Corrections to the Hamiltonian induced by finite-strength coupling to the environment

If a quantum system interacts with the environment, then the Hamiltonian acquires a correction known as the Lamb-shift term. There are two other corrections to the Hamiltonian, related to the stationary state. Namely, the stationary state is to first approximation a Gibbs state with respect to original Hamiltonian. However, if we have finite coupling, then the true stationary state will be different, and regarding it as a Gibbs state to some effective Hamiltonian, one can extract a correction, which is called “steady-state” correction. Alternatively, one can take a static point of view, and consider the reduced state of total equilibrium state, i.e., system plus bath Gibbs state. The extracted Hamiltonian correction is called the “mean-force” correction. This paper presents several analytical results on second-order corrections (in coupling strength) of the three types mentioned above. Instead of the steady state, we focus on a state annihilated by the Liouvillian of the master equation, labeling it as the “quasi-steady state.” Specifically, we derive a general formula for the mean-force correction as well as the quasi-steady state and Lamb-shift correction for a general class of master equations. Furthermore, specific formulas for corrections are obtained for the Davies, Bloch-Redfield, and cumulant equation (refined weak coupling). In particular, the cumulant equation serves as a case study of the Liouvillian, featuring a nontrivial fourth-order generator. This generator forms the basis for calculating the diagonal quasi-steady-state correction. We consider spin-boson model as an example, and in addition to using our formulas for corrections, we consider mean-force correction from reaction-coordinate approach.