Chidiebele E.J. Uzoagba , Edmund Okoroigwe , Marzieh Kadivar , Vitalis C. Anye , Abdulhakeem Bello , Uchechukwu Ezealigo , Fayen Odette Ngasoh , Helena Pereira , Peter Azikiwe Onwualu
{"title":"用于生产生物燃料的非洲罂粟生物质中的木材、树叶、树皮和豆荚废弃物的特性分析","authors":"Chidiebele E.J. Uzoagba , Edmund Okoroigwe , Marzieh Kadivar , Vitalis C. Anye , Abdulhakeem Bello , Uchechukwu Ezealigo , Fayen Odette Ngasoh , Helena Pereira , Peter Azikiwe Onwualu","doi":"10.1016/j.wmb.2024.07.007","DOIUrl":null,"url":null,"abstract":"<div><p>One of the approaches for increasing the contribution of biomass to the renewable energy mix is the valorization of biomass to bioenergy. Evaluating the potential of unconventional biomass sources could significantly accelerate the assessment for suitability as feedstock for bioenergy production as a sustainable solution. The study aimed to characterize the <em>Prosopis africana</em> biomass of wood, barks, leaves, and pods towards providing valuable data for scaling up and incorporating these materials into the bioenergy crop database. Characterizations of wood, leaves, barks, and pod wastes from <em>Prosopis africana</em> biomass were investigated based on the proximate, ultimate, and compositional analysis of pulverized samples of the <em>PA</em> biomass to determine their physical, thermal, and chemical properties towards assessing their potential for valorization to bioenergy. The lignocellulosic materials were characterized by scanning electron microscopy, energy dispersive X-ray, Fourier transform infrared spectroscopy, thermogravimetric analysis, and X-ray diffraction. The results show that the pulverized sample wastes have porous structures with varying degrees of crystallinity (wood: 89.20 %, bark: 23.90 %, leaves: 32.48 %, pods: 23.08 %), suggesting different susceptibilities to conversion processes. Notably, the wood sample had the lowest moisture content (3.13 %), and the pod sample had the highest volatile matter content (75.83 %), indicating a high potential for biofuel production. The higher heating values (HHV) and lower heating values (LHV) of the samples ranged from 15.23 to 20.49 MJ/kg and 13.83 to 18.79 MJ/kg, respectively. These calorific values are competitive with established lignocellulosic bioenergy feedstocks, positioning PA biomass as promising candidates for solid biofuel applications.</p></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"2 3","pages":"Pages 172-182"},"PeriodicalIF":0.0000,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949750724000646/pdfft?md5=84c2479d061245b29c439ec6086f6c76&pid=1-s2.0-S2949750724000646-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Characterization of Wood, Leaves, Barks, and pod wastes from Prosopis africana biomass for biofuel production\",\"authors\":\"Chidiebele E.J. Uzoagba , Edmund Okoroigwe , Marzieh Kadivar , Vitalis C. Anye , Abdulhakeem Bello , Uchechukwu Ezealigo , Fayen Odette Ngasoh , Helena Pereira , Peter Azikiwe Onwualu\",\"doi\":\"10.1016/j.wmb.2024.07.007\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>One of the approaches for increasing the contribution of biomass to the renewable energy mix is the valorization of biomass to bioenergy. Evaluating the potential of unconventional biomass sources could significantly accelerate the assessment for suitability as feedstock for bioenergy production as a sustainable solution. The study aimed to characterize the <em>Prosopis africana</em> biomass of wood, barks, leaves, and pods towards providing valuable data for scaling up and incorporating these materials into the bioenergy crop database. Characterizations of wood, leaves, barks, and