偏置电压对 Ar/CH2F2/O2 等离子刻蚀 Si3N4 薄膜的影响

Shuichi Kuboi, Junji Kataoka, Daiki Iino, Kazuaki Kurihara, Hirotaka Toyoda, Hiroyuki Fukumizu
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摘要

研究了氮化硅(Si3N4)薄膜在 Ar/CH2F2/O2 混合气体等离子体中进行高宽比蚀刻过程时,峰峰偏置电压(V pp)对其蚀刻机理的影响。结果表明,随着 V pp 的增加,Si3N4 薄膜的蚀刻速率最初会降低到 3630 V,但超过这一阈值后又会增加。这种不寻常的蚀刻行为可归因于 Si3N4 薄膜表面形成了改性层。研究发现,改性层的厚度和原子成分等特征受离子能量和工艺条件中气体化学成分的影响很大。
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Influence of bias voltage on the Ar/CH2F2/O2 plasma etching of Si3N4 films
The etching mechanism of silicon nitride (Si3N4) film depending on peak-to-peak bias voltage (V pp) in Ar/CH2F2/O2 gas-mixture plasmas for high-aspect-ratio etching process was investigated. It was observed that the Si3N4-film etch rate initially decreased with increase in the V pp up to 3630 V, but then increased beyond this threshold. This unusual etching behavior can be attributed to the formation of a modified layer on the surface of the Si3N4 film. The characteristics of the modified layer, such as thickness and atomic composition, were found to be strongly influenced by the ion energy and gas chemistry of the process conditions.
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