含有热激活破碎拆除残渣(TCDR)的砂浆的微结构行为

Karine Miranda de Souza Tavares, Natália Tavares Gomes, Gustavo de Castro Xavier, Sidnei José Gomes Sousa, Afonso Rangel Garcez de Azevedo, Carlos Maurício Fontes Vieira, Jonas Alexandre, Sérgio Neves Monteiro
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摘要

建筑行业一直在不断扩大,因此消耗了大量的天然原材料,并产生了大量废物。针对这种情况,本研究提出了建筑和拆除废料(CDW)的再利用方案,尤其是用于制作灰泥的石膏废料。残渣在 650 °C 的温度下经过 2 小时的热激活,加热速度为 10 °C/分钟,然后在颚式破碎机中破碎,并通过 ABNT N° 16 筛。灰泥的质量比(水泥:沙子)为 1:6,沙子部分由残渣代替,比例为 0、10、20 和 30%,使用普通硅酸盐水泥(OPC)。对稠度指数、质量密度、含气量、等温量热、保水性、硬化状态下的质量密度、抗弯强度、抗压强度、吸水率和空隙指数进行了测试、此外,还采用了各种测试技术,如激光粒度仪、采用改良查佩尔法和鲁山法的水胶活性、X 射线荧光 (XRF)、X 射线衍射 (XRD)、扫描电子显微镜 (SEM) 以及汞渗入孔隙度法 (MIP)。通过 X 射线衍射(XRD)和量热试验证明的较小颗粒的异质成核,可以观察到残留物具有无定形相,这有助于提高机械强度。结果表明,添加 30% 替代物的混合物机械强度提高幅度更大,吸收率更低,孔径分布也随之减小。
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Microstructural behavior of mortars containing thermo-activated crushed demolition residue (TCDR)
The construction industry has been constantly expanding and is, consequently responsible for a high consumption volume of natural raw materials and for generating large amounts of waste. In detriment of this scenario, this research proposes the reuse of Construction and Demolition Waste (CDW), especially that from plaster for making mortars. The residue was thermo-activated at 650 °C for a period of 2h, a heating rate of 10 °C/min, it was crushed in a jaw crusher and passed through an ABNT N° 16 sieve. The mortars were prepared with a (cement:sand) ratio of 1:6 by mass, the sand was partially replaced by the residue in proportions of 0, 10, 20 and 30%, using Ordinary Portland Cement (OPC). Tests were carried out on consistency index, mass density, incorporated air content, isothermal calorimetry, water retention, mass density in the hardened state, flexural strength, compressive strength, water absorption and void index, in addition to testing techniques characterization, such as laser granulometry, pozzolanic activity using the Modified Chapelle method and Lúxan method, X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) as well as Mercury Intrusion Porosimetry (MIP). It was possible to observe that the residue has amorphous phases, through XRD and heterogeneous nucleation of smaller particles, proven by the calorimetry test, contributing to the increase in mechanical strength. The results indicate that the mixture with 30% replacement achieved a greater increase in mechanical strength, lower absorption rates and consequently, a reduction in the distribution of pore sizes.
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