抗坏血酸基环氧树脂的合成

IF 2.8 4区 工程技术 Q2 POLYMER SCIENCE Macromolecular Research Pub Date : 2024-07-23 DOI:10.1007/s13233-024-00301-6
Huibeom Yeon, Hyunshick Youn, Yeonha Ju, Munju Goh
{"title":"抗坏血酸基环氧树脂的合成","authors":"Huibeom Yeon, Hyunshick Youn, Yeonha Ju, Munju Goh","doi":"10.1007/s13233-024-00301-6","DOIUrl":null,"url":null,"abstract":"<p>This study aimed to address the environmental concerns associated with petrochemical-derived bisphenol-A, commonly used in epoxy resin synthesis, by developing an eco-friendly alternative utilizing bio-based ascorbic acid, or vitamin C. The epoxy compound was synthesized by leveraging the hydroxyl group inherent in ascorbic acid through a reaction with epichlorohydrin. Optimal curing conditions were determined via dynamic scan and isotherm analysis using Differential Scanning Calorimetry (DSC) for the newly synthesized epoxy resin in combination with isophorone diamine (IPDA) as the curing agent. The cured product, obtained under the identified optimal curing conditions, exhibited a soft hardened form with a tensile strength of 7.5 MPa and an elongation of 6%. These findings underscore the feasibility of synthesizing a commercially viable eco-friendly epoxy resin utilizing ascorbic acid, thus contributing to the ongoing pursuit of sustainable material alternatives. The results suggest potential scalability for mass production, emphasizing the significance of this approach in addressing the demand for environmentally friendly materials in various industrial applications.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3><p>Synthesis of ascorbic acid-based epoxy resin.</p>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"25 1","pages":""},"PeriodicalIF":2.8000,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of ascorbic acid-based epoxy resin\",\"authors\":\"Huibeom Yeon, Hyunshick Youn, Yeonha Ju, Munju Goh\",\"doi\":\"10.1007/s13233-024-00301-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This study aimed to address the environmental concerns associated with petrochemical-derived bisphenol-A, commonly used in epoxy resin synthesis, by developing an eco-friendly alternative utilizing bio-based ascorbic acid, or vitamin C. The epoxy compound was synthesized by leveraging the hydroxyl group inherent in ascorbic acid through a reaction with epichlorohydrin. Optimal curing conditions were determined via dynamic scan and isotherm analysis using Differential Scanning Calorimetry (DSC) for the newly synthesized epoxy resin in combination with isophorone diamine (IPDA) as the curing agent. The cured product, obtained under the identified optimal curing conditions, exhibited a soft hardened form with a tensile strength of 7.5 MPa and an elongation of 6%. These findings underscore the feasibility of synthesizing a commercially viable eco-friendly epoxy resin utilizing ascorbic acid, thus contributing to the ongoing pursuit of sustainable material alternatives. The results suggest potential scalability for mass production, emphasizing the significance of this approach in addressing the demand for environmentally friendly materials in various industrial applications.</p><h3 data-test=\\\"abstract-sub-heading\\\">Graphical abstract</h3><p>Synthesis of ascorbic acid-based epoxy resin.</p>\",\"PeriodicalId\":688,\"journal\":{\"name\":\"Macromolecular Research\",\"volume\":\"25 1\",\"pages\":\"\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2024-07-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecular Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1007/s13233-024-00301-6\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1007/s13233-024-00301-6","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

摘要

本研究旨在利用生物基抗坏血酸或维生素 C 开发一种生态友好型替代品,从而解决环氧树脂合成中常用的石化衍生双酚 A 带来的环境问题。通过使用差示扫描量热仪(DSC)进行动态扫描和等温线分析,确定了新合成的环氧树脂与作为固化剂的异佛尔酮二胺(IPDA)的最佳固化条件。在确定的最佳固化条件下获得的固化产品呈现软硬化形态,抗拉强度为 7.5 兆帕,伸长率为 6%。这些发现强调了利用抗坏血酸合成商业上可行的生态友好型环氧树脂的可行性,从而推动了对可持续材料替代品的不断追求。研究结果表明该方法具有大规模生产的潜在可扩展性,强调了该方法在满足各种工业应用对环保材料需求方面的重要意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Synthesis of ascorbic acid-based epoxy resin

This study aimed to address the environmental concerns associated with petrochemical-derived bisphenol-A, commonly used in epoxy resin synthesis, by developing an eco-friendly alternative utilizing bio-based ascorbic acid, or vitamin C. The epoxy compound was synthesized by leveraging the hydroxyl group inherent in ascorbic acid through a reaction with epichlorohydrin. Optimal curing conditions were determined via dynamic scan and isotherm analysis using Differential Scanning Calorimetry (DSC) for the newly synthesized epoxy resin in combination with isophorone diamine (IPDA) as the curing agent. The cured product, obtained under the identified optimal curing conditions, exhibited a soft hardened form with a tensile strength of 7.5 MPa and an elongation of 6%. These findings underscore the feasibility of synthesizing a commercially viable eco-friendly epoxy resin utilizing ascorbic acid, thus contributing to the ongoing pursuit of sustainable material alternatives. The results suggest potential scalability for mass production, emphasizing the significance of this approach in addressing the demand for environmentally friendly materials in various industrial applications.

Graphical abstract

Synthesis of ascorbic acid-based epoxy resin.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Macromolecular Research
Macromolecular Research 工程技术-高分子科学
CiteScore
4.70
自引率
8.30%
发文量
100
审稿时长
1.3 months
期刊介绍: Original research on all aspects of polymer science, engineering and technology, including nanotechnology Presents original research articles on all aspects of polymer science, engineering and technology Coverage extends to such topics as nanotechnology, biotechnology and information technology The English-language journal of the Polymer Society of Korea Macromolecular Research is a scientific journal published monthly by the Polymer Society of Korea. Macromolecular Research publishes original researches on all aspects of polymer science, engineering, and technology as well as new emerging technologies using polymeric materials including nanotechnology, biotechnology, and information technology in forms of Articles, Communications, Notes, Reviews, and Feature articles.
期刊最新文献
Biodegradable and antioxidant lignin-adsorbed polylactic acid microparticles for eco-friendly primary microparticles Discarded bamboo chopstick cellulose-based fibers for bio-based polybutylene succinate composite reinforcement Recent achievements in conjugated polymer-based gas sensors by side-chain engineering Antimicrobial polymer coatings on surfaces: preparation and activity Polymer-induced surface wrinkling and imine polymer-based doping of sol–gel zinc oxide in electrolyte-gated transistors
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1