Using Iron Stable Isotopes to Quantify the Origins of the Cryoconite Iron Materials in Western China and Exploring Controlling Factors

Iron (Fe) has profound impacts on Earth's ecosystem and global biogeochemical cycles. Fe deposited onto glacier surfaces reduces snow and ice albedo, thereby accelerating glacier melting, and supplying downstream ecosystems with dissolved Fe. However, the origins of atmospheric Fe deposition in glacier regions of western China remain unclear. This study presents novel insights into Fe isotopic composition (refer to δ⁵⁶Fe) and origins, gained from geochemical analysis of large-scale cryoconite samples collected from glaciers in western China, which encompass the Tibetan Plateau (TP) and the Tianshan Mountains. Results showed that cryoconite δ⁵⁶Fe ranged from −1.06 ± 0.07‰ to 0.33 ± 0.04‰, regardless of their concentration. Moreover, anomalous δ⁵⁶Fe values deviating significantly from the upper continental crust values (with an average of 0.09‰) were detected, indicating a significant impact of anthropogenic Fe materials on the investigated glaciers. This impact was particularly prominent in the margin regions of the TP and its surroundings, but was less apparent in the interior and southern of the plateau. Using MixSIAR isotope mixing model, we determined that coal combustion and other anthropogenic combustion sources (such as liquid fuel combustion and steel smelting) contributed to cryoconite Fe in the range of 6.9%–43.1% and 0.8%–23.4%, respectively. Among these, coal combustion was the predominant anthropogenic source of cryoconite Fe in western China's glaciers. Compared with other sink areas in the Northern Hemisphere, glaciers in western China are obviously affected by anthropogenically sourced Fe. This study has significant implications for understanding glacier-fed downstream ecosystems and the regional biogeochemical cycle.