Oleg A. Kononenko, Vitaly V. Milyutin, Victor O. Kaptakov, Vadim I. Makarenkov, Evgeny A. Kozlitin
{"title":"基于氧化锰的颗粒吸附剂用于去除受放射性污染的天然水中的锶放射性核素","authors":"Oleg A. Kononenko, Vitaly V. Milyutin, Victor O. Kaptakov, Vadim I. Makarenkov, Evgeny A. Kozlitin","doi":"10.1007/s10967-024-09672-7","DOIUrl":null,"url":null,"abstract":"<div><p>A granular manganese oxide-based sorbent was synthesized. One volume of the sorbent decontaminates 125–145 volumes of hardness water from strontium radionuclides to background values of radioactivity. The synthesis includes interaction of MnSO<sub>4</sub> with KMnO<sub>4</sub> in aqueous medium at [Mn<sup>2+</sup>]/[MnO<sub>4</sub><sup>−</sup>] = 1.8, followed by the precipitation, aging the precipitate at pH = 11, and calcining it at 160 °C. Characteristics of the sorbent obtained were as follows: the distribution coefficient of the tracer <sup>85</sup>Sr radionuclide in 0.01 mol dm<sup>−3</sup> CaCl<sub>2</sub> solution of 1.6 × 10<sup>4</sup> cm<sup>3</sup> g<sup>−1</sup>, the batch capacity by Ca<sup>2+</sup> of 1.10 mol g<sup>−1</sup>, and the Sr/Ca pair separation coefficient of 65.</p></div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":"333 10","pages":"4889 - 4897"},"PeriodicalIF":1.5000,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Manganese oxide-based granular sorbent for the removal of strontium radionuclides from radioactively contaminated natural water\",\"authors\":\"Oleg A. Kononenko, Vitaly V. Milyutin, Victor O. Kaptakov, Vadim I. Makarenkov, Evgeny A. Kozlitin\",\"doi\":\"10.1007/s10967-024-09672-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A granular manganese oxide-based sorbent was synthesized. One volume of the sorbent decontaminates 125–145 volumes of hardness water from strontium radionuclides to background values of radioactivity. The synthesis includes interaction of MnSO<sub>4</sub> with KMnO<sub>4</sub> in aqueous medium at [Mn<sup>2+</sup>]/[MnO<sub>4</sub><sup>−</sup>] = 1.8, followed by the precipitation, aging the precipitate at pH = 11, and calcining it at 160 °C. Characteristics of the sorbent obtained were as follows: the distribution coefficient of the tracer <sup>85</sup>Sr radionuclide in 0.01 mol dm<sup>−3</sup> CaCl<sub>2</sub> solution of 1.6 × 10<sup>4</sup> cm<sup>3</sup> g<sup>−1</sup>, the batch capacity by Ca<sup>2+</sup> of 1.10 mol g<sup>−1</sup>, and the Sr/Ca pair separation coefficient of 65.</p></div>\",\"PeriodicalId\":661,\"journal\":{\"name\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"volume\":\"333 10\",\"pages\":\"4889 - 4897\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-07-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10967-024-09672-7\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Radioanalytical and Nuclear Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10967-024-09672-7","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Manganese oxide-based granular sorbent for the removal of strontium radionuclides from radioactively contaminated natural water
A granular manganese oxide-based sorbent was synthesized. One volume of the sorbent decontaminates 125–145 volumes of hardness water from strontium radionuclides to background values of radioactivity. The synthesis includes interaction of MnSO4 with KMnO4 in aqueous medium at [Mn2+]/[MnO4−] = 1.8, followed by the precipitation, aging the precipitate at pH = 11, and calcining it at 160 °C. Characteristics of the sorbent obtained were as follows: the distribution coefficient of the tracer 85Sr radionuclide in 0.01 mol dm−3 CaCl2 solution of 1.6 × 104 cm3 g−1, the batch capacity by Ca2+ of 1.10 mol g−1, and the Sr/Ca pair separation coefficient of 65.
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An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.
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