经济有效的微生物诱导 ZnO 合成建筑材料:抗菌、光催化和机械特性

IF 6.7 2区 环境科学与生态学 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Environmental Technology & Innovation Pub Date : 2024-07-22 DOI:10.1016/j.eti.2024.103762
Pin-Yun Lin , Yi-Hsun Huang , Jung-Sheng Chen , Raju Kumar Sharma , Koyeli Das , Uttara Sukul , Gobinda Dey , Pritam Banerjee , Mayur Shinde , Md. Taharia , Chien-Yen Chen
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引用次数: 0

摘要

在土木工程中使用有效、经济的纳米颗粒/纳米复合材料仍然是当前研究领域的一项重大挑战。本研究将微生物诱导沉淀法用于白水泥砂浆的整合,以提高其效率,并评估其在亚甲基蓝的抗菌和光催化降解方面的潜在应用。经过 28 天的分析,合成的氧化锌呈六方菱镁矿结构,结晶度高,水化产物贡献显著。随着吸附剂比例从 ZnO-0 增加到 2.5,合成材料的形态也从针状结构变为管状结构。与商用 ZnO 12.71% 的基准吸水率相比,ZnO-2.5 样品浆料中的吸水率显著降低了 52.75%,接触角高达 89.54°,这表明材料具有亲水性。样品 ZnO-2.5 的最高抗压强度为 508.89 kgf/cm2(湿固化法 28 天),这表明样品中的硅酸钙有效地形成了凝胶。在使用 ZnO-2.5 的情况下,亚甲基蓝染料的最大降解率为 79.95%,这显示了另一种具有出色效率的影响特性。此外,所制备的样品在模拟阳光下几乎具有完全的杀菌效率。与商品白水泥砂浆相比,生物白水泥砂浆在工业规模上每立方米可节省 149 531 新台币。因此,研究结果表明,采用水热法制备生物白水泥砂浆时,微生物诱导的锌沉淀可改善其表面性能,提高其应用价值,并降低其研究成本。
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Cost-effective microbial induced ZnO synthesis for building material: Antibacterial, photocatalytic and mechanical characteristics

Utilization of effective and economical nanoparticles/nanocomposite materials in civil engineering is still remaining a significant challenge in current research arena. In this study, microbial-induced precipitation was formulated for integration of white cement mortar to enhance efficiency and evaluate its potential applications in antibacterial and photocatalytic degradation of methylene blue. Hexagonal wurtzite structure of synthesized ZnO exhibited high crystallinity with significant contribution of hydration product after 28days analysis. Morphology of produced material showed less homogeneity with high densification and morphology altered from needles-like structure to tube with the integration of adsorbent ratio from ZnO-0 to 2.5, presented all the required chemical components in EDXS analysis. The water absorption rate in sample slurry of ZnO-2.5 exhibited significant reduction of 52.75 % compared to baseline water absorption rate of 12.71 % in commercial ZnO and contact angle was noted higher as 89.54°, which indicates hydrophilic character of material. The highest compressive strength of sample ZnO-2.5 was noted 508.89 kgf/cm2 in 28days of wet curing method, indicated the effective gel formation of calcium silicate in samples. Maximum methylene blue dye degradation recorded 79.95 % in case of using ZnO-2.5, which showed another influential character with excellent efficiency. In addition, prepared sample has shown almost complete bactericidal efficiency under simulated sunlight. Compared to commercial white cement mortar, biological white cement mortar can save NT$149,531 per cubic meter at industrial scale. Therefore, results indicate that microbial-induced zinc precipitation incorporated using hydrothermal preparation of biological white cement mortar improves the surface properties for applications and reduces its cost of study.

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来源期刊
Environmental Technology & Innovation
Environmental Technology & Innovation Environmental Science-General Environmental Science
CiteScore
14.00
自引率
4.20%
发文量
435
审稿时长
74 days
期刊介绍: Environmental Technology & Innovation adopts a challenge-oriented approach to solutions by integrating natural sciences to promote a sustainable future. The journal aims to foster the creation and development of innovative products, technologies, and ideas that enhance the environment, with impacts across soil, air, water, and food in rural and urban areas. As a platform for disseminating scientific evidence for environmental protection and sustainable development, the journal emphasizes fundamental science, methodologies, tools, techniques, and policy considerations. It emphasizes the importance of science and technology in environmental benefits, including smarter, cleaner technologies for environmental protection, more efficient resource processing methods, and the evidence supporting their effectiveness.
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