Al2O3 含量对聚醚酰亚胺薄膜电树发展的影响

IF 2.9 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC IEEE Transactions on Dielectrics and Electrical Insulation Pub Date : 2024-06-12 DOI:10.1109/TDEI.2024.3413046
Jiajian Yuan;Haiyan Chen;Hang Luo
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引用次数: 0

摘要

介电纳米复合材料因其快速充放电能力和高功率密度而被认为是最有前途的储能材料。为进一步提高储能性能,纳米电介质复合材料的预分解降解机制已成为当前的研究热点之一。本文采用 Weismann-Zeller (WZ) 模型模拟了添加一维 Al2O3 小板的聚醚酰亚胺(PEI)聚合物的电树传输路径和击穿损伤形态演变。同时,还使用 COMSOL Multiphysics 分析了电位移和电动势的分布。从模拟结果来看,随着 Al2O3 小板的不断添加,电树趋于分叉,电树的分形维数先增大后减小。适量的 Al2O3 微板能有效抑制电树的发展,延缓破坏速度,最终提高纳米复合材料的击穿强度。由于小板与聚合物基体之间存在较大的介电常数差,因此电势会集中在小板与聚合物基体之间的界面上。上述研究可为设计具有高击穿强度和高储能密度的介电纳米复合材料在电力电子器件中的应用提供指导。
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Influence of Al2O3 Contents on the Progression of Electrical Tree in Polyetherimide Films
Dielectric nanocomposites are considered to be the most promising energy storage material due to their fast charging and discharging capabilities and high-power density. Pre-breakdown degradation mechanisms for dielectric nanocomposites have become one of the current research hotspots to further improve the energy storage performance. Herein, the Weismann–Zeller (WZ) model is used to simulate the transmission path of the electric tree and the evolution of breakdown damage morphology for polyetherimide (PEI) polymers with the addition of 1-D Al2O3 platelets. Simultaneously, the distribution of electric displacement and electric potential is analyzed using COMSOL Multiphysics. From the simulation results, the electrical tree tends to be more bifurcated, the fractal dimension of the electric tree increases first and then decreases with the continuous addition of Al2O3 platelets. Appropriate quantities of Al2O3 platelets can effectively inhibit the progression of electric tree, delay the damage speed, and finally improve the breakdown strength of nanocomposites. An electric potential can be concentrated on the interface between platelets and polymer matrix due to their large permittivity difference. The above research can provide guidance for designing dielectric nanocomposites with high breakdown strength and high energy storage density in the application of power electronic devices.
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来源期刊
IEEE Transactions on Dielectrics and Electