TiN 单层和 Ti/TiN 多层涂层对钛合金拉伸疲劳行为的影响

Zhaolu Zhang, Minglei Yang, Guangyu He
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摘要

本文研究了单层和多层涂层对 TC11 钛合金拉伸疲劳性能的影响。通过扫描电子显微镜、X 射线衍射仪和纳米压痕测量了涂层的形貌、相组成和力学性能。电子背散射衍射用于研究失效机理。未涂层 TC11、TiN 涂层 TC11、TiN/Ti 多层(ML-6、ML-3、ML-1)和 1 × 10 循环后的疲劳极限分别为 855 兆帕、550 兆帕、525 兆帕、500 兆帕和 400 兆帕。在疲劳加载条件下,硬涂层/TC11 基体通过涂层开裂加速基体的疲劳失效。EBSD 分析结果表明,TC11 钛合金在拉伸-张力疲劳载荷下的主要滑移体系是 α 相(10-10)[-12-10]。在疲劳极限循环 1 × 10 次后,TiN 涂层 TC11 表面的平均位错密度低于 TC11。由于涂层制备引起的表面缺陷和较高的裂纹扩展速度,硬涂层通过缩短疲劳裂纹起始周期而显著降低了 TC11 的疲劳性能。因此,与其从涂层结构设计的角度出发来提高疲劳裂纹扩展周期,不如降低涂层表面粗糙度来提高疲劳裂纹萌发周期更为有效。
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Effect of TiN monolithic and Ti/TiN multilayer coating on the fatigue behavior of titanium alloy under tension-tension
This paper investigates the fatigue failure mechanism of mono- and multilayer coatings on the fatigue performance of TC11 titanium alloy under tension-tension. The morphology, phase composition, mechanical properties were measured by scanning electron microscope, X-ray diffractometer and nanoindentation. Electron back scatter diffraction was employed to investigated the failure mechanism. Fatigue limits obtained of uncoated TC11, TC11 with TiN coating, TiN/Ti multilayer (ML-6, ML-3, ML-1) and after 1 × 10 cycles are 855 MPa, 550 MPa, 525 MPa, 500 MPa and 400 MPa. Under fatigue loading, the hard-coating/TC11 substrate experiences fatigue failure through coating cracking hastens the substrate's fatigue failure. EBSD analysis results indicate that the main slip system of TC11 titanium alloy under tension-tension fatigue load is α phase (10-10)[-12-10]. After 1 × 10 cycles at fatigue limits, the average dislocation density on the surface of the TC11 with TiN coating is lower than that of TC11. Due to the surface defect induced by coating preparation and high crack propagation velocity, the hard coating significantly deteriorates fatigue property of TC11 by reducing fatigue crack initiation period. Therefore, instead of approaching from the perspective of coating structure design to increase the fatigue crack propagation cycles, it is more effective to reduce the surface roughness of the coating and enhance the fatigue crack initiation cycles.
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