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Optical clearing of synthetic opals: a fluid kinetics study using optical coherence tomography 合成蛋白石的光学清除:使用光学相干层析成像的流体动力学研究
IF 2 3区 物理与天体物理 Q3 OPTICS Pub Date : 2026-03-14 DOI: 10.1007/s00340-026-08649-6
Arseniy P. Fashchevskiy, Yuriy I. Surkov, Isabella A. Serebryakova, Arsen K. Zotov, Kirill I. Zaytsev, Gleb M. Katyba, Anna S. Kycheryavenko, Vladimir M. Masalov, Valery V. Tuchin

A non-contact method for assessing the local geometrical thickness, porosity, and effective refractive index of synthetic opals using spectral optical coherence tomography is proposed. This approach was employed to investigate the diffusion of aqueous glycerol solutions with varying concentrations into the macropores of synthetic opals pre-filled with water. The kinetics of changes in the optical thickness and refractive index of synthetic opals during the optical clearing process were monitored. The obtained data were analyzed using the least-squares method, which enabled the determination of porosity 20–30%, refractive index 1.37–1.45, and geometrical thickness 0.94–1.17 mm of the synthetic opals. The results were validated by an alternative method of refractive index matching. It is demonstrated that the proposed approach can be applied to the analysis of local structural and optical parameters of porous materials, offering promising prospects for applications in materials science and bioengineering.

提出了一种利用光谱光学相干层析技术对合成蛋白石进行局部几何厚度、孔隙度和有效折射率评估的非接触方法。该方法用于研究不同浓度的甘油水溶液在预充水的合成蛋白石大孔中的扩散。研究了合成蛋白石在光学净化过程中光学厚度和折射率的变化动力学。利用最小二乘法对所得数据进行分析,确定了合成蛋白石的孔隙率为20 ~ 30%,折射率为1.37 ~ 1.45,几何厚度为0.94 ~ 1.17 mm。用另一种折射率匹配方法验证了结果。结果表明,该方法可用于多孔材料的局部结构和光学参数分析,在材料科学和生物工程领域具有广阔的应用前景。
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引用次数: 0
Quantum discord: as a measure of quantumness of correlation between superposed non-degenerate three-level laser and suharmonic cavity light beams 量子不和谐:作为叠加非简并三能级激光与超调和腔光束之间相关量子量的度量
IF 2 3区 物理与天体物理 Q3 OPTICS Pub Date : 2026-03-12 DOI: 10.1007/s00340-026-08654-9
Menwuyelet Melaku Folla, Deribe Hirpo Aredo

This research offers a thorough analysis of the non-classical features associated with cavity radiation produced by a combination of superposed non-degenerate three-level lasers and non-degenerate subharmonic light beams. The Q-functions of the individual light beams are utilized to derive the Q-function for the superposed cavity radiation. From this derived Q-function, we analyze the expectation values of operators. Using the relevant expectation values (correlations) of these operators, we calculate the quantum discord for the superposed cavity light beams being studied. The results indicate that quantum discord increases with the linear gain coefficient and atomic coherence, while it decreases with the parameter (gamma ) and population inversion, (xi ). Although the trends of forward and backward quantum discord are generally similar, it is distinctly observed that the forward quantum discord is consistently less than the backward quantum discord. The variation in quantum discord observed in the forward and reverse processes is primarily linked to the differences in the mean photon numbers of mode-a and mode-b within the non-degenerate three-level laser system. Additionally, a juxtaposition of quantum discord with entanglement, evaluated through the Logarithmic Negativity criterion, reveals that the quantum discord associated with the superposed cavity radiation remains above the Logarithmic Negativity level. Nonetheless, for certain values of (gamma ) exceeding 0.3, quantum discord may fall below the Logarithmic Negativity threshold. This observation underscores the notion that quantum discord is a significant aspect of entanglement. Through the application of quantum discord and the Logarithmic Negativity criterion, it is established that the superposed non-degenerate cavity radiation manifests quantum properties and entanglement.

