基于廉价非贵金属阴极的高性能铝空气电池设计

Jingyu Hu
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摘要

随着移动电子设备和电动汽车等领域的快速发展,环境问题和能源问题日益突出。因此,开发绿色、安全、高效、廉价、可持续的储能和大规模应用的储能装置显得尤为重要。铝空气电池是一种通过电化学反应将正极铝的化学能直接转化为电能的装置。铝空气电池理论电压高(2.75 V)、比容量大(2.98 Ah/g)、比能量高(8.1 Wh/g),且金属铝是一种高强度的能量载体,具有资源丰富、价格低廉、环境友好等优点,完全符合当前形势下的供电要求。然而,由于正极氧还原反应动力学缓慢,且使用昂贵的贵金属 Pt/C 作为催化剂,现有的铝空气电池面临着成本高昂的经济问题。为了降低铝空气电池的成本,本文计划采用廉价的非贵金属纳米碳材料作为阴极催化剂,并灵活运用结构设计构建双阴极铝空气电池结构,有效增加了阴极反应面积。本文通过实验方法对其放电性能进行了研究,其峰值功率是传统单阴极电池的1.42倍,具有良好的催化性能和稳定性,表明非贵金属双阴极结构电池既实用又经济。
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Designofhighperformancealuminum-airbatterybasedoncheapnon-preciousmetalcathodes
With the rapid development of areas such as mobile electronic devices and electric vehicles, environmental problems and energy problems have become increasingly prominent. Therefore, it is particularly important to develop green, safe, efficient, cheap, sustainable energy storage and large-scale application of energy storage devices. Aluminum-air battery is a device that converts the chemical energy of anode aluminum directly into electric energy through electrochemical reaction. The theoretical voltage of aluminum-air battery is high (2.75 V), large specific capacity (2.98 Ah/g), high specific energy (8.1 Wh/g), and metal aluminum is a high strength energy carrier, has the advantages of rich resources, low price, environment friendly, perfectly matching the current situation of power supply requirements. However, the existing aluminum-air batteries face the economic problem of high cost, due to the slow oxygen reduction reaction dynamics of the cathode and the use of the expensive precious metal Pt/C as a catalyst. In order to reduce the cost of aluminum-air batteries, this paper plans to use the cheap non-precious metal nano carbon materials as the cathode catalyst, and flexibly use the structural design to construct the structure of the aluminum-air battery with double cathodes, which effectively increases the cathode reaction area. In this paper, the discharge performance was studied by experimental method, and its peak power is 1.42 times that of the traditional single cathode battery, which has good catalytic performance and stability, and shows that the non-precious metal double-cathode structure battery is both practical and economical.
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