{"title":"通过等离子体二氧化碳催化推进地球和太空应用中的原地资源利用","authors":"Naama Alhemeiri , Lance Kosca , Marko Gacesa , Kyriaki Polychronopoulou","doi":"10.1016/j.jcou.2024.102887","DOIUrl":null,"url":null,"abstract":"<div><p>Catalysis has optimized and improved production rates in many industrial processes. Conventional catalysis plays a key role in the mass-production of otherwise difficult to obtain substances. Plasma catalysis, plasma incorporation to appropriate catalysts, has been shown in literature to further outperform the typical conventional methods, and has shown potential to become a key production method in deep space exploration and survival. However, it faces a few more challenges that hinder it from being used industrially. In this review, we discuss known mechanisms in literature and the instrumentation and diagnostics that were utilized to be able to determine and explain these mechanisms in detail, and thus have led to the development of plasma catalysts with up to 80 % conversion rates for CO<sub>2</sub> conversion processes. We also discuss diagnostics that may be employed in the near future to reveal the last few unconventional mechanisms that must be explained in order to address the current instability and short life of catalysts due to the harsh conditions of plasma. In successful implementations of diagnostics in literature, they have proven to be the key to unlocking the knowledge required to develop appropriate catalysts optimized for converting CO<sub>2</sub> in a plasma environment.</p></div>","PeriodicalId":350,"journal":{"name":"Journal of CO2 Utilization","volume":"85 ","pages":"Article 102887"},"PeriodicalIF":7.2000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212982024002221/pdfft?md5=3934367e81281f7feac89bf08b1767d0&pid=1-s2.0-S2212982024002221-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Advancing in-situ resource utilization for earth and space applications through plasma CO2 catalysis\",\"authors\":\"Naama Alhemeiri , Lance Kosca , Marko Gacesa , Kyriaki Polychronopoulou\",\"doi\":\"10.1016/j.jcou.2024.102887\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Catalysis has optimized and improved production rates in many industrial processes. Conventional catalysis plays a key role in the mass-production of otherwise difficult to obtain substances. Plasma catalysis, plasma incorporation to appropriate catalysts, has been shown in literature to further outperform the typical conventional methods, and has shown potential to become a key production method in deep space exploration and survival. However, it faces a few more challenges that hinder it from being used industrially. In this review, we discuss known mechanisms in literature and the instrumentation and diagnostics that were utilized to be able to determine and explain these mechanisms in detail, and thus have led to the development of plasma catalysts with up to 80 % conversion rates for CO<sub>2</sub> conversion processes. We also discuss diagnostics that may be employed in the near future to reveal the last few unconventional mechanisms that must be explained in order to address the current instability and short life of catalysts due to the harsh conditions of plasma. In successful implementations of diagnostics in literature, they have proven to be the key to unlocking the knowledge required to develop appropriate catalysts optimized for converting CO<sub>2</sub> in a plasma environment.</p></div>\",\"PeriodicalId\":350,\"journal\":{\"name\":\"Journal of CO2 Utilization\",\"volume\":\"85 \",\"pages\":\"Article 102887\"},\"PeriodicalIF\":7.2000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2212982024002221/pdfft?md5=3934367e81281f7feac89bf08b1767d0&pid=1-s2.0-S2212982024002221-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of CO2 Utilization\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2212982024002221\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of CO2 Utilization","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2212982024002221","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
催化作用优化并提高了许多工业流程的生产率。传统催化在大规模生产难以获得的物质方面发挥着关键作用。文献显示,等离子体催化,即在适当的催化剂中加入等离子体,进一步超越了典型的传统方法,并已显示出成为深空探索和生存的关键生产方法的潜力。然而,它还面临着一些挑战,阻碍了它在工业上的应用。在这篇综述中,我们将讨论文献中已知的机理,以及为详细确定和解释这些机理而使用的仪器和诊断方法,从而开发出转化率高达 80% 的等离子催化剂,用于 CO 转化过程。我们还讨论了在不久的将来可能采用的诊断方法,以揭示必须解释的最后几种非常规机制,从而解决目前由于等离子体的苛刻条件造成的催化剂不稳定和寿命短的问题。在文献中成功实施的诊断方法证明,它们是开启知识大门的关键,而这些知识正是开发适当催化剂所需的,这些催化剂经过优化,可在等离子体环境中转化一氧化碳。
Advancing in-situ resource utilization for earth and space applications through plasma CO2 catalysis
Catalysis has optimized and improved production rates in many industrial processes. Conventional catalysis plays a key role in the mass-production of otherwise difficult to obtain substances. Plasma catalysis, plasma incorporation to appropriate catalysts, has been shown in literature to further outperform the typical conventional methods, and has shown potential to become a key production method in deep space exploration and survival. However, it faces a few more challenges that hinder it from being used industrially. In this review, we discuss known mechanisms in literature and the instrumentation and diagnostics that were utilized to be able to determine and explain these mechanisms in detail, and thus have led to the development of plasma catalysts with up to 80 % conversion rates for CO2 conversion processes. We also discuss diagnostics that may be employed in the near future to reveal the last few unconventional mechanisms that must be explained in order to address the current instability and short life of catalysts due to the harsh conditions of plasma. In successful implementations of diagnostics in literature, they have proven to be the key to unlocking the knowledge required to develop appropriate catalysts optimized for converting CO2 in a plasma environment.
期刊介绍:
The Journal of CO2 Utilization offers a single, multi-disciplinary, scholarly platform for the exchange of novel research in the field of CO2 re-use for scientists and engineers in chemicals, fuels and materials.
The emphasis is on the dissemination of leading-edge research from basic science to the development of new processes, technologies and applications.
The Journal of CO2 Utilization publishes original peer-reviewed research papers, reviews, and short communications, including experimental and theoretical work, and analytical models and simulations.