本研究对叠加非简并三能级激光与非简并次谐波光束组合产生的腔辐射的非经典特征进行了深入分析。利用单个光束的q函数推导出叠加腔辐射的q函数。从这个导出的q函数,我们分析了算子的期望值。利用这些算子的相关期望值(相关性),我们计算了所研究的叠加腔光束的量子不谐。结果表明,量子不和谐随线性增益系数和原子相干度的增加而增加,随参数(gamma )和居数反转(xi )的增加而减小。虽然前向和后向量子不和谐的趋势大致相似,但可以清楚地观察到,前向量子不和谐始终小于后向量子不和谐。在非简并三能级激光系统中,正反过程中观测到的量子不和谐的变化主要与模a和模b的平均光子数的差异有关。此外,通过对数负性标准评估量子不和谐与纠缠的并置,揭示了与叠加腔辐射相关的量子不和谐仍然高于对数负性水平。然而,对于(gamma )超过0.3的某些值,量子不和谐可能低于对数负性阈值。这一观察结果强调了量子不和谐是纠缠的一个重要方面。通过应用量子失谐和对数负性判据,证明了叠加的非简并腔辐射具有量子特性和纠缠态。
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引用次数: 0
Essential characterization of q-plates for the design of Pancharatnam-Berry topological phase based gadgets 基于Pancharatnam-Berry拓扑相位器件设计中q板的基本特性
IF 2 3区 物理与天体物理 Q3 OPTICS Pub Date : 2026-03-10 DOI: 10.1007/s00340-026-08651-y
Nilesh Rajput, P. Kanaka Raju, G. Raghavan

Scalar vortex beams may be generated using multiple techniques. However, the generation of vector vortex beams from a single optical component has fewer options. A liquid crystal plate called a q-plate has a distribution of optical axis alignments that can vary radially and azimuthally. These plates provide a very robust and cost-effective method of generating vector-vortex and structured beams based on the Pancharatnam-Berry phase. Multi-plate gadgets can be generated from these plates to generate full-Poincaré beams, wavelength-tunable q-plates, and a wide range of structured light. The successful realization of such gadgets relies on the careful characterization of individual plates, which are characterized by their topological charge, offset angle, and retardance at the designed wavelength. In order to make complex multi-plate devices, a thorough mathematical modeling followed by multiple experimental measurements and simulations is essential. In the present work, a systematic and thorough protocol for such a characterization is provided with ample experimental and simulation results. The results presented here should be of value to experimentalists and device makers alike.

标量涡旋光束可以通过多种技术产生。然而,从单个光学元件产生矢量涡旋光束的选择较少。一种称为q板的液晶板具有光轴排列的分布,可以在径向和方位角上变化。这些板提供了一种非常稳健和经济的方法来产生矢量涡和基于Pancharatnam-Berry相位的结构光束。多片装置可以由这些片产生,以产生全poincarcars光束、波长可调的q片和大范围的结构光。这种器件的成功实现依赖于对单个板的仔细表征,这些板的特征在于它们的拓扑电荷、偏移角和在设计波长处的延迟。为了制造复杂的多板器件,必须进行全面的数学建模,然后进行多次实验测量和模拟。在目前的工作中,为这种表征提供了一个系统和彻底的协议,并提供了充足的实验和模拟结果。这里提出的结果应该对实验家和设备制造商都有价值。
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引用次数: 0
Topological light fields in free space: fundamentals and applications 自由空间中的拓扑光场:基础与应用
IF 2 3区 物理与天体物理 Q3 OPTICS Pub Date : 2026-03-07 DOI: 10.1007/s00340-026-08648-7
Jian Wang, Zhenyu Wan, Jinfeng Liu, Rui Sun, Junjie Chen, Shiao Ding

The incorporation of topology into physical dimensions of light introduces global and quantized characteristics that give rise to a new class of optical fields with enhanced robustness and functionality. Topological light fields are defined by nontrivial topological invariants, such as winding numbers, linking numbers, and skyrmion or Hopf indices, encoded in phase singularities, polarization textures, or spatiotemporal structures, providing a unifying framework for understanding and engineering complex optical structures. In this review, we present an overview of the fundamentals and applications of topological light fields in free space. We first classify topological light according to two-dimensional cross-profile topology, three-dimensional spatially-propagated topology, and spatiotemporal topology, and summarize the underlying physical principles, generation methods, and characterization techniques for representative structures, including optical vortices, vector beams, skyrmions, optical knots, Möbius strips, Hopfions, and spatiotemporal optical vortices. We then survey recent advances in applications enabled by topological light fields, covering high-capacity and robust optical communications, topological quantum entanglement, optical storage, precision optical metrology, and multidimensional optical trapping. Finally, we discuss key challenges and emerging opportunities in this rapidly evolving field. This review aims to provide a detailed roadmap for both fundamental research and technological development in free-space topological photonics.

