玻璃纤维增强聚碳酸酯/丙烯腈-丁二烯-苯乙烯复合材料的紫外线和户外风化以及老化复合材料的回收利用

IF 3.6 4区 材料科学 Q2 MATERIALS SCIENCE, COMPOSITES Journal of Thermoplastic Composite Materials Pub Date : 2024-08-09 DOI:10.1177/08927057241270890
E. Kuram, B. Ozcelik, H. Koçoğlu, Hamza Ayas, Mehmet Dogan
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引用次数: 0

摘要

聚合材料的用量在不断增加,它们在整个生命周期中都会受到温度、光、水等因素的影响。聚合物用量的增加导致了废物问题。从环保角度来看,聚合物的回收(再加工)是减少废物问题的可行解决方案之一。因此,在这项研究中,我们测定了不同玻璃纤维含量的老化玻璃纤维增强聚碳酸酯/丙烯腈-丁二烯-苯乙烯(PC/ABS)复合材料的再加工对其机械性能(拉伸、冲击、弯曲)、熔融流动指数和形态的影响。原始玻璃纤维增强 PC/ABS 试样暴露在两种环境中,即 2018 年 1 月至 2019 年 1 月期间在 QUV 试验室中进行长达 336 小时的人工加速老化,以及在盖布泽(土耳其)进行长达 1 年的自然老化,以确定长期户外暴露对性能的影响。经过这些老化步骤后,自然老化和紫外线老化的试样被磨碎,磨碎的试样按 25%、50% 和 75% 的重量比与原玻璃纤维增强 PC/ABS 混合。混合后的材料被重新成型,制成测试试样,然后进行表征。简而言之,在当前的研究中,研究了原生、室外老化 12 个月、紫外线室老化 336 小时以及原生老化玻璃纤维增强 PC/ABS 复合材料混合物的机械、流变和形态特性。由于目前还没有关于不同玻璃纤维含量的 PC/ABS 的自然老化和紫外线老化的研究,因此本研究对确定这些复合材料老化后的行为做出了重要贡献。实验研究发现,一般来说,机械性能会随着自然老化和紫外线老化而降低,但加入纯聚合物后,性能会得到一定程度的保留。
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UV and outdoor weathering of glass fiber reinforced polycarbonate/acrylonitrile-butadiene-styrene composites and recycling of aged composites
Polymeric materials usage is rising, and they are exposed to some effects such as temperature, light, water throughout their lifetime. Increase in use of polymer has led to waste problems. From an environmental point of view, recycling (reprocessing) of polymers is one of the viable solutions to diminish waste issues. Thus, in this work, the effect of reprocessing for aged glass fiber reinforced polycarbonate/acrylonitrile-butadiene-styrene (PC/ABS) composites having different glass fiber content was determined on the mechanical properties (tensile, impact, flexural), melt flow index and morphology. Virgin glass fiber reinforced PC/ABS specimens were exposed to two environments, namely artificial accelerated ageing in a QUV chamber for up to 336 h and natural ageing in Gebze (Turkey) for up to 1 year between January 2018 and January 2019 to determine the influence of a long-term outdoor exposure on the properties. After these ageing steps, naturally and UV aged specimens were ground and the ground specimens were mixed with virgin glass fiber reinforced PC/ABS at ratios of 25%, 50% and 75% by weight. The mixed materials were re-molded to fabricate test specimens and then characterized. In brief, in current research, the mechanical, rheological, and morphological properties of virgin, aged in outdoors for 12 months, aged in UV chamber for 336 h and blends of virgin-aged glass fiber reinforced PC/ABS composites were studied. Because there is no research regarding natural and UV ageing of PC/ABS having different glass fiber content, this study represents an important contribution to determining behavior of these composites after ageing. From experimental study, in general, it was found that mechanical properties decreased with natural and UV ageing, but some retention in properties could be achieved with the incorporation of pure polymer.
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来源期刊
Journal of Thermoplastic Composite Materials
Journal of Thermoplastic Composite Materials 工程技术-材料科学:复合
CiteScore
8.00
自引率
18.20%
发文量
104
审稿时长
5.9 months
期刊介绍: The Journal of Thermoplastic Composite Materials is a fully peer-reviewed international journal that publishes original research and review articles on polymers, nanocomposites, and particulate-, discontinuous-, and continuous-fiber-reinforced materials in the areas of processing, materials science, mechanics, durability, design, non destructive evaluation and manufacturing science. This journal is a member of the Committee on Publication Ethics (COPE).
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