高效合成 IrPtPdNi/GO 纳米催化剂,在水电解中发挥卓越性能

IF 9.5 2区 材料科学 Q1 CHEMISTRY, PHYSICAL Nano Research Pub Date : 2024-08-08 DOI:10.1007/s12274-024-6900-6
Sanha Jang, Young Hwa Yun, Jin Gyu Lee, Kyung Hee Oh, Shin Wook Kang, Jung-Il Yang, MinJoong Kim, Changsoo Lee, Ji Chan Park
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引用次数: 0

摘要

传统的氧化铱(Ir)催化剂在水电解中面临着很大的局限性,尤其是在酸性条件下,其不稳定性和降解性严重限制了氧进化反应(OER)和氢进化反应(HER)的效率。为了克服这些挑战,本研究利用垂直移动反应器在氧化石墨烯载体上成功合成了高度分散的 IrPtPdNi 合金纳米粒子,在水电解中表现出卓越的性能。这些通过快速移动床热解方法合成的纳米粒子结合了铱、铂、钯和镍。它们在 OER 中的过电位较低,在 HER 中的性能与商用催化剂相当,同时还具有更高的稳定性。这些成果超越了传统催化剂的局限性,标志着在实现更高效、更可持续的制氢技术方面取得了重大进展。通过创新性地提高催化剂在电化学分水过程中的性能,这一进步有望极大地促进可持续能源系统的发展。
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Efficient synthesis of IrPtPdNi/GO nanocatalysts for superior performance in water electrolysis

Traditional iridium (Ir) oxide catalysts have faced significant limitations in water electrolysis, particularly under acidic conditions where instability and degradation severely restrict the efficiency of the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). To overcome these challenges, this study successfully synthesized highly dispersed IrPtPdNi alloy nanoparticles on a graphene oxide support using a vertically moving reactor, demonstrating exceptional performance in water electrolysis. These nanoparticles, synthesized via a fast-moving bed pyrolysis method, combine iridium, platinum, palladium, and nickel. They exhibit lower overpotentials in OER and comparable performance in HER to commercial catalysts, while also offering enhanced stability. These results surpass the limitations of traditional catalysts, marking significant progress toward more efficient and sustainable hydrogen production technologies. This advancement is expected to contribute significantly to the development of sustainable energy systems by innovatively enhancing the performance of catalysts in the electrochemical water-splitting process.

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来源期刊
Nano Research
Nano Research 化学-材料科学:综合
CiteScore
14.30
自引率
11.10%
发文量
2574
审稿时长
1.7 months
期刊介绍: Nano Research is a peer-reviewed, international and interdisciplinary research journal that focuses on all aspects of nanoscience and nanotechnology. It solicits submissions in various topical areas, from basic aspects of nanoscale materials to practical applications. The journal publishes articles on synthesis, characterization, and manipulation of nanomaterials; nanoscale physics, electrical transport, and quantum physics; scanning probe microscopy and spectroscopy; nanofluidics; nanosensors; nanoelectronics and molecular electronics; nano-optics, nano-optoelectronics, and nano-photonics; nanomagnetics; nanobiotechnology and nanomedicine; and nanoscale modeling and simulations. Nano Research offers readers a combination of authoritative and comprehensive Reviews, original cutting-edge research in Communication and Full Paper formats. The journal also prioritizes rapid review to ensure prompt publication.
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