将拓扑结构整合到光的物理维度中,引入了全局和量子化的特征,从而产生了一类具有增强鲁棒性和功能性的新型光场。拓扑光场由非平凡的拓扑不变量定义,如圈数、连接数、skyrmion或Hopf指数,编码在相位奇点、偏振织构或时空结构中,为理解和工程复杂的光学结构提供了统一的框架。本文综述了自由空间拓扑光场的基本原理及其应用。本文首先根据二维横截面拓扑、三维空间传播拓扑和时空拓扑对拓扑光进行了分类,并总结了代表性结构的基本物理原理、生成方法和表征技术,包括光涡、矢量光束、skyrmions、光学结、Möbius条、Hopfions和时空光涡。然后,我们调查了拓扑光场的最新应用进展,包括高容量和鲁棒光通信、拓扑量子纠缠、光存储、精密光学计量和多维光捕获。最后,我们讨论了这个快速发展领域的主要挑战和新兴机遇。本文旨在为自由空间拓扑光子学的基础研究和技术发展提供一个详细的路线图。
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引用次数: 0
Magnetic field controlled nucleation and size selection of silver nanoparticles 磁场控制纳米银的成核及粒径选择
IF 2 3区 物理与天体物理 Q3 OPTICS Pub Date : 2026-03-07 DOI: 10.1007/s00340-026-08656-7
Yazeed Tawalbeh, Mauro F. Pereira

We examine the reduction of silver nanoparticle (AgNP) size under an external magnetic field within a classical nucleation theory framework combined with a sphere-packing description of atomic assembly. The model incorporates magnetic free-energy contributions arising from the coupling between the applied field and the magnetic susceptibility of the nucleating material, yielding a closed-form relation between nanoparticle radius and field strength. Our approach reproduces the experimentally observed decrease in the most-probable particle radius from approximately (170text { nm}) at (mathcal {B}=49.27text { mT}) when the magnetic field is oriented parallel to the stirring plane, and to (155text { nm}) at (mathcal {B}=180.78text { mT}) in the perpendicular configuration. Across the investigated field range, the theoretical predictions remain consistent with experimental measurements obtained under continuous mechanical stirring, supporting the interpretation that the observed size reduction originates from a magnetic-field-induced modification of the nucleation free-energy landscape. Within the limits of classical capillarity and spherical demagnetization, the results provide a physically transparent and computationally efficient framework for understanding magnetic-field-controlled nanoparticle size selection.

我们在经典成核理论框架内结合原子组装的球形堆积描述,研究了外磁场下银纳米颗粒(AgNP)尺寸的减小。该模型考虑了外加磁场与成核材料磁化率之间的耦合所产生的磁性自由能贡献,得出纳米颗粒半径与场强之间的封闭关系。我们的方法再现了实验观察到的最可能粒子半径的减小,当磁场方向平行于搅拌平面时,最可能粒子半径从(mathcal {B}=49.27text { mT})处的近似(170text { nm})减小到垂直配置时的(155text { nm})减小到(mathcal {B}=180.78text { mT})。在整个研究的磁场范围内,理论预测与连续机械搅拌下获得的实验测量结果保持一致,支持了观察到的尺寸减小源于磁场诱导的成核自由能景观的改变的解释。在经典毛细作用和球形退磁的限制下,研究结果为理解磁场控制的纳米颗粒尺寸选择提供了一个物理透明和计算高效的框架。
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引用次数: 0
Nonreciprocal photonic spin hall effect in a bulk Dirac semimetal based tribonacci photonic crystal 块体Dirac半金属基tribonacci光子晶体中的非互易光子自旋霍尔效应
IF 2 3区 物理与天体物理 Q3 OPTICS Pub Date : 2026-03-02 DOI: 10.1007/s00340-026-08623-2
Zhi Ji, Ning-Yi Wang, Wen-Tao Liu, Zhi-Wei Liu, Qi Song, Hua-Peng Ye, Hai-Xia Da

Nonreciprocal photonic spin Hall effect manifests it as the different spin dependent reflected/transmitted transverse splittings of linearly polarized incident waves at two opposite wave propagation directions. However, its realization remains obscure. Here, we report the discovery of the prominent nonreciprocal photonic spin Hall effect in a bulk Dirac semimetal based on quasiperiodic Tribonacci photonic crystal, which is evidenced by the significantly large reflected spin shift along one propagation direction but the trivial spin shift along the opposite propagation direction due to its asymmetrical geometrical structure and electromagnetic field distribution. In addition, the Fermi energy of the bulk Dirac semimetal can be continuously modified by the external stimulus, which enables the effective control of the nonreciprocal photonic spin Hall effect in the Dirac semimetal based Tribonacci photonic crystal. Our results open up the alternative platform to generate the controllably nonreciprocal photonic spin Hall effect in the quasiperiodic systems via the combination of the bulk Dirac semimetals and Tribonacci photonic crystal.

