Yasha Tayal, Rupesh A. Talewar, Sk. Mahamuda, Kartika Maheshwari, Sheetal Kumari, Mohit Kumar, Ravita Pilania, Aman Prasad, A. S. Rao
{"title":"掺杂钕3+的硼硅玻璃在近红外范围内的增强发射,用于激光应用","authors":"Yasha Tayal, Rupesh A. Talewar, Sk. Mahamuda, Kartika Maheshwari, Sheetal Kumari, Mohit Kumar, Ravita Pilania, Aman Prasad, A. S. Rao","doi":"10.1007/s00340-024-08294-x","DOIUrl":null,"url":null,"abstract":"<div><p>Borosilicate glasses were prepared via melt quench technique with different concentration of Nd<sup>3+</sup> ions. X-ray diffraction (XRD) was performed for the prepared glass to study the amorphous structure. The glass stability was studied by Thermo-gravimetric Analysis (TGA). Spectroscopic analysis of the prepared glasses was done through absorption, excitation, emission and decay measurements. Absorption spectra was used to evaluate the J-O parameters. Radiative parameters are evaluated with the help of application of J-O theory. Emission spectra show three prominent bands in NIR region arising from <sup>4</sup>F<sub>3/2</sub> → <sup>4</sup>I<sub>9/2</sub>, <sup>4</sup>I<sub>11/2</sub> and <sup>4</sup>I<sub>13/2</sub> centered around 910, 1068 and 1339 nm accordingly, with the most intense being the one at 1068 nm. Stimulated emission cross section, branching ratio and quantum efficiency for <sup>4</sup>F<sub>3/2</sub> → <sup>4</sup>I<sub>11/2</sub> transition is very high and is suitable for lasing applications. Dipole–dipole interaction is observed among activator ions on the basis of Dexter theory. The optimized Nd<sup>3+</sup> doped glass (NBS10) possess maximum value for all radiative parameters and hence can be best suited for applications in the area of lasers and fiber amplifiers.</p></div>","PeriodicalId":474,"journal":{"name":"Applied Physics B","volume":"130 9","pages":""},"PeriodicalIF":2.0000,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhanced emission in the NIR range by Nd3+ doped borosilicate glass for lasing applications\",\"authors\":\"Yasha Tayal, Rupesh A. Talewar, Sk. Mahamuda, Kartika Maheshwari, Sheetal Kumari, Mohit Kumar, Ravita Pilania, Aman Prasad, A. S. Rao\",\"doi\":\"10.1007/s00340-024-08294-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Borosilicate glasses were prepared via melt quench technique with different concentration of Nd<sup>3+</sup> ions. X-ray diffraction (XRD) was performed for the prepared glass to study the amorphous structure. The glass stability was studied by Thermo-gravimetric Analysis (TGA). Spectroscopic analysis of the prepared glasses was done through absorption, excitation, emission and decay measurements. Absorption spectra was used to evaluate the J-O parameters. Radiative parameters are evaluated with the help of application of J-O theory. Emission spectra show three prominent bands in NIR region arising from <sup>4</sup>F<sub>3/2</sub> → <sup>4</sup>I<sub>9/2</sub>, <sup>4</sup>I<sub>11/2</sub> and <sup>4</sup>I<sub>13/2</sub> centered around 910, 1068 and 1339 nm accordingly, with the most intense being the one at 1068 nm. Stimulated emission cross section, branching ratio and quantum efficiency for <sup>4</sup>F<sub>3/2</sub> → <sup>4</sup>I<sub>11/2</sub> transition is very high and is suitable for lasing applications. Dipole–dipole interaction is observed among activator ions on the basis of Dexter theory. The optimized Nd<sup>3+</sup> doped glass (NBS10) possess maximum value for all radiative parameters and hence can be best suited for applications in the area of lasers and fiber amplifiers.</p></div>\",\"PeriodicalId\":474,\"journal\":{\"name\":\"Applied Physics B\",\"volume\":\"130 9\",\"pages\":\"\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2024-08-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Physics B\",\"FirstCategoryId\":\"4\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00340-024-08294-x\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"OPTICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Physics B","FirstCategoryId":"4","ListUrlMain":"https://link.springer.com/article/10.1007/s00340-024-08294-x","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"OPTICS","Score":null,"Total":0}
Enhanced emission in the NIR range by Nd3+ doped borosilicate glass for lasing applications
Borosilicate glasses were prepared via melt quench technique with different concentration of Nd3+ ions. X-ray diffraction (XRD) was performed for the prepared glass to study the amorphous structure. The glass stability was studied by Thermo-gravimetric Analysis (TGA). Spectroscopic analysis of the prepared glasses was done through absorption, excitation, emission and decay measurements. Absorption spectra was used to evaluate the J-O parameters. Radiative parameters are evaluated with the help of application of J-O theory. Emission spectra show three prominent bands in NIR region arising from 4F3/2 → 4I9/2, 4I11/2 and 4I13/2 centered around 910, 1068 and 1339 nm accordingly, with the most intense being the one at 1068 nm. Stimulated emission cross section, branching ratio and quantum efficiency for 4F3/2 → 4I11/2 transition is very high and is suitable for lasing applications. Dipole–dipole interaction is observed among activator ions on the basis of Dexter theory. The optimized Nd3+ doped glass (NBS10) possess maximum value for all radiative parameters and hence can be best suited for applications in the area of lasers and fiber amplifiers.
期刊介绍:
Features publication of experimental and theoretical investigations in applied physics
Offers invited reviews in addition to regular papers
Coverage includes laser physics, linear and nonlinear optics, ultrafast phenomena, photonic devices, optical and laser materials, quantum optics, laser spectroscopy of atoms, molecules and clusters, and more
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Publishing essential research results in two of the most important areas of applied physics, both Applied Physics sections figure among the top most cited journals in this field.
In addition to regular papers Applied Physics B: Lasers and Optics features invited reviews. Fields of topical interest are covered by feature issues. The journal also includes a rapid communication section for the speedy publication of important and particularly interesting results.