Pingping Huang, Zhijie He, Yupeng Xie, Yuzhen Mai, Mingfeng Chen, Zhitao Hu
{"title":"微波烧结法在地聚合物衍生的锶长石-白云石复合相陶瓷中共同固定锶和铯","authors":"Pingping Huang, Zhijie He, Yupeng Xie, Yuzhen Mai, Mingfeng Chen, Zhitao Hu","doi":"10.1007/s10967-024-09666-5","DOIUrl":null,"url":null,"abstract":"<div><p>The ceramic products derived from cesium-strontium co-doped geopolymers ((Cs, Sr)-GP) have been synthesized by microwave sintering to realize the co-immobilization of Cs and Sr. Results show that (Cs, Sr)-GP with various Cs/Sr ratios (2–4) form Sr-feldspar-pollucite composite ceramic, the formation temperatures of monoclinic Sr-feldspar decrease from 1000 ℃ (for Sr-GP) to 800 ℃ (for (Cs, Sr)-GP) with Cs addition. The ceramic product heat treated from the (4Cs, Sr)-GP at 1000 ℃ has a high crystalline and optimal leaching resistance, is considered as an ideal host to immobilization the real fission products containing Cs and Sr.</p></div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":"333 10","pages":"4983 - 4993"},"PeriodicalIF":1.5000,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Co-immobilization of strontium and cesium in Sr-feldspar-pollucite composite phase ceramics derived from geopolymer by microwave sintering\",\"authors\":\"Pingping Huang, Zhijie He, Yupeng Xie, Yuzhen Mai, Mingfeng Chen, Zhitao Hu\",\"doi\":\"10.1007/s10967-024-09666-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The ceramic products derived from cesium-strontium co-doped geopolymers ((Cs, Sr)-GP) have been synthesized by microwave sintering to realize the co-immobilization of Cs and Sr. Results show that (Cs, Sr)-GP with various Cs/Sr ratios (2–4) form Sr-feldspar-pollucite composite ceramic, the formation temperatures of monoclinic Sr-feldspar decrease from 1000 ℃ (for Sr-GP) to 800 ℃ (for (Cs, Sr)-GP) with Cs addition. The ceramic product heat treated from the (4Cs, Sr)-GP at 1000 ℃ has a high crystalline and optimal leaching resistance, is considered as an ideal host to immobilization the real fission products containing Cs and Sr.</p></div>\",\"PeriodicalId\":661,\"journal\":{\"name\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"volume\":\"333 10\",\"pages\":\"4983 - 4993\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-08-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Radioanalytical and Nuclear Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10967-024-09666-5\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Radioanalytical and Nuclear Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10967-024-09666-5","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Co-immobilization of strontium and cesium in Sr-feldspar-pollucite composite phase ceramics derived from geopolymer by microwave sintering
The ceramic products derived from cesium-strontium co-doped geopolymers ((Cs, Sr)-GP) have been synthesized by microwave sintering to realize the co-immobilization of Cs and Sr. Results show that (Cs, Sr)-GP with various Cs/Sr ratios (2–4) form Sr-feldspar-pollucite composite ceramic, the formation temperatures of monoclinic Sr-feldspar decrease from 1000 ℃ (for Sr-GP) to 800 ℃ (for (Cs, Sr)-GP) with Cs addition. The ceramic product heat treated from the (4Cs, Sr)-GP at 1000 ℃ has a high crystalline and optimal leaching resistance, is considered as an ideal host to immobilization the real fission products containing Cs and Sr.
期刊介绍:
An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.