非互易光子自旋霍尔效应表现为线偏振入射波在两个相反的波传播方向上反射/透射的不同自旋相关的横向分裂。然而,它的实现仍然模糊不清。本文报道了在基于准周期Tribonacci光子晶体的块体Dirac半金属中发现了显著的非倒易光子自旋霍尔效应,这证明了由于其不对称的几何结构和电磁场分布,沿一个传播方向的反射自旋位移很大,但沿相反的传播方向的自旋位移很小。此外,外部刺激可以连续地改变本体狄拉克半金属的费米能量,从而有效地控制基于狄拉克半金属的Tribonacci光子晶体中的非互易光子自旋霍尔效应。我们的研究结果为在准周期系统中通过体Dirac半金属和Tribonacci光子晶体的组合产生可控非互易光子自旋霍尔效应开辟了替代平台。
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引用次数: 0
Spatio-spectral characterization of ultrashort-pulse laser with wavelength-scanning ptychography 超短脉冲激光的波长扫描空间光谱表征
IF 2 3区 物理与天体物理 Q3 OPTICS Pub Date : 2026-03-02 DOI: 10.1007/s00340-026-08640-1
Qiang Zhang, Xuejie Zhang, Ping Zhu, Xiaomeng Sun, Qingfan Wu, Xiuyu Yao, Dongjun Zhang, Shiyou Chen, Cheng Liu, Yanying Zhao, Wenjun Ma, Xueqing Yan, Jianqiang Zhu

Spatio-spectral measurement of ultrashort-pulse beam is very important for the performance optimization of laser facilities. A reference-free, spectrally resolved measurement method based on ptychography with an advanced iterative algorithm for high-precision synthesis of full-spectrum data is proposed. We designed an integrated measurement device with robust implementation and high reliability. The device was successfully applied in a target chamber of a terawatt-class ultrashort-pulse laser facility. The spatio-spectral complex amplitude of a complicated pulsed laser was accurately reconstructed with high spatial resolution of 11 μm and some wavelength-dependent spatial phase characteristics in the laser pulse were identified. This method offers a promising approach for advanced beam characterization of high-power femtosecond laser system.

超短脉冲光束的空间光谱测量对激光设备的性能优化具有重要意义。提出了一种基于平面图的无参考光谱分辨测量方法和先进的迭代算法,用于高精度合成全光谱数据。设计了一种实现稳健、可靠性高的集成测量装置。该装置已成功应用于太瓦级超短脉冲激光装置的靶室。以11 μm的高空间分辨率精确重建了复杂脉冲激光的空间光谱复幅,并识别了激光脉冲中一些与波长相关的空间相位特征。该方法为高功率飞秒激光系统的高级光束表征提供了一种有前途的方法。
{"title":"Spatio-spectral characterization of ultrashort-pulse laser with wavelength-scanning ptychography","authors":"Qiang Zhang,&nbsp;Xuejie Zhang,&nbsp;Ping Zhu,&nbsp;Xiaomeng Sun,&nbsp;Qingfan Wu,&nbsp;Xiuyu Yao,&nbsp;Dongjun Zhang,&nbsp;Shiyou Chen,&nbsp;Cheng Liu,&nbsp;Yanying Zhao,&nbsp;Wenjun Ma,&nbsp;Xueqing Yan,&nbsp;Jianqiang Zhu","doi":"10.1007/s00340-026-08640-1","DOIUrl":"10.1007/s00340-026-08640-1","url":null,"abstract":"<div><p>Spatio-spectral measurement of ultrashort-pulse beam is very important for the performance optimization of laser facilities. A reference-free, spectrally resolved measurement method based on ptychography with an advanced iterative algorithm for high-precision synthesis of full-spectrum data is proposed. We designed an integrated measurement device with robust implementation and high reliability. The device was successfully applied in a target chamber of a terawatt-class ultrashort-pulse laser facility. The spatio-spectral complex amplitude of a complicated pulsed laser was accurately reconstructed with high spatial resolution of 11 μm and some wavelength-dependent spatial phase characteristics in the laser pulse were identified. This method offers a promising approach for advanced beam characterization of high-power femtosecond laser system.</p></div>","PeriodicalId":474,"journal":{"name":"Applied Physics B","volume":"132 3","pages":""},"PeriodicalIF":2.0,"publicationDate":"2026-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00340-026-08640-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147335766","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluating the viscoelastic properties and folding dynamics of red blood cells maintained at 4 °C using optical tweezers 用光学镊子评价红细胞在4°C下的粘弹性和折叠动力学
IF 2 3区 物理与天体物理 Q3 OPTICS Pub Date : 2026-03-02 DOI: 10.1007/s00340-026-08646-9
Theodoros Giannakis, Sotirios P. Fortis, Sergey V. Starinskiy, Anastasios G. Kriebardis, Maria Kandyla

