Shaikha S. AlNeyadi, Seeta SA, Shooq N. Aljasmi, Dana S. Alshkeili, M.H. Al Anoud, O.S. Salama
{"title":"利用 IB-COF 共价有机框架去除水中的布洛芬","authors":"Shaikha S. AlNeyadi, Seeta SA, Shooq N. Aljasmi, Dana S. Alshkeili, M.H. Al Anoud, O.S. Salama","doi":"10.1016/j.hazadv.2024.100451","DOIUrl":null,"url":null,"abstract":"<div><p>The rising presence of ibuprofen (IBP) in natural water bodies, restricting from its widespread pharmaceutical usage, necessitates effective remediation strategies. This study introduces IB-COF, a novel covalent organic framework synthesized via a solvothermal method, specifically engineered for IBP extraction from aqueous solutions. IB-COF showcases remarkable adsorption performance, achieving equilibrium within 60 min with a capacity of 512 mg/g, outperforming conventional adsorbents. Its adsorption kinetics align with pseudo-second-order and Langmuir models, indicating efficient monolayer adsorption. Significantly, IB-COF exhibits robust recyclability over five cycles. Among the prevalence of IBP contamination, IB-COF demonstrates promise in selectively extracting IBP even in the presence of competing pharmaceuticals. Overall, our findings underscore the potential of IB-COF as an advanced adsorbent for mitigating IBP pollution in water sources, contributing significantly to environmental purification efforts and water pollution mitigation strategies.</p></div>","PeriodicalId":73763,"journal":{"name":"Journal of hazardous materials advances","volume":"15 ","pages":"Article 100451"},"PeriodicalIF":5.4000,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772416624000524/pdfft?md5=b3f2d0237f6ccd30f8124630e2d1a815&pid=1-s2.0-S2772416624000524-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Ibuprofen removal from water using the IB-COF covalent organic framework\",\"authors\":\"Shaikha S. AlNeyadi, Seeta SA, Shooq N. Aljasmi, Dana S. Alshkeili, M.H. Al Anoud, O.S. Salama\",\"doi\":\"10.1016/j.hazadv.2024.100451\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The rising presence of ibuprofen (IBP) in natural water bodies, restricting from its widespread pharmaceutical usage, necessitates effective remediation strategies. This study introduces IB-COF, a novel covalent organic framework synthesized via a solvothermal method, specifically engineered for IBP extraction from aqueous solutions. IB-COF showcases remarkable adsorption performance, achieving equilibrium within 60 min with a capacity of 512 mg/g, outperforming conventional adsorbents. Its adsorption kinetics align with pseudo-second-order and Langmuir models, indicating efficient monolayer adsorption. Significantly, IB-COF exhibits robust recyclability over five cycles. Among the prevalence of IBP contamination, IB-COF demonstrates promise in selectively extracting IBP even in the presence of competing pharmaceuticals. Overall, our findings underscore the potential of IB-COF as an advanced adsorbent for mitigating IBP pollution in water sources, contributing significantly to environmental purification efforts and water pollution mitigation strategies.</p></div>\",\"PeriodicalId\":73763,\"journal\":{\"name\":\"Journal of hazardous materials advances\",\"volume\":\"15 \",\"pages\":\"Article 100451\"},\"PeriodicalIF\":5.4000,\"publicationDate\":\"2024-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2772416624000524/pdfft?md5=b3f2d0237f6ccd30f8124630e2d1a815&pid=1-s2.0-S2772416624000524-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of hazardous materials advances\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2772416624000524\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of hazardous materials advances","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2772416624000524","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Ibuprofen removal from water using the IB-COF covalent organic framework
The rising presence of ibuprofen (IBP) in natural water bodies, restricting from its widespread pharmaceutical usage, necessitates effective remediation strategies. This study introduces IB-COF, a novel covalent organic framework synthesized via a solvothermal method, specifically engineered for IBP extraction from aqueous solutions. IB-COF showcases remarkable adsorption performance, achieving equilibrium within 60 min with a capacity of 512 mg/g, outperforming conventional adsorbents. Its adsorption kinetics align with pseudo-second-order and Langmuir models, indicating efficient monolayer adsorption. Significantly, IB-COF exhibits robust recyclability over five cycles. Among the prevalence of IBP contamination, IB-COF demonstrates promise in selectively extracting IBP even in the presence of competing pharmaceuticals. Overall, our findings underscore the potential of IB-COF as an advanced adsorbent for mitigating IBP pollution in water sources, contributing significantly to environmental purification efforts and water pollution mitigation strategies.