{"title":"利用 GeC 分子的 (2)3∏ - X3∏ 体系计算源的有效振动温度","authors":"R. Sindhan , N. Venkatesh Bharathi , S. Ramaswamy","doi":"10.1016/j.ascom.2024.100859","DOIUrl":null,"url":null,"abstract":"<div><p>In this work, the experimental potential energy curves for <span><math><mrow><msup><mrow><mo>(</mo><mn>2</mn><mo>)</mo></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle></mrow></math></span> and <span><math><mrow><msup><mrow><mi>X</mi></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle></mrow></math></span> electronic states of GeC molecule have been constructed by using Rydberg-Klein-Rees (RKR) method. The radiative transition parameters viz., Franck-Condon (FC) factor, r-centroid, electronic transition moment, band strength, relative band strength, Einstein coefficients, radiative lifetime and oscillator strength for the <span><math><mrow><msup><mrow><mo>(</mo><mn>2</mn><mo>)</mo></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle><mo>−</mo><msup><mrow><mi>X</mi></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle></mrow></math></span> system of GeC molecule have been estimated for the experimentally observed vibrational levels from Rydberg-Klein-Rees (RKR) potential and the estimated values are tabulated. The estimated effective vibrational temperature found as 5628 K for the <span><math><mrow><msup><mrow><mo>(</mo><mn>2</mn><mo>)</mo></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle><mo>−</mo><msup><mrow><mi>X</mi></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle></mrow></math></span> system of GeC molecule. The radiative transition parameters and effective vibrational temperature are evident that the possible presence of GeC molecule in solar and sunspots atmosphere. Further, these parameters are employed in rationalizations of astrochemical and astrophysical observations.</p></div>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"On the effective vibrational temperature of the source using (2)3∏ - X3∏ system of GeC molecule\",\"authors\":\"R. Sindhan , N. Venkatesh Bharathi , S. Ramaswamy\",\"doi\":\"10.1016/j.ascom.2024.100859\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this work, the experimental potential energy curves for <span><math><mrow><msup><mrow><mo>(</mo><mn>2</mn><mo>)</mo></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle></mrow></math></span> and <span><math><mrow><msup><mrow><mi>X</mi></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle></mrow></math></span> electronic states of GeC molecule have been constructed by using Rydberg-Klein-Rees (RKR) method. The radiative transition parameters viz., Franck-Condon (FC) factor, r-centroid, electronic transition moment, band strength, relative band strength, Einstein coefficients, radiative lifetime and oscillator strength for the <span><math><mrow><msup><mrow><mo>(</mo><mn>2</mn><mo>)</mo></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle><mo>−</mo><msup><mrow><mi>X</mi></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle></mrow></math></span> system of GeC molecule have been estimated for the experimentally observed vibrational levels from Rydberg-Klein-Rees (RKR) potential and the estimated values are tabulated. The estimated effective vibrational temperature found as 5628 K for the <span><math><mrow><msup><mrow><mo>(</mo><mn>2</mn><mo>)</mo></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle><mo>−</mo><msup><mrow><mi>X</mi></mrow><mn>3</mn></msup><mstyle><mi>Π</mi></mstyle></mrow></math></span> system of GeC molecule. The radiative transition parameters and effective vibrational temperature are evident that the possible presence of GeC molecule in solar and sunspots atmosphere. Further, these parameters are employed in rationalizations of astrochemical and astrophysical observations.</p></div>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S221313372400074X\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S221313372400074X","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
On the effective vibrational temperature of the source using (2)3∏ - X3∏ system of GeC molecule
In this work, the experimental potential energy curves for and electronic states of GeC molecule have been constructed by using Rydberg-Klein-Rees (RKR) method. The radiative transition parameters viz., Franck-Condon (FC) factor, r-centroid, electronic transition moment, band strength, relative band strength, Einstein coefficients, radiative lifetime and oscillator strength for the system of GeC molecule have been estimated for the experimentally observed vibrational levels from Rydberg-Klein-Rees (RKR) potential and the estimated values are tabulated. The estimated effective vibrational temperature found as 5628 K for the system of GeC molecule. The radiative transition parameters and effective vibrational temperature are evident that the possible presence of GeC molecule in solar and sunspots atmosphere. Further, these parameters are employed in rationalizations of astrochemical and astrophysical observations.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.