Kieu Do Trung Kien, Hanh Ong Dieu, Khoi Nguyen Hoang Thien, Minh Huynh Ngoc
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引用次数: 0
摘要
碳化硅(SiC)是一种具有良好技术特性和较高经济价值的矿物。然而,由于碳化硅的合成需要在高温环境下(1500 摄氏度以上)进行,因此合成成本较高。利用生物质合成碳化硅可以大大降低合成温度。稻壳是合成碳化硅的一种常用生物质材料。然而,合成 SiC 的能力取决于稻壳的形状。本研究探讨了稻壳形态对合成碳化硅能力的影响。实验结果表明,原始稻壳比稻壳粉具有更好的碳化硅形成能力。原始稻壳经硅酸钠溶液浸渍并在 1200 摄氏度高温分解后,形成的 SiC 量为 18.3%(重量百分比)。使用稻壳粉则为 15.12%(重量百分比)。通过 X 射线衍射 (XRD)、傅立叶红外变换法 (FT-IR) 和扫描电子显微镜 (SEM) 对矿物成分、官能团和形态进行分析的结果表明,SiC 的多形态为 α-SiC 和 β-SiC。这些矿物是稻壳中 SiC 的基础,可用作耐磨材料。
Effect of rice husk morphology on the ability to synthesize silicon carbide by pyrolysis method
Silicon carbide (SiC) is a mineral with good technical properties and high economic value. However, the synthesis of SiC is expensive because it is synthesized at a high-temperature environment (above 1500oC). The synthesis of SiC from biomass can significantly reduce the synthesis temperature. One commonly used biomass material for synthesizing SiC is rice husk. However, the ability to synthesize SiC depends on the shape of the rice husk. The influence of the morphology of rice husk on the ability to synthesize SiC was studied in this study. Experimental results showed that the original rice husk would give better SiC formation capacity than the rice husk powder. The amount of SiC formed using the original rice husk when impregnated by sodium silicate solution and pyrolysis at 1200oC is 18.3% (wt%.). With rice husk powder, it is 15.12% (wt%.). The results of analysis of the mineral composition, functional groups, and morphologies by X-ray diffraction (XRD), Fourier Infrared Transform Method (FT-IR), and Scanning Electron Microscopy (SEM) found that the polymorphy of SiC is α-SiC and β-SiC. These minerals are the basis for SiC from rice husks, which can be applied as wear-resistant materials.