Water Generation on the Moon from Solar Wind and Meteoroid Impacts

The kinetics of water formation on the lunar surface from impact-driven melts (IM) of meteoroids and recombinative desorption (RD) of solar-wind-implanted regolith grains is assessed. The ratio of water generated from RD:IM is ultimately controlled by the diffusion constant of the implanted defects. Higher diffusion activation energies of hydroxyls (-OH) result in more trapping of the implanted defects and, consequently, higher water production from IM versus RD. At diffusion activation energies >1 eV, water production from RD is negligible and IM is the dominant channel. Our results suggest that RD can be associated with the observed latitude and diurnal dependence but RD and/or micrometeorite IM are not major contributors to the water ice observed within the permanently shadowed regions (PSRs). This suggests that volcanic and/or delivery via large impactors are the more likely major sources of water on the Moon. However, our model generally agrees with the observed latitudinal dependence of the inferred OH/H2O and the overall diurnal trend from orbital observations in the infrared. In addition, our results also suggest that micrometeorites are responsible for the high content of molecular water in the glass of regolith grains.