通过一锅三组份反应合成二硫代氨基甲酸酯官能化脂肪族磺酰氟

IF 2.8 4区化学 Q1 CHEMISTRY, ORGANIC Asian Journal of Organic Chemistry Pub Date : 2024-08-08 DOI:10.1002/ajoc.202400269

Heba H. Mohamedy, Eman Fayad, Hanadi A. Katouah, Hua-Li Qin

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引用次数: 0

摘要

通过无催化剂的一锅反应合成一类新型脂肪族磺酰氟的方法既环保又高效。新方法通过将胺、二硫化碳和乙烯磺酰氟结合在一起，简化了 N-（取代）-2-（氟磺酰基）二硫代氨基甲酸乙酯的合成过程。在温和的条件下，合成的化合物产率很高，使该反应成为探索新化学转化的重要工具。

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Synthesis of Dithiocarbamate-Functionalized Aliphatic Sulfonyl Fluoride via a One-Pot Three-Component Reaction

An eco-friendly and efficient method was developed for synthesizing a novel class of aliphatic sulfonyl fluorides in a catalyst-free one-pot reaction. The new approach offers a streamlined synthesis for N-(Substituted)-2-(fluorosulfonyl) ethyl carbamodithioates by combining amines, carbon disulfide, with ethenesulfonyl fluoride. The synthesized compounds were obtained in good yields under mild conditions, making this reaction a valuable tool for exploring new chemical transformations.

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来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.