{"title":"不同热解温度下热解大豆秸秆制备生物炭用于废水除镉及热解气体研究","authors":"Chao Lv , Peng Liu , Song Cheng","doi":"10.1016/j.arabjc.2024.105946","DOIUrl":null,"url":null,"abstract":"<div><p>The Cd<sup>2+</sup> adsorption performance of biochar derived from soybean straw pyrolysis at 400–600 °C is investigated. Langmuir model can accurately describe the Cd<sup>2+</sup> adsorption data with adsorption amount of 47.30 mg/g with pH=5. Cd<sup>2+</sup> adsorption kinetic process could be analyzed using Pseudo-second-order. Biochar has large Cd<sup>2+</sup> wastewater treatment volume, based on column adsorption experiment. The π-electrons play an important role in Cd<sup>2+</sup> adsorption, based on adsorption mechanism analysis. Biochar has good stability after three cycles. Biochar also has good application potential used in lithium ion battery anode with specific capacity of 132 mA g<sup>−1</sup>. Besides, pyrolysis gas is recycled in the preparation process of biochar with heating value of the 12.10 MJ/Nm<sup>3</sup>. These results indicate that soybean straw waste is converted into sustainable adsorbent for Cd<sup>2+</sup> wastewater treatment.</p></div>","PeriodicalId":249,"journal":{"name":"Arabian Journal of Chemistry","volume":"17 9","pages":"Article 105946"},"PeriodicalIF":5.3000,"publicationDate":"2024-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1878535224003484/pdfft?md5=86eeeb37b6f7cc4db9ff0d2c9a2dd424&pid=1-s2.0-S1878535224003484-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Preparation of biochar from pyrolysis of soybean straw at different pyrolysis temperature for cadmium removal from wastewater and pyrolysis gas investigation\",\"authors\":\"Chao Lv , Peng Liu , Song Cheng\",\"doi\":\"10.1016/j.arabjc.2024.105946\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Cd<sup>2+</sup> adsorption performance of biochar derived from soybean straw pyrolysis at 400–600 °C is investigated. Langmuir model can accurately describe the Cd<sup>2+</sup> adsorption data with adsorption amount of 47.30 mg/g with pH=5. Cd<sup>2+</sup> adsorption kinetic process could be analyzed using Pseudo-second-order. Biochar has large Cd<sup>2+</sup> wastewater treatment volume, based on column adsorption experiment. The π-electrons play an important role in Cd<sup>2+</sup> adsorption, based on adsorption mechanism analysis. Biochar has good stability after three cycles. Biochar also has good application potential used in lithium ion battery anode with specific capacity of 132 mA g<sup>−1</sup>. Besides, pyrolysis gas is recycled in the preparation process of biochar with heating value of the 12.10 MJ/Nm<sup>3</sup>. These results indicate that soybean straw waste is converted into sustainable adsorbent for Cd<sup>2+</sup> wastewater treatment.</p></div>\",\"PeriodicalId\":249,\"journal\":{\"name\":\"Arabian Journal of Chemistry\",\"volume\":\"17 9\",\"pages\":\"Article 105946\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2024-08-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1878535224003484/pdfft?md5=86eeeb37b6f7cc4db9ff0d2c9a2dd424&pid=1-s2.0-S1878535224003484-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Arabian Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1878535224003484\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Arabian Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1878535224003484","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Preparation of biochar from pyrolysis of soybean straw at different pyrolysis temperature for cadmium removal from wastewater and pyrolysis gas investigation
The Cd2+ adsorption performance of biochar derived from soybean straw pyrolysis at 400–600 °C is investigated. Langmuir model can accurately describe the Cd2+ adsorption data with adsorption amount of 47.30 mg/g with pH=5. Cd2+ adsorption kinetic process could be analyzed using Pseudo-second-order. Biochar has large Cd2+ wastewater treatment volume, based on column adsorption experiment. The π-electrons play an important role in Cd2+ adsorption, based on adsorption mechanism analysis. Biochar has good stability after three cycles. Biochar also has good application potential used in lithium ion battery anode with specific capacity of 132 mA g−1. Besides, pyrolysis gas is recycled in the preparation process of biochar with heating value of the 12.10 MJ/Nm3. These results indicate that soybean straw waste is converted into sustainable adsorbent for Cd2+ wastewater treatment.
期刊介绍:
The Arabian Journal of Chemistry is an English language, peer-reviewed scholarly publication in the area of chemistry. The Arabian Journal of Chemistry publishes original papers, reviews and short reports on, but not limited to: inorganic, physical, organic, analytical and biochemistry.
The Arabian Journal of Chemistry is issued by the Arab Union of Chemists and is published by King Saud University together with the Saudi Chemical Society in collaboration with Elsevier and is edited by an international group of eminent researchers.