pod wastes from <em>Prosopis africana</em> biomass were investigated based on the proximate, ultimate, and compositional analysis of pulverized samples of the <em>PA</em> biomass to determine their physical, thermal, and chemical properties towards assessing their potential for valorization to bioenergy. The lignocellulosic materials were characterized by scanning electron microscopy, energy dispersive X-ray, Fourier transform infrared spectroscopy, thermogravimetric analysis, and X-ray diffraction. The results show that the pulverized sample wastes have porous structures with varying degrees of crystallinity (wood: 89.20 %, bark: 23.90 %, leaves: 32.48 %, pods: 23.08 %), suggesting different susceptibilities to conversion processes. Notably, the wood sample had the lowest moisture content (3.13 %), and the pod sample had the highest volatile matter content (75.83 %), indicating a high potential for biofuel production. The higher heating values (HHV) and lower heating values (LHV) of the samples ranged from 15.23 to 20.49 MJ/kg and 13.83 to 18.79 MJ/kg, respectively. 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引用次数: 0
摘要
提高生物质在可再生能源组合中的比例的方法之一是将生物质转化为生物能源。对非常规生物质来源的潜力进行评估,可大大加快对其作为生物能源生产原料的适宜性的评估,使其成为一种可持续的解决方案。这项研究旨在描述非洲罂粟的木材、树皮、树叶和豆荚等生物质的特征,为扩大这些材料的规模并将其纳入生物能源作物数据库提供有价值的数据。通过对非洲罂粟生物质粉碎样本进行近似、最终和成分分析,研究了非洲罂粟生物质中的木材、树叶、树皮和荚果废料的特性,以确定其物理、热和化学特性,从而评估其作为生物能源的价值潜力。通过扫描电子显微镜、能量色散 X 射线、傅立叶变换红外光谱、热重分析和 X 射线衍射对木质纤维素材料进行了表征。结果表明,粉碎后的废料样品具有多孔结构,结晶度各不相同(木材:89.20%;树皮:23.90%;树叶:32.48%;豆荚:23.08%),这表明它们对转化过程具有不同的敏感性。值得注意的是,木材样本的含水量最低(3.13 %),豆荚样本的挥发性物质含量最高(75.83 %),这表明其具有生产生物燃料的巨大潜力。样品的较高热值(HHV)和较低热值(LHV)分别为 15.23 至 20.49 兆焦/千克和 13.83 至 18.79 兆焦/千克。这些热值与现有的木质纤维素生物能源原料相比具有竞争力,因此 PA 生物质有望成为固体生物燃料的候选原料。
Characterization of Wood, Leaves, Barks, and pod wastes from Prosopis africana biomass for biofuel production
One of the approaches for increasing the contribution of biomass to the renewable energy mix is the valorization of biomass to bioenergy. Evaluating the potential of unconventional biomass sources could significantly accelerate the assessment for suitability as feedstock for bioenergy production as a sustainable solution. The study aimed to characterize the Prosopis africana biomass of wood, barks, leaves, and pods towards providing valuable data for scaling up and incorporating these materials into the bioenergy crop database. Characterizations of wood, leaves, barks, and pod wastes from Prosopis africana biomass were investigated based on the proximate, ultimate, and compositional analysis of pulverized samples of the PA biomass to determine their physical, thermal, and chemical properties towards assessing their potential for valorization to bioenergy. The lignocellulosic materials were characterized by scanning electron microscopy, energy dispersive X-ray, Fourier transform infrared spectroscopy, thermogravimetric analysis, and X-ray diffraction. The results show that the pulverized sample wastes have porous structures with varying degrees of crystallinity (wood: 89.20 %, bark: 23.90 %, leaves: 32.48 %, pods: 23.08 %), suggesting different susceptibilities to conversion processes. Notably, the wood sample had the lowest moisture content (3.13 %), and the pod sample had the highest volatile matter content (75.83 %), indicating a high potential for biofuel production. The higher heating values (HHV) and lower heating values (LHV) of the samples ranged from 15.23 to 20.49 MJ/kg and 13.83 to 18.79 MJ/kg, respectively. These calorific values are competitive with established lignocellulosic bioenergy feedstocks, positioning PA biomass as promising candidates for solid biofuel applications.