基于废聚氨酯硬质泡沫和木皮的新型复合材料的制造与研究

IF 1.3 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Bioresources Pub Date : 2024-07-16 DOI:10.15376/biores.19.3.5916-5934
Xuanyuan Xia, Wenqian Cai, Yujie Wang, Zhongyuan Zhao
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引用次数: 0

摘要

由于对聚氨酯硬质泡沫(PURF)的需求不断增长,导致聚氨酯废品大幅增加。鉴于废旧 PURF 难以回收利用,本研究介绍了一种新型机械回收工艺,该工艺具有成本效益高、生产 PUW(废旧 PURF 与木皮结合)的简单制造过程等特点,解决了机械回收利用聚氨酯废料所获得的产品强度低的问题。通过对 PURF(使用前研磨成颗粒)的粒度、芯层密度、树脂用量和厚度进行研究,确定了最佳制造工艺如下:芯层成分为粒度为 1 至 3 毫米的颗粒,芯层密度为 0.9 克/立方厘米,MDI 的添加量为 20 wt%,整个复合材料的厚度为 8 毫米。结果表明,基于 PURF 的复合材料具有优异的隔热性能、机械强度和隔音性能。优化后的 PUW 复合材料的导热系数为 0.04126 W/(m-K),明显低于岩棉板(0.04 W/(m-K))。在机械性能方面,最佳 PUW 复合材料的湿剪切强度达到了 0.61 兆帕。此外,聚氨酯岩棉复合材料还具有相对较高的隔音性能,尤其是在高频率下。
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Fabrication and investigation of a novel composite based on waste polyurethane rigid foam and wood veneer
The escalating demand for polyurethane rigid foams (PURF) has resulted in a substantial increase in waste polyurethane products. In view of the difficulty in recycling waste PURF, this study introduces a novel mechanical recycling process that is cost-effective and features a straightforward fabrication process for producing PUW (waste PURF combined with wood veneers), which solves the problem of low strength products obtained from mechanical recycling of PU waste. Through investigation of the PURF (ground into particles before using) particle size, core layer density, the amount of resin and thickness, the optimal fabrication process was confirmed as follows: particles with the size of 1 to 3 mm as its core layer components, 0.9 g/cm3 as its core layer density, the addition of MDI to be 20 wt%, and 8 mm thickness of whole composite. The resulting PURF-based composite exhibited superior thermal insulation properties, mechanical strength, and sound insulation performance. The optimized PUW composite had a notably low thermal conductivity of 0.04126 W/(m·K), slightly higher than that of rock wool board (0.04 W/(m·K)). In terms of mechanical performance, the wet shear strength of the optimal PUW composite reached 0.61 MPa. Furthermore, the PUW composite exhibited relatively high sound insulation, particularly at high frequencies.
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来源期刊
Bioresources
Bioresources 工程技术-材料科学:纸与木材
CiteScore
2.90
自引率
13.30%
发文量
397
审稿时长
2.3 months
期刊介绍: The purpose of BioResources is to promote scientific discourse and to foster scientific developments related to sustainable manufacture involving lignocellulosic or woody biomass resources, including wood and agricultural residues. BioResources will focus on advances in science and technology. Emphasis will be placed on bioproducts, bioenergy, papermaking technology, wood products, new manufacturing materials, composite structures, and chemicals derived from lignocellulosic biomass.
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