but diesel alters the particle size distribution, mitigating its impact. The oil sealing effect within intra-aggregate and inter-aggregate pores not only weakened the swelling characteristics of the mixture at all stages but also increased the permeability resistance, thereby reducing the duration of the rapid swelling phase and extending the slow swelling and stable swelling phases.
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来源期刊
Frontiers in Materials
Frontiers in Materials Materials Science-Materials Science (miscellaneous)
CiteScore
4.80
自引率
6.20%
发文量
749
审稿时长
12 weeks
期刊介绍: Frontiers in Materials is a high visibility journal publishing rigorously peer-reviewed research across the entire breadth of materials science and engineering. This interdisciplinary open-access journal is at the forefront of disseminating and communicating scientific knowledge and impactful discoveries to researchers across academia and industry, and the public worldwide. Founded upon a research community driven approach, this Journal provides a balanced and comprehensive offering of Specialty Sections, each of which has a dedicated Editorial Board of leading experts in the respective field.
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