Nanosecond laser-assisted fabrication of Ti6Al4V surfaces with gradient wettability and robust cross-linked microstructures

Surfaces with gradient wettability outperform singular superhydrophobic surfaces in terms of self-cleaning efficiency, anti-contamination properties, and fluid manipulation. These attributes offer extensive application potential across various industrial and scientific domains. This study introduces and employs nanosecond pulsed laser ablation to create wettability gradient surfaces on Ti6Al4V alloys, featuring robust cross-linked frame microstructures. Experimental results demonstrate that by varying the ridge width (w), associated with the liquid-solid contact fraction, we can achieve varying wettability and mechanical durability in these cross-linked frame microstructures. Wettability tests indicate static contact angles ranging from 150.7° to 105.45°. Furthermore, the sandpaper linear abrasion test illustrates a decrease in material wear rate with an increase in w. Under similar test conditions, the proposed surfaces demonstrate superior mechanical durability compared to two other prevalent wettability surface structures. The proposed surfaces, efficiently and eco-friendly produced through nanosecond laser fabrication, hold tremendous potential for diverse applications.