通过火焰热喷涂探索陶瓷基系统的结构和物理特性

Eximia Pub Date : 2024-08-10 DOI:10.47577/eximia.v13i1.497
Farah S. Khasrw, Aya N. Abdullah, Salih Y. Darweesh
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摘要

火焰热喷涂是一种重要的表面处理技术,适用于包括发电厂涡轮叶片、桥梁和输油管道在内的许多受到外部腐蚀的材料。因此,以氧化铝 Al2O3 为代表的陶瓷材料被用作基体材料,并以 5%, 10%, 15%, 20%, 25%Wt.形成金属陶瓷合金。考虑到铜的浓度,将两种粉末混合,并将混合物放入火焰热喷涂装置的坩埚中。乙炔气体比率固定为 0.7 巴,氧气比率为 4 巴,这是获得的最佳混合比率。喷涂过程在尺寸为 20mm×5mm 的圆形停用涡轮叶片基座上进行。完成涂层工艺后,样品在 1100°C 的热烘箱中烧结仅一个半小时。对样品进行扫描电子显微镜(SEM)检查后发现,加入铜后,样品的结构变得规整、均匀,并且发现金属的最佳强化比例为 25%Wt。烧结后还发现,平均晶粒大小约为 109nm。此外,还进行了 EDX 光谱分析,以显示氧化铝和铜的混合材料。此外,还对一些机械性能进行了检测,结果表明,烧结后的最佳混合比例为(75%Wt.Al2O3-25%Wt.Cu),在此比例下,显微维氏硬度为(605 kg/mm2),计算得出的磨损率最低(1.84×10-6g/cm)。计算了有涂层和无涂层样品的粘合强度,发现最佳机械粘合强度为(53 兆帕)。在计算了真实孔隙率和吸水率后发现,在最低加固比(25%Wt.
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Exploration of Structural and Physical Characteristics of a Ceramic-Based System via Flame Thermal Spraying
Flame thermal spraying is an important technique in surface treatment of many materials exposed to external corrosion, including turbine blades in power plants, bridges, and oil pipelines. Therefore, a ceramic material represented by aluminum oxide Al2O3 was used as a base material and copper metal Cu was added at different reinforcement ratios of 5%, 10%, 15%, 20%, 25%Wt. To form a cermet alloy. The two powders were mixed after taking into account the copper concentrations, and the mixture was placed in the flame thermal spraying device crucible. The acetylene gas ratio was fixed at 0.7 bar and oxygen at 4 bar as the best mixing ratios obtained. The coating process was carried out on out-of-service turbine blade bases with dimensions of 20mm×5mm in a circular shape. After completing the coating process, the samples were sintered in a thermal oven at 1100°C for only one and a half hours. The scanning electron microscope (SEM) of the samples was examined and it was found that by adding copper we get a regular and homogeneous structure, and it was found that the best reinforcement with metal is 25%Wt. After sintering, it was also found that the average grain size is approximately 109nm. An EDX spectroscopy was also conducted to show the materials that were mixed for both alumina and copper. Some mechanical properties were also examined which showed that the best mixing ratio is (75%Wt.Al2O3-25%Wt.Cu) after sintering, at which the micro-Vickers hardness was found to be (605 kg/mm2), and the wear rate was calculated which gave the lowest value (1.84×10-6g/cm). While the adhesive strength was calculated for a coated and uncoated sample to find that the best mechanical adhesive strength is (53 MPa). The true porosity and water absorption were calculated to give the lowest values at the lowest reinforcement ratio which is 25%Wt.
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