This work investigates the viscoelastic properties and folding dynamics of red blood cells (RBCs) at the single-cell level, using optical tweezers. Cell elasticity and membrane viscosity are measured by dragging optically trapped RBCs against the surrounding plasma environment. A custom-developed image processing algorithm is employed for high-throughput processing of single-cell trapping data. The effect of refrigerated plasma storage on the mechanical properties of the cells is investigated by measuring their folding dynamics after one day and seven days of storage for several trapping laser powers and the findings indicate that mechanical stiffening of the cells takes place while they are stored. A novel correlation between RBC area and folding time is established. These results provide new insights into the mechanical behavior of RBCs, which are related to several blood disorders.

本研究使用光学镊子在单细胞水平上研究了红细胞的粘弹性特性和折叠动力学。细胞弹性和膜粘度是通过拖拽光学捕获的红细胞对抗周围的等离子体环境来测量的。采用自定义的图像处理算法对单细胞捕获数据进行高通量处理。通过测量等离子体在不同诱捕激光功率下储存1天和7天后的折叠动力学,研究了冷冻等离子体储存对细胞力学性能的影响,结果表明,细胞在储存过程中发生了机械硬化。红细胞面积与折叠时间之间建立了一种新的相关性。这些结果为红细胞的机械行为提供了新的见解,这与几种血液疾病有关。
{"title":"Evaluating the viscoelastic properties and folding dynamics of red blood cells maintained at 4 °C using optical tweezers","authors":"Theodoros Giannakis,&nbsp;Sotirios P. Fortis,&nbsp;Sergey V. Starinskiy,&nbsp;Anastasios G. Kriebardis,&nbsp;Maria Kandyla","doi":"10.1007/s00340-026-08646-9","DOIUrl":"10.1007/s00340-026-08646-9","url":null,"abstract":"<div>\u0000 \u0000 <p>This work investigates the viscoelastic properties and folding dynamics of red blood cells (RBCs) at the single-cell level, using optical tweezers. Cell elasticity and membrane viscosity are measured by dragging optically trapped RBCs against the surrounding plasma environment. A custom-developed image processing algorithm is employed for high-throughput processing of single-cell trapping data. The effect of refrigerated plasma storage on the mechanical properties of the cells is investigated by measuring their folding dynamics after one day and seven days of storage for several trapping laser powers and the findings indicate that mechanical stiffening of the cells takes place while they are stored. A novel correlation between RBC area and folding time is established. These results provide new insights into the mechanical behavior of RBCs, which are related to several blood disorders.</p>\u0000 </div>","PeriodicalId":474,"journal":{"name":"Applied Physics B","volume":"132 3","pages":""},"PeriodicalIF":2.0,"publicationDate":"2026-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00340-026-08646-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147335931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The universal statistics of multipulse laser damage 多脉冲激光损伤的通用统计
IF 2 3区 物理与天体物理 Q3 OPTICS Pub Date : 2026-02-28 DOI: 10.1007/s00340-026-08622-3
A. M. Zheltikov

We show that, in a vast class of multiple-pulse laser–matter interaction settings, the S-pulse laser damage probability and the expected number of pulses before the damage can be expressed in the S >  > 1 limit as closed-form functions of the laser fluence and the variation coefficient of laser-driver statistics. The statistics of such rare laser-damage events is found in the class of generalized extreme-event distributions, allowing multiple-pulse laser damage to be understood in terms of universal properties of extreme-event statistics. As a demonstration of its descriptive power, this approach is shown to provide an accurate, physically insightful fit for the reference experimental data for multipulse laser damage in optical-grade glasses and nonlinear crystals.

我们表明,在大量的多脉冲激光-物质相互作用设置中,S脉冲激光损伤概率和损伤前的预期脉冲数可以用S >; >; 1极限表示为激光能量和激光驱动统计变异系数的封闭函数。这种罕见的激光损伤事件的统计是在广义的极端事件分布中发现的,允许用极端事件统计的普遍性质来理解多脉冲激光损伤。作为其描述能力的演示,该方法被证明为光学级玻璃和非线性晶体中多脉冲激光损伤的参考实验数据提供了准确的,物理上深刻的适合。
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引用次数: 0
Enhanced accuracy in nuclear fuel analysis: a novel standard addition method with LIBS for quantifying La and Nd in unknown Th-U MOX fuel 提高核燃料分析的准确性:用LIBS定量未知Th-U MOX燃料中的La和Nd的新标准添加方法
IF 2 3区 物理与天体物理 Q3 OPTICS Pub Date : 2026-02-26 DOI: 10.1007/s00340-026-08624-1
Min Zhang, Hao Li, Qingyao Meng, Lingling Peng, Debo Wu, Yuhong Li, Zuoye Liu, Xiaoliang Liu, Xiaoyan Li, Yanhua Shi

Impurity elements such as lanthanum (La) and neodymium (Nd) in nuclear fuel can adversely impact its efficiency and operational lifespan, making their accurate quantification essential. This study employed laser-induced breakdown spectroscopy (LIBS) to analyze La and Nd in unknown thorium (Th) uranium (U) mixed oxide (Th-U MOX) fuel materials. A novel difference method (DM) was integrated with the standard addition method (SAM) and compared with the conventional extrapolation method (EM). Following a rigorous comparison, three analytical lines for each element were selected: 442.99 nm, 465.55 nm and 545.51 nm for La, and 430.35 nm, 445.15 nm and 529.31 nm for Nd. At 465.55 nm, the SAM-DM approach predicted a La concentration of 530 ppm with a relative error of the mean (REM) of 5.2%, markedly lower than the EM result of 600 ppm (REM = 24.9%). For Nd at 529.31 nm, SAM-DM yielded 475 ppm with 4.5% REM, compared to 550 ppm and 10.6% REM by EM. These results confirm the superior accuracy of SAM-DM over EM, particularly at the selected analytical lines. The two lines were subsequently used to construct optimized calibration curves, yielding limits of detection (LODs) of 155.22 ppm for La and 355.97 ppm for Nd. Furthermore, leave-one-out cross-validation (LOO-CV) confirmed the robustness of the proposed strategy, with prediction errors generally below 9% except in low concentration cases. Overall, this work establishes a reliable analytical framework for nuclear fuel impurity quantification by pioneering the combination of SAM-DM with LIBS for Th-U MOX analysis, demonstrating strong potential for quality control and safeguards applications.

核燃料中的杂质元素如镧(La)和钕(Nd)会对其效率和使用寿命产生不利影响,因此对其进行准确量化至关重要。本研究采用激光诱导击穿光谱(LIBS)分析未知钍(Th)铀(U)混合氧化物(Th-U MOX)燃料材料中的La和Nd。将差分法与标准加法法相结合,并与传统的外推法进行了比较。经过严格的比较,每种元素选择了3条分析线:La为442.99 nm、465.55 nm和545.51 nm, Nd为430.35 nm、445.15 nm和529.31 nm。在465.55 nm处,SAM-DM方法预测的La浓度为530 ppm,平均相对误差(REM)为5.2%,明显低于EM结果600 ppm (REM = 24.9%)。对于529.31 nm的Nd, SAM-DM在4.5% REM下产生475 ppm,相比之下,EM产生550 ppm和10.6% REM。这些结果证实了SAM-DM优于EM的准确性,特别是在选定的分析线上。利用这两条线构建优化的校准曲线,La的检出限为155.22 ppm, Nd的检出限为355.97 ppm。此外,留一交叉验证(LOO-CV)证实了该策略的稳健性,除低浓度情况外,预测误差一般在9%以下。总的来说,这项工作通过开创性地将SAM-DM与LIBS结合用于Th-U MOX分析,建立了一个可靠的核燃料杂质定量分析框架,展示了质量控制和保障应用的强大潜力。
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引用次数: 0
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Applied Physics B
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