Anderson M.B. Silva , Daniel S. Rodrigues , Beatriz D.O. Guedes , Iury S. Silveira , Patrícia L. Antonio , Danilo O. Junot , Linda V.E. Caldas , Divanizia N. Souza
{"title":"探索慢速蒸发路线合成的 CaSO4:Tb、CaSO4:Mn 和 CaSO4:Mn,Tb 磷光体的发光特性和剂量测定特征","authors":"Anderson M.B. Silva , Daniel S. Rodrigues , Beatriz D.O. Guedes , Iury S. Silveira , Patrícia L. Antonio , Danilo O. Junot , Linda V.E. Caldas , Divanizia N. Souza","doi":"10.1016/j.radmeas.2024.107261","DOIUrl":null,"url":null,"abstract":"<div><p>This work aimed to investigate and compare the luminescence properties of CaSO<sub>4</sub>:Tb, CaSO<sub>4</sub>:Mn, and CaSO<sub>4</sub>:Mn,Tb synthesized by slow evaporation route. The crystalline structure, morphology, and optical properties of the phosphors were characterized by X-ray diffraction analysis (XRD), photoluminescence (PL), radioluminescence (RL), and scanning electron microscopy (SEM). In addition, thermoluminescence (TL) and optically stimulated luminescence (OSL) were used to comprehensively investigate the dosimetric properties of the phosphors, such as the TL glow curve and continuous wave OSL (CW-OSL) curves, dose-response and its reproducibility, fading, and sensitivity. For dosimetric analyses, the samples were irradiated with beta radiation. PL and RL emission spectra confirmed the presence of Tb<sup>3+</sup> and Mn<sup>2+</sup> ions in crystalline matrices. The samples showed a typical exponential OSL decay curve, indicating that the charge traps have a high photoionization cross-section for blue LEDs. The synthesized pellets exhibited good luminescent and dosimetric properties, with linear luminescent response over a wide dose range (169 mGy–100 Gy) and reproducibility of both OSL and TL signals. Furthermore, the incorporation of terbium as a co-dopant in the CaSO<sub>4</sub>:Mn matrix reduced its fading from 75% to only 17%. The phosphors had high TL and OSL sensitivities in comparison to some commercially available dosimeters.</p></div>","PeriodicalId":21055,"journal":{"name":"Radiation Measurements","volume":null,"pages":null},"PeriodicalIF":1.6000,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Exploring the luminescence properties and dosimetric characteristics of CaSO4:Tb, CaSO4:Mn, and CaSO4:Mn,Tb phosphors synthesized by slow evaporation route\",\"authors\":\"Anderson M.B. Silva , Daniel S. Rodrigues , Beatriz D.O. Guedes , Iury S. Silveira , Patrícia L. Antonio , Danilo O. Junot , Linda V.E. Caldas , Divanizia N. Souza\",\"doi\":\"10.1016/j.radmeas.2024.107261\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This work aimed to investigate and compare the luminescence properties of CaSO<sub>4</sub>:Tb, CaSO<sub>4</sub>:Mn, and CaSO<sub>4</sub>:Mn,Tb synthesized by slow evaporation route. The crystalline structure, morphology, and optical properties of the phosphors were characterized by X-ray diffraction analysis (XRD), photoluminescence (PL), radioluminescence (RL), and scanning electron microscopy (SEM). In addition, thermoluminescence (TL) and optically stimulated luminescence (OSL) were used to comprehensively investigate the dosimetric properties of the phosphors, such as the TL glow curve and continuous wave OSL (CW-OSL) curves, dose-response and its reproducibility, fading, and sensitivity. For dosimetric analyses, the samples were irradiated with beta radiation. PL and RL emission spectra confirmed the presence of Tb<sup>3+</sup> and Mn<sup>2+</sup> ions in crystalline matrices. The samples showed a typical exponential OSL decay curve, indicating that the charge traps have a high photoionization cross-section for blue LEDs. The synthesized pellets exhibited good luminescent and dosimetric properties, with linear luminescent response over a wide dose range (169 mGy–100 Gy) and reproducibility of both OSL and TL signals. Furthermore, the incorporation of terbium as a co-dopant in the CaSO<sub>4</sub>:Mn matrix reduced its fading from 75% to only 17%. The phosphors had high TL and OSL sensitivities in comparison to some commercially available dosimeters.</p></div>\",\"PeriodicalId\":21055,\"journal\":{\"name\":\"Radiation Measurements\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2024-07-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiation Measurements\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1350448724002099\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"NUCLEAR SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiation Measurements","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1350448724002099","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"NUCLEAR SCIENCE & TECHNOLOGY","Score":null,"Total":0}
Exploring the luminescence properties and dosimetric characteristics of CaSO4:Tb, CaSO4:Mn, and CaSO4:Mn,Tb phosphors synthesized by slow evaporation route
This work aimed to investigate and compare the luminescence properties of CaSO4:Tb, CaSO4:Mn, and CaSO4:Mn,Tb synthesized by slow evaporation route. The crystalline structure, morphology, and optical properties of the phosphors were characterized by X-ray diffraction analysis (XRD), photoluminescence (PL), radioluminescence (RL), and scanning electron microscopy (SEM). In addition, thermoluminescence (TL) and optically stimulated luminescence (OSL) were used to comprehensively investigate the dosimetric properties of the phosphors, such as the TL glow curve and continuous wave OSL (CW-OSL) curves, dose-response and its reproducibility, fading, and sensitivity. For dosimetric analyses, the samples were irradiated with beta radiation. PL and RL emission spectra confirmed the presence of Tb3+ and Mn2+ ions in crystalline matrices. The samples showed a typical exponential OSL decay curve, indicating that the charge traps have a high photoionization cross-section for blue LEDs. The synthesized pellets exhibited good luminescent and dosimetric properties, with linear luminescent response over a wide dose range (169 mGy–100 Gy) and reproducibility of both OSL and TL signals. Furthermore, the incorporation of terbium as a co-dopant in the CaSO4:Mn matrix reduced its fading from 75% to only 17%. The phosphors had high TL and OSL sensitivities in comparison to some commercially available dosimeters.
期刊介绍：
The journal seeks to publish papers that present advances in the following areas: spontaneous and stimulated luminescence (including scintillating materials, thermoluminescence, and optically stimulated luminescence); electron spin resonance of natural and synthetic materials; the physics, design and performance of radiation measurements (including computational modelling such as electronic transport simulations); the novel basic aspects of radiation measurement in medical physics. Studies of energy-transfer phenomena, track physics and microdosimetry are also of interest to the journal.
Applications relevant to the journal, particularly where they present novel detection techniques, novel analytical approaches or novel materials, include: personal dosimetry (including dosimetric quantities, active/electronic and passive monitoring techniques for photon, neutron and charged-particle exposures); environmental dosimetry (including methodological advances and predictive models related to radon, but generally excluding local survey results of radon where the main aim is to establish the radiation risk to populations); cosmic and high-energy radiation measurements (including dosimetry, space radiation effects, and single event upsets); dosimetry-based archaeological and Quaternary dating; dosimetry-based approaches to thermochronometry; accident and retrospective dosimetry (including activation detectors), and dosimetry and measurements related to medical applications.
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