1,4-二羧酸在 Cu(110) 上的立体化学：军士与士兵、表面爆炸和手性重构

IF 2.1 4区化学 Q3 CHEMISTRY, PHYSICAL Surface Science Pub Date : 2024-08-02 DOI:10.1016/j.susc.2024.122569

Karl-Heinz Ernst

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引用次数: 0

摘要

在金属表面手性识别的研究中，包括酒石酸在内的二羧酸与氨基酸一起发挥了至关重要的作用。在过去的二十年里，人们对表面立体化学有了更深入的了解，尤其是在铜(110)表面。本综述探讨了在 1,4-二羧酸与 Cu(110) 表面相互作用过程中观察到的各种现象。我们探讨了手性表面重构、分子间手性识别、立体选择性自催化分解以及通过掺杂打破手性对称等多个方面。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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The stereochemistry of 1,4-dicarboxylic acids on Cu(110): Sergeants & soldiers, surface explosions and chiral reconstructions

Dicarboxylic acids, including tartaric acid, have played a crucial role alongside amino acids in the study of chiral recognition on metal surfaces. Over the past two decades, significant insights into surface stereochemistry have emerged, particularly on Cu(110). This review examines various phenomena observed during the interaction of 1,4-dicarboxylic acids with the Cu(110) surface. We explore diverse aspects such as chiral surface reconstructions, intermolecular chiral recognition, stereoselective autocatalytic decomposition, and chiral symmetry breaking through doping.

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来源期刊

Surface Science 化学-物理：凝聚态物理

CiteScore

3.30

自引率

5.30%

发文量

137

审稿时长

25 days

期刊介绍： Surface Science is devoted to elucidating the fundamental aspects of chemistry and physics occurring at a wide range of surfaces and interfaces and to disseminating this knowledge fast. The journal welcomes a broad spectrum of topics, including but not limited to: • model systems (e.g. in Ultra High Vacuum) under well-controlled reactive conditions • nanoscale science and engineering, including manipulation of matter at the atomic/molecular scale and assembly phenomena • reactivity of surfaces as related to various applied areas including heterogeneous catalysis, chemistry at electrified interfaces, and semiconductors functionalization • phenomena at interfaces relevant to energy storage and conversion, and fuels production and utilization • surface reactivity for environmental protection and pollution remediation • interactions at surfaces of soft matter, including polymers and biomaterials. Both experimental and theoretical work, including modeling, is within the scope of the journal. Work published in Surface Science reaches a wide readership, from chemistry and physics to biology and materials science and engineering, providing an excellent forum for cross-fertilization of ideas and broad dissemination of scientific discoveries.