1,3-二取代二茂铁衍生物的合成进展:从计量方法到催化方法

IF 2.8 4区 化学 Q1 CHEMISTRY, ORGANIC Asian Journal of Organic Chemistry Pub Date : 2024-10-01 DOI:10.1002/ajoc.202400301
Javier Santamaría , Patricia García‐Martínez , Luis A. López
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引用次数: 0

摘要

功能化二茂铁衍生物在各个科学领域都有广泛的应用。尽管在合成 1,2-二茂铁衍生物方面取得了重大进展,但 1,3-二茂铁的制备仍然具有挑战性。不过,最近有报道称,1,3-二取代二茂铁有几种强大的合成方法。本综述旨在介绍这些合成方法的演变,从最初的化学计量学方法到最近的催化方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Advances in the Synthesis of 1,3‐Disubstituted Ferrocene Derivatives: From Stoichiometric to Catalytic Methods
Functionalized ferrocene derivatives have a wide range of applications across various scientific fields. Although significant progress has been made in synthesizing 1,2‐disubstituted ferrocene derivatives, the preparation of 1,3‐disubstituted ferrocenes remains challenging. Recently, however, several powerful synthetic approaches to 1,3‐disubstituted ferrocenes have been reported. This review aims to present the evolution of these synthetic methods, from initial stoichiometric approaches to the more recent catalytic methodologies.
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来源期刊
CiteScore
4.70
自引率
3.70%
发文量
372
期刊介绍: Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.
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