{"title":"原位重氮化苯胺与杂环烯的电化学 C-H 芳基化反应","authors":"Zhen-Xiang Liu, Hui Mao, Hang-Cheng Ni, Tai-Jin Chen","doi":"10.1016/j.mencom.2024.06.036","DOIUrl":null,"url":null,"abstract":"<div><p>A simple and efficient electrochemical C–H arylation of five- membered active heteroarenes involves the application of arenediazonium salts generated <em>in situ</em> from anilines and <em>tert</em>- butyl nitrite. A cathodic reduction-induced radical chain mechanism is proposed.</p></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":"34 4","pages":"Pages 579-580"},"PeriodicalIF":1.8000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrochemical C–H arylation of heteroarenes with in situ diazotizated anilines\",\"authors\":\"Zhen-Xiang Liu, Hui Mao, Hang-Cheng Ni, Tai-Jin Chen\",\"doi\":\"10.1016/j.mencom.2024.06.036\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A simple and efficient electrochemical C–H arylation of five- membered active heteroarenes involves the application of arenediazonium salts generated <em>in situ</em> from anilines and <em>tert</em>- butyl nitrite. A cathodic reduction-induced radical chain mechanism is proposed.</p></div>\",\"PeriodicalId\":18542,\"journal\":{\"name\":\"Mendeleev Communications\",\"volume\":\"34 4\",\"pages\":\"Pages 579-580\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Mendeleev Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S095994362400213X\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mendeleev Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S095994362400213X","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Electrochemical C–H arylation of heteroarenes with in situ diazotizated anilines
A simple and efficient electrochemical C–H arylation of five- membered active heteroarenes involves the application of arenediazonium salts generated in situ from anilines and tert- butyl nitrite. A cathodic reduction-induced radical chain mechanism is proposed.
期刊介绍：
Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications.
Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.
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