{"title":"石墨烯-氧化锌复合微珠吸附氟离子的性能分析及其人工神经网络(ANN)建模预测","authors":"","doi":"10.1016/j.nanoso.2024.101288","DOIUrl":null,"url":null,"abstract":"<div><p>In this present study, a facile, sustainable, eco-friendly, and low-cost material was developed using synthesized graphene-oxide (SGO) incorporated with zinc oxide (SGO/ZnO) and its adsorptive performance was compared with commercial graphene oxide (CGO) and synthesized graphene-oxide (SGO) for the removal of fluoride ion from aqueous environment. The materials were characterized using techniques such as Fourier transform spectroscopy (FTIR), Scanning electron microscopy coupled with energy dispersive X-Ray spectroscopy (SEM-EDX), X-ray diffraction (XRD), Zeta potentiometer, Brunauer–Emmett–Teller (BET) measurement, Transmission Electron Microscopy (TEM). The SEM analysis confirmed the existence of a spherical structure, smooth and agglomerated white particle in between the wrinkled GO sheet, demonstrating a successful synthesis of SGO/ZnO composite. The EDX analysis revealed the presence of carbon, zinc, and oxygen with no impurities. The successful incorporation of ZnO on SGO yielded a BET surface of 123 m<sup>2</sup>/g for SGO/ZnO, which is far greater than that of the separate SGO and ZnO with surface areas of 19 m<sup>2</sup>/g and 76 m<sup>2</sup>/g respectively. The batch studies revealed that the removal of fluoride ion by CGO, SGO, and SGO/ZnO was 89.4 %, 94.8 %, and 99.2 %. Also, the jovanovic isotherm model fitted well to the fluoride ion adsorption onto CGO, SGO, and SGO/ZnO suggesting a monolayer adsorption with mechanical contact possibility. The estimated adsorption capacities (Q<sub>max</sub>) were 105.64, 116.37, and 188.60 mg/g for CGO, SGO, and SGO/ZnO, respectively. In addition, the adsorption kinetics study showed that the pseudo-second-order kinetic model suits the adsorption model, indicating the presence of an ionic interaction between the adsorbent functional groups and the fluoride ion. The adsorption thermodynamic analysis indicates that the adsorption process was spontaneous, endothermic, with strong affinity between the adsorbate and adsorbents. Furthermore, the regenerability and reusability analysis showed that about 39.5 %, 49.9 %, and 70.6 % of fluoride ion on CGO, SGO, and SGO/ZnO was removed after fifth desorption-adsorption cycles, suggesting that the SGO/ZnO was more stable. The interaction mechanism between SGO/ZnO and fluoride ion was governed primarily by pore-filling, hydrogen bonding, electrostatic attraction, and physical adsorption.</p></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":null,"pages":null},"PeriodicalIF":5.4500,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2352507X24001999/pdfft?md5=be4cf7622951c9f491063d41440b31a7&pid=1-s2.0-S2352507X24001999-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Insightful performance analysis of fluoride ion adsorption onto graphene-zinc oxide composite beads and its prediction by Artificial Neural Network (ANN) modeling\",\"authors\":\"\",\"doi\":\"10.1016/j.nanoso.2024.101288\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this present study, a facile, sustainable, eco-friendly, and low-cost material was developed using synthesized graphene-oxide (SGO) incorporated with zinc oxide (SGO/ZnO) and its adsorptive performance was compared with commercial graphene oxide (CGO) and synthesized graphene-oxide (SGO) for the removal of fluoride ion from aqueous environment. The materials were characterized using techniques such as Fourier transform spectroscopy (FTIR), Scanning electron microscopy coupled with energy dispersive X-Ray spectroscopy (SEM-EDX), X-ray diffraction (XRD), Zeta potentiometer, Brunauer–Emmett–Teller (BET) measurement, Transmission Electron Microscopy (TEM). The SEM analysis confirmed the existence of a spherical structure, smooth and agglomerated white particle in between the wrinkled GO sheet, demonstrating a successful synthesis of SGO/ZnO composite. The EDX analysis revealed the presence of carbon, zinc, and oxygen with no impurities. The successful incorporation of ZnO on SGO yielded a BET surface of 123 m<sup>2</sup>/g for SGO/ZnO, which is far greater than that of the separate SGO and ZnO with surface areas of 19 m<sup>2</sup>/g and 76 m<sup>2</sup>/g respectively. The batch studies revealed that the removal of fluoride ion by CGO, SGO, and SGO/ZnO was 89.4 %, 94.8 %, and 99.2 %. Also, the jovanovic isotherm model fitted well to the fluoride ion adsorption onto CGO, SGO, and SGO/ZnO suggesting a monolayer adsorption with mechanical contact possibility. The estimated adsorption capacities (Q<sub>max</sub>) were 105.64, 116.37, and 188.60 mg/g for CGO, SGO, and SGO/ZnO, respectively. In addition, the adsorption kinetics study showed that the pseudo-second-order kinetic model suits the adsorption model, indicating the presence of an ionic interaction between the adsorbent functional groups and the fluoride ion. The adsorption thermodynamic analysis indicates that the adsorption process was spontaneous, endothermic, with strong affinity between the adsorbate and adsorbents. Furthermore, the regenerability and reusability analysis showed that about 39.5 %, 49.9 %, and 70.6 % of fluoride ion on CGO, SGO, and SGO/ZnO was removed after fifth desorption-adsorption cycles, suggesting that the SGO/ZnO was more stable. The interaction mechanism between SGO/ZnO and fluoride ion was governed primarily by pore-filling, hydrogen bonding, electrostatic attraction, and physical adsorption.</p></div>\",\"PeriodicalId\":397,\"journal\":{\"name\":\"Nano-Structures & Nano-Objects\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.4500,\"publicationDate\":\"2024-08-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2352507X24001999/pdfft?md5=be4cf7622951c9f491063d41440b31a7&pid=1-s2.0-S2352507X24001999-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nano-Structures & Nano-Objects\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352507X24001999\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Physics and Astronomy\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano-Structures & Nano-Objects","FirstCategoryId":"1","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352507X24001999","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Physics and Astronomy","Score":null,"Total":0}
Insightful performance analysis of fluoride ion adsorption onto graphene-zinc oxide composite beads and its prediction by Artificial Neural Network (ANN) modeling
In this present study, a facile, sustainable, eco-friendly, and low-cost material was developed using synthesized graphene-oxide (SGO) incorporated with zinc oxide (SGO/ZnO) and its adsorptive performance was compared with commercial graphene oxide (CGO) and synthesized graphene-oxide (SGO) for the removal of fluoride ion from aqueous environment. The materials were characterized using techniques such as Fourier transform spectroscopy (FTIR), Scanning electron microscopy coupled with energy dispersive X-Ray spectroscopy (SEM-EDX), X-ray diffraction (XRD), Zeta potentiometer, Brunauer–Emmett–Teller (BET) measurement, Transmission Electron Microscopy (TEM). The SEM analysis confirmed the existence of a spherical structure, smooth and agglomerated white particle in between the wrinkled GO sheet, demonstrating a successful synthesis of SGO/ZnO composite. The EDX analysis revealed the presence of carbon, zinc, and oxygen with no impurities. The successful incorporation of ZnO on SGO yielded a BET surface of 123 m2/g for SGO/ZnO, which is far greater than that of the separate SGO and ZnO with surface areas of 19 m2/g and 76 m2/g respectively. The batch studies revealed that the removal of fluoride ion by CGO, SGO, and SGO/ZnO was 89.4 %, 94.8 %, and 99.2 %. Also, the jovanovic isotherm model fitted well to the fluoride ion adsorption onto CGO, SGO, and SGO/ZnO suggesting a monolayer adsorption with mechanical contact possibility. The estimated adsorption capacities (Qmax) were 105.64, 116.37, and 188.60 mg/g for CGO, SGO, and SGO/ZnO, respectively. In addition, the adsorption kinetics study showed that the pseudo-second-order kinetic model suits the adsorption model, indicating the presence of an ionic interaction between the adsorbent functional groups and the fluoride ion. The adsorption thermodynamic analysis indicates that the adsorption process was spontaneous, endothermic, with strong affinity between the adsorbate and adsorbents. Furthermore, the regenerability and reusability analysis showed that about 39.5 %, 49.9 %, and 70.6 % of fluoride ion on CGO, SGO, and SGO/ZnO was removed after fifth desorption-adsorption cycles, suggesting that the SGO/ZnO was more stable. The interaction mechanism between SGO/ZnO and fluoride ion was governed primarily by pore-filling, hydrogen bonding, electrostatic attraction, and physical adsorption.
期刊介绍:
Nano-Structures & Nano-Objects is a new journal devoted to all aspects of the synthesis and the properties of this new flourishing domain. The journal is devoted to novel architectures at the nano-level with an emphasis on new synthesis and characterization methods. The journal is focused on the objects rather than on their applications. However, the research for new applications of original nano-structures & nano-objects in various fields such as nano-electronics, energy conversion, catalysis, drug delivery and nano-medicine is also welcome. The scope of Nano-Structures & Nano-Objects involves: -Metal and alloy nanoparticles with complex nanostructures such as shape control, core-shell and dumbells -Oxide nanoparticles and nanostructures, with complex oxide/metal, oxide/surface and oxide /organic interfaces -Inorganic semi-conducting nanoparticles (quantum dots) with an emphasis on new phases, structures, shapes and complexity -Nanostructures involving molecular inorganic species such as nanoparticles of coordination compounds, molecular magnets, spin transition nanoparticles etc. or organic nano-objects, in particular for molecular electronics -Nanostructured materials such as nano-MOFs and nano-zeolites -Hetero-junctions between molecules and nano-objects, between different nano-objects & nanostructures or between nano-objects & nanostructures and surfaces -Methods of characterization specific of the nano size or adapted for the nano size such as X-ray and neutron scattering, light scattering, NMR, Raman, Plasmonics, near field microscopies, various TEM and SEM techniques, magnetic studies, etc .