{"title":"基于综合实验和理论计算的 β-环糊精/石墨烯的 Co2+ 吸附特性研究","authors":"Ping Bao, Xiaowei Wang, Jinfeng Men, Zhilin Hu","doi":"10.1007/s10967-024-09668-3","DOIUrl":null,"url":null,"abstract":"<div><p>In order to effectively remove Co<sup>2+</sup> from radioactive wastewater, β-cyclodextrin/graphene oxide (β-CD/GO) was synthesized. The factors affecting the adsorption of Co<sup>2+</sup>in water were determined by static adsorption experiments, and the synthesis and adsorption mechanism of the materials were discussed by using Density Functional Theory (DFT). The results show that β-CD and GO are mainly bonded by ester group and hydrogen bond, the adsorption of Co<sup>2+</sup> by β-CD/GO belongs to single molecular layer chemisorption, and the intramolecular diffusion is the main factor of affecting the adsorption rate. The adsorption capacity of Co<sup>2+</sup> can reach 95.83 mg/g under appropriate conditions, but it will be affected by interference ions.</p></div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":"333 9","pages":"4543 - 4558"},"PeriodicalIF":1.5000,"publicationDate":"2024-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on Co2+ adsorption properties of β-cyclodextrin/graphene based on comprehensive experiments and theoretical calculation\",\"authors\":\"Ping Bao, Xiaowei Wang, Jinfeng Men, Zhilin Hu\",\"doi\":\"10.1007/s10967-024-09668-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In order to effectively remove Co<sup>2+</sup> from radioactive wastewater, β-cyclodextrin/graphene oxide (β-CD/GO) was synthesized. The factors affecting the adsorption of Co<sup>2+</sup>in water were determined by static adsorption experiments, and the synthesis and adsorption mechanism of the materials were discussed by using Density Functional Theory (DFT). The results show that β-CD and GO are mainly bonded by ester group and hydrogen bond, the adsorption of Co<sup>2+</sup> by β-CD/GO belongs to single molecular layer chemisorption, and the intramolecular diffusion is the main factor of affecting the adsorption rate. The adsorption capacity of Co<sup>2+</sup> can reach 95.83 mg/g under appropriate conditions, but it will be affected by interference ions.</p></div>\",\"PeriodicalId\":661,\"journal\":{\"name\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"volume\":\"333 9\",\"pages\":\"4543 - 4558\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-08-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10967-024-09668-3\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Radioanalytical and Nuclear Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10967-024-09668-3","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Study on Co2+ adsorption properties of β-cyclodextrin/graphene based on comprehensive experiments and theoretical calculation
In order to effectively remove Co2+ from radioactive wastewater, β-cyclodextrin/graphene oxide (β-CD/GO) was synthesized. The factors affecting the adsorption of Co2+in water were determined by static adsorption experiments, and the synthesis and adsorption mechanism of the materials were discussed by using Density Functional Theory (DFT). The results show that β-CD and GO are mainly bonded by ester group and hydrogen bond, the adsorption of Co2+ by β-CD/GO belongs to single molecular layer chemisorption, and the intramolecular diffusion is the main factor of affecting the adsorption rate. The adsorption capacity of Co2+ can reach 95.83 mg/g under appropriate conditions, but it will be affected by interference ions.
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An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.
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