Nikolai S. Bushkov , Andrey V. Rumyantsev , Anton A. Zhizhin , Ivan A. Godovikov , Pavel A. Zhizhko , Dmitry N. Zarubin
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引用次数: 0
摘要
定义明确的二氧化硅支撑 Ti 亚氨基配合物 (SiO)Ti(NBut)(Me2Pyr)(Py)2 （Me2Pyr = 2,5 二甲基吡咯基）通过氧化/亚氨基异构反应催化 N-亚磺酰苯胺缩合成硫代二亚胺，为功能化硫代二亚胺提供了一条便捷的合成路线。
Ti-catalyzed heterometathetical condensation of N-sulfinylamines into sulfurdiimines
Well-defined silica-supported Ti imido complex (SiO)Ti(NBut)(Me2Pyr)(Py)2 (Me2Pyr = 2,5-dimethyl- pyrrolyl) catalyzes condensation of N-sulfinylanilines into sulfurdiimines via the oxo/imido heterometathesis providing a convenient synthetic route to functionalized sulfurdiimines.
期刊介绍：
Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications.
Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.
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