对罗切斯特矿的浸出柱进行三维成像,以了解孔隙网络特征和晶格玻尔兹曼法模拟的渗透性

IF 4.8 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Hydrometallurgy Pub Date : 2024-07-20 DOI:10.1016/j.hydromet.2024.106365
Amanda N. Erskine , Jiaqi Jin , Chen-Luh Lin , Jan D. Miller , Shijie Wang
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引用次数: 0

摘要

在堆浸操作中,金属回收从根本上受矿石粒度分布(PSD)的控制,而粒度分布又决定了矿石的暴露特性、浸出反应速率和流体流动现象。溶液在堆中的流畅循环对于沥滤设备的成功运行非常重要。采用 X 射线计算机断层扫描 (XCT) 技术对罗切斯特矿场直径 6 英寸沥滤柱内部的孔隙网络进行了扫描,体素尺寸为 100 μm,以通过晶格玻尔兹曼法 (LBM) 估算渗透率。6 英寸色谱柱底部的孔隙率和相应的渗透率远低于顶部。底层和顶层的 PSD 没有显示出细粒的迁移,重力压缩降低了底层的渗透率。通过 XCT 扫描了具有可控 PSD 的直径 4 英寸沥滤柱内部的孔隙网络,分辨率更高,体素尺寸为 68 μm。除了大颗粒(岩石)和孔隙网络外,还发现了另一个由局部流体运动产生的细粒团聚阶段。这一阶段的团聚细粒会挤占沥滤柱内部孔隙网络的体积,从而降低渗透性,导致堆内可能出现积水问题。
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3D imaging of leach columns from Rochester mine for pore network characteristics and permeability simulated by the Lattice Boltzmann Method

In heap leach operations, metal recovery is fundamentally controlled by the ore's particle size distribution (PSD), which determines mineral exposure characteristics, the rate of leaching reactions, and fluid flow phenomena. A fluent circulation of solution through the heap is important for successful leach plant operation. The pore networks inside 6-in. diameter leach columns from the Rochester mine were scanned by X-ray Computed Tomography (XCT) at a voxel size of 100 μm, to estimate the permeability by Lattice Boltzmann Method (LBM). The bottom sections of 6-in. columns had much less porosity and corresponding permeability than the top sections. PSD of the bottom and top sections showed no migration of fines, and gravity compression reduced the bottom sections' permeability. The pore networks inside 4-in. diameter leach columns with controlled PSD were scanned by XCT at a higher resolution with a voxel size of 68 μm. In addition to the large particles (rocks) and pore network, another phase of agglomerated fines from local fluid movement was identified. This phase of agglomerated fines can overwhelm the volume of the pore network inside leach columns and thus reduce the permeability, leading to possible ponding issues in the heap.

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来源期刊
Hydrometallurgy
Hydrometallurgy 工程技术-冶金工程
CiteScore
9.50
自引率
6.40%
发文量
144
审稿时长
3.4 months
期刊介绍: Hydrometallurgy aims to compile studies on novel processes, process design, chemistry, modelling, control, economics and interfaces between unit operations, and to provide a forum for discussions on case histories and operational difficulties. Topics covered include: leaching of metal values by chemical reagents or bacterial action at ambient or elevated pressures and temperatures; separation of solids from leach liquors; removal of impurities and recovery of metal values by precipitation, ion exchange, solvent extraction, gaseous reduction, cementation, electro-winning and electro-refining; pre-treatment of ores by roasting or chemical treatments such as halogenation or reduction; recycling of reagents and treatment of effluents.
期刊最新文献
Editorial Board A novel method for leaching rare earth element from fluorescent lamp waste via acid fusion Preparation of high-purity iron oxide from end-of-life NdFeB magnet waste Efficient separation and recovery of cobalt from grinding waste of cemented carbide using a sulfuric acid-sodium persulfate mixed solution Separation of cerium from solution by oxidative precipitation with hydrogen peroxide: The reaction mechanism
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