碳微球杂化 CuFe2O4 提高电荷存储特性,用于高能量密度固态混合超级电容器

IF 7.1 3区 材料科学 Q1 GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY Materials Today Sustainability Pub Date : 2024-08-03 DOI:10.1016/j.mtsust.2024.100950
J.J. Rushmittha , S. Radhika , Khalid A. Alrashidi , G. Maheshwaran , S. Dhinesh , S. Sambasivam
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引用次数: 0

摘要

我们合成了铜铁氧体/碳球(CuFeO/C-sphere NC)的混合纳米复合材料,并实现了它们在超级电容器中的组合电化学活性。XRD 研究显示 CuFeO/C-sphere NC 的平均结晶尺寸为 112 nm。CuFeO/C-sphere NC 具有 532 m/g 的巨大比表面积。循环伏安法(CV)分析表明,在 10 mV/s 的扫描速率下,CuFeO/C-球状 NC 的竞争比容量为 320 C/g。电静态充放电(GCD)研究表明,在 1 A/g 时,比容量为 264 C/g,循环稳定性极佳,5000 次循环的比容量为 82.4%。CuFeO/C-sphere//AC 固态混合超级电容器的比容量高达 131 C/g,能量密度和功率密度分别为 40.9 Wh/kg 和 11248 W/kg。
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Hybridization of CuFe2O4 by carbon microspheres with improved charge storage characteristics for high energy density solid-state hybrid supercapacitor

The hybrid nanocomposite of Copper Ferrite/Carbon sphere (CuFe2O4/C-sphere NC) has been synthesized and their combined electrochemical activity for supercapacitors is achieved. XRD study reveals the average crystallite size of CuFe2O4/C-sphere NC as 112 nm. CuFe2O4/C-sphere NC provides a huge specific surface area of 532 m2/g. Cyclic voltammetry (CV) analysis exhibits the competitive specific capacity of CuFe2O4/C-sphere NC as 320 C/g at the sweep rate of 10 mV/s. The galvanostatic charge-discharge (GCD) study shows a good specific capacity of 264 C/g at 1 A/g and excellent cyclic stability of 82.4% for 5000 cycles. The CuFe2O4/C-sphere//AC solid-state hybrid supercapacitor provides a high specific capacity of 131 C/g along with remarkable energy density and power density of 40.9 Wh/kg and 11248 W/kg respectively.

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来源期刊
CiteScore
5.80
自引率
6.40%
发文量
174
审稿时长
32 days
期刊介绍: Materials Today Sustainability is a multi-disciplinary journal covering all aspects of sustainability through materials science. With a rapidly increasing population with growing demands, materials science has emerged as a critical discipline toward protecting of the environment and ensuring the long term survival of future generations.
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