通过高压固溶体实现具有均匀腐蚀行为的高强度抗菌 Zn-4Ag-Mn 合金

IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Transactions of Nonferrous Metals Society of China Pub Date : 2024-07-01 DOI:10.1016/S1003-6326(24)66537-4
Kun-ning NIU , De-chuang ZHANG , Fu-gang QI , Jian-guo LIN , Yi-long DAI
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引用次数: 0

摘要

通过高压固溶(HPS)方法成功制备了 Zn-4Ag-Mn 合金,从而获得了高强度、抗菌且可均匀降解的植入材料。显微结构表征显示,高压固溶法处理 Zn-4Ag-Mn 合金后,晶粒细化了 57.9%,与铸造(AC)合金相比,第二相的平均尺寸减小到 10.2 μm。压缩、维氏硬度和磨损与摩擦测试表明,HPS 合金具有极高的机械性能,包括 333.5 兆帕的压缩屈服强度和 Hv 89.5 的维氏硬度。电化学腐蚀和浸泡腐蚀测试表明,HPS 处理优化了合金的耐腐蚀性能,并具有均匀腐蚀性。此外。经 HPS 处理的 Zn-4Ag-Mn 合金在抗菌测试中表现出优异的抗菌性能,抗菌率高达 71.6%。这些结果表明,经 HPS 处理的 Zn-4Ag-Mn 合金可被视为一种前景广阔的可生物降解植入材料。
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Achieving high strength and antibacterial Zn−4Ag−Mn alloy with homogenous corrosion behavior via high-pressure solid solution

Zn−4Ag−Mn alloy was successfully prepared by high-pressure solid solution (HPS) method to achieve high strength and antibacterial implant materials which can degrade uniformly. Microstructural characterization showed that HPS treatment on Zn−4Ag−Mn alloy resulted in 57.9% grain refinement, and the average size of the second phases was reduced to 10.2 μm compared with as-cast (AC) alloy. The compression, Vickers hardness and wear and friction tests showed particularly high mechanical properties of HPS alloys, including a compressive yield strength of 333.5 MPa and a Vickers hardness of Hv 89.5. Electrochemical corrosion, and immersion corrosion tests showed that HPS treatment optimized the corrosion resistance of the alloy with homogenous corrosion. Furthermore. The HPS-treated Zn−4Ag−Mn alloy exhibited excellent antibacterial properties through antibacterial testing, with an antibacterial rate of 71.6%. These results suggest that the HPS-treated Zn−4Ag−Mn alloy can be considered as a promising biodegradable implant material.

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来源期刊
CiteScore
7.40
自引率
17.80%
发文量
8456
审稿时长
3.6 months
期刊介绍: The Transactions of Nonferrous Metals Society of China (Trans. Nonferrous Met. Soc. China), founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, INSPEC, CA, METADEX, AJ and JICST.
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