将太阳能盐封装到 3D 打印活性炭/氧化铝支架中,用于热能储存应用

IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Open Ceramics Pub Date : 2024-09-01 Epub Date: 2024-07-26 DOI:10.1016/j.oceram.2024.100648
Irene Díaz-Herrezuelo , Quentin Falcoz , Audrey Soum-Glaude , Manuel Belmonte
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引用次数: 0

摘要

将相变材料(PCM)封装到添加剂制造的多孔支撑物中,对于开发具有更高能量性能的热能储存(TES)材料,正引起人们的极大兴趣。在这里,通过直接墨水写入(DIW)技术制造出了高孔隙率(86%)的自支撑三维活性炭/氧化铝支撑物,然后将太阳盐渗入其中,太阳盐是一种高腐蚀性 PCM,熔化温度约为 220 °C,通常用于聚光太阳能发电厂。这种新型、坚固、化学相容性好且重量轻的浸润式 3DTES 具有良好的热能储存效率(70%)和热稳定性,能量储存密度高(381 J g-1),并避免了熔盐的液体泄漏。此外,三维活性炭/氧化铝支架还提高了吸收太阳能的能力(79%),并增强了太阳能盐的热导率(高达 64%)。这些结果验证了利用 DIW 制造创新型 TES 的可行性,这种 TES 具有更强的储能性能。
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Solar salt encapsulated into 3D printed activated carbon/alumina supports for thermal energy storage applications

The encapsulation of phase change materials (PCMs) into additive manufactured porous supports is attracting great interest for developing thermal energy storage (TES) materials with improved energy performance. Here, highly porous (86 %) self-supported 3D activated carbon/alumina supports are fabricated by direct ink writing (DIW) and, then, infiltrated with solar salt, a highly corrosive PCM with a melting temperature around 220 °C commonly employed in concentrated solar power plants. This novel, robust, chemically compatible, and lightweight infiltrated 3DTES exhibits good thermal energy storage efficiency (70 %) and thermal stability, high energy storage density (381 J g−1), and avoids the liquid leakage of the molten salt. Besides, the 3D activated carbon/alumina support promotes a better ability to absorb solar energy (79 %) and enhances the thermal conductivity of the solar salt (up to 64 %). These results validate the use of DIW for manufacturing innovative TES with an enhanced energy storage behaviour.

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来源期刊
Open Ceramics
Open Ceramics Materials Science-Materials Chemistry
CiteScore
4.20
自引率
0.00%
发文量
102
审稿时长
67 days
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