Matilda Johansson , Mikael Skrifvars , Nawar Kadi , Hom Nath Dhakal
{"title":"先进应用领域的木质素-聚乳酸生物聚合物混合物--抗冲改性剂的影响","authors":"Matilda Johansson , Mikael Skrifvars , Nawar Kadi , Hom Nath Dhakal","doi":"10.1016/j.jcomc.2024.100502","DOIUrl":null,"url":null,"abstract":"<div><p>In this study, lignin underwent chemical modification via acetylation of hydroxyl groups to enhance its interfacial connection with poly (lactic acid) (PLA). Further enhancement of the blend was attained by adding an impact modifier, Biomax Strong. Incorporating Biomax Strong into PLA-lignin blends resulted in improvements in material characteristics, particularly in impact strength and thermal stability. This blend exhibited a unique set of mechanical properties, characterized by a reduction in tensile modulus as well as an increase in ductility. This will allow a more versatile use of PLA in various applications. The observed improved impact strength highlights the synergistic effect of stress redistribution within the PLA matrix contributing to widespread applications of PLA based composites. This can clearly be observed for the compound containing PLA and 15 wt.% lignin, where the impact strength was approximately 15 kJ/m<sup>2</sup>. With the addition of 5 wt.% impact modifier, the impact strength increased by 60 %, reaching approximately 25 kJ/m<sup>2</sup>. This synergy effect reinforces the overall structure, improving the impact toughness behavior. The combination of Biomax Strong and lignin not only address the limitations of PLA but also introduces new opportunities for applications requiring a balance of impact strength, ductility, and thermal stability. These advancements indicate a promising future for composite materials in various applications.</p></div>","PeriodicalId":34525,"journal":{"name":"Composites Part C Open Access","volume":"14 ","pages":"Article 100502"},"PeriodicalIF":5.3000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666682024000719/pdfft?md5=f3be200077709b70d0ae4e5e4a92028e&pid=1-s2.0-S2666682024000719-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Lignin-polylactic acid biopolymer blends for advanced applications – Effect of impact modifier\",\"authors\":\"Matilda Johansson , Mikael Skrifvars , Nawar Kadi , Hom Nath Dhakal\",\"doi\":\"10.1016/j.jcomc.2024.100502\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this study, lignin underwent chemical modification via acetylation of hydroxyl groups to enhance its interfacial connection with poly (lactic acid) (PLA). Further enhancement of the blend was attained by adding an impact modifier, Biomax Strong. Incorporating Biomax Strong into PLA-lignin blends resulted in improvements in material characteristics, particularly in impact strength and thermal stability. This blend exhibited a unique set of mechanical properties, characterized by a reduction in tensile modulus as well as an increase in ductility. This will allow a more versatile use of PLA in various applications. The observed improved impact strength highlights the synergistic effect of stress redistribution within the PLA matrix contributing to widespread applications of PLA based composites. This can clearly be observed for the compound containing PLA and 15 wt.% lignin, where the impact strength was approximately 15 kJ/m<sup>2</sup>. With the addition of 5 wt.% impact modifier, the impact strength increased by 60 %, reaching approximately 25 kJ/m<sup>2</sup>. This synergy effect reinforces the overall structure, improving the impact toughness behavior. The combination of Biomax Strong and lignin not only address the limitations of PLA but also introduces new opportunities for applications requiring a balance of impact strength, ductility, and thermal stability. These advancements indicate a promising future for composite materials in various applications.</p></div>\",\"PeriodicalId\":34525,\"journal\":{\"name\":\"Composites Part C Open Access\",\"volume\":\"14 \",\"pages\":\"Article 100502\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2666682024000719/pdfft?md5=f3be200077709b70d0ae4e5e4a92028e&pid=1-s2.0-S2666682024000719-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Composites Part C Open Access\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666682024000719\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composites Part C Open Access","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666682024000719","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
Lignin-polylactic acid biopolymer blends for advanced applications – Effect of impact modifier
In this study, lignin underwent chemical modification via acetylation of hydroxyl groups to enhance its interfacial connection with poly (lactic acid) (PLA). Further enhancement of the blend was attained by adding an impact modifier, Biomax Strong. Incorporating Biomax Strong into PLA-lignin blends resulted in improvements in material characteristics, particularly in impact strength and thermal stability. This blend exhibited a unique set of mechanical properties, characterized by a reduction in tensile modulus as well as an increase in ductility. This will allow a more versatile use of PLA in various applications. The observed improved impact strength highlights the synergistic effect of stress redistribution within the PLA matrix contributing to widespread applications of PLA based composites. This can clearly be observed for the compound containing PLA and 15 wt.% lignin, where the impact strength was approximately 15 kJ/m2. With the addition of 5 wt.% impact modifier, the impact strength increased by 60 %, reaching approximately 25 kJ/m2. This synergy effect reinforces the overall structure, improving the impact toughness behavior. The combination of Biomax Strong and lignin not only address the limitations of PLA but also introduces new opportunities for applications requiring a balance of impact strength, ductility, and thermal stability. These advancements indicate a promising future for composite materials in various applications.