开发用于木材粘合的高性能环保型碳水化合物基粘合剂的新兴技术

IF 3.2 3区 材料科学 Q2 ENGINEERING, CHEMICAL International Journal of Adhesion and Adhesives Pub Date : 2024-07-22 DOI:10.1016/j.ijadhadh.2024.103801
Awaly Ilham Dewantoro , Muhammad Adly Rahandi Lubis , Desy Nurliasari , Efri Mardawati
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引用次数: 0

摘要

粘合剂市场主要由致癌且对环境有毒的石油基粘合剂供应,包括甲醛和异氰酸酯。环保意识促使人们开发木质素、蛋白质和碳水化合物等生物基粘合剂,以取代石油基粘合剂的广泛使用。碳水化合物或多糖是很有前景的材料,因为它们价格低廉,在自然界中含量丰富。因此,我们采用文献计量分析和系统综述的方法来讨论以碳水化合物为基础的粘合剂的最新发展。该方法从 Scopus 数据库中收集了 2005-2024 年期间的数据。研究了不同类型的碳水化合物,包括纤维素、半纤维素、淀粉、壳聚糖和糖,这些物质自 2014 年以来有了显著增长。虽然碳水化合物被广泛应用于胶合板、纸浆和纸、刨花板和木质复合材料,但由于其水溶性低、耐水性差,因此需要对其进行改性以改善其性能。化学改性包括交联、酯化和氧化,是最常用的方法。本文深入讨论了作为木材粘合剂原料的各类碳水化合物的发展情况。改性碳水化合物应与乙二醛、单宁、甲酸或柠檬酸等添加剂混合,以改善粘合性能,尤其是剪切强度、耐水性和固化(温度和时间方面)。此外,还概述了碳水化合物基粘合剂的未来发展,包括与食品供应和安全问题、碳足迹、循环经济实施和技术经济分析有关的材料替代。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Emerging technologies on developing high-performance and environmentally friendly carbohydrate-based adhesives for wood bonding

The adhesive market is predominantly supplied by carcinogenic and environmentally toxic petroleum-based adhesives including formaldehyde and isocyanate. Environmental awareness has led to the development of bio-based adhesives such as lignin, proteins, and carbohydrates to replace the extensive use of petroleum-based adhesives. Carbohydrates or polysaccharides are promising materials because they are inexpensive and abundant in nature. A bibliometric analysis and systematic review were then used to discuss the most recent developments in carbohydrate-based adhesives. Methodi Ordinatio has been applied to gathering data from the Scopus database for the period of 2005–2024. Different types of carbohydrates were examined, including cellulose, hemicellulose, starch, chitosan, and sugars, which have grown significantly since 2014. Although carbohydrates are extensively applied in plywood, pulp and paper, particleboard, and wood composites, they should be modified to improve their properties because of their low water solubility and poor water resistance. Chemical modification, which includes crosslinking, esterification, and oxidation, is the most commonly used method. The development of each type of carbohydrate as a raw material for wood adhesives is thoroughly discussed. Modified carbohydrates should be blended with additives, such as glyoxal, tannin, formic acid, or citric acid, to improve adhesion performance, especially shear strength, water resistance, and curing (in terms of temperature and time). The future development of carbohydrate-based adhesives has been outlined, including material substitutions related to food supply and security issues, carbon footprint, circular economy implementation, and techno-economic analysis.

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来源期刊
International Journal of Adhesion and Adhesives
International Journal of Adhesion and Adhesives 工程技术-材料科学:综合
CiteScore
6.90
自引率
8.80%
发文量
200
审稿时长
8.3 months
期刊介绍: The International Journal of Adhesion and Adhesives draws together the many aspects of the science and technology of adhesive materials, from fundamental research and development work to industrial applications. Subject areas covered include: interfacial interactions, surface chemistry, methods of testing, accumulation of test data on physical and mechanical properties, environmental effects, new adhesive materials, sealants, design of bonded joints, and manufacturing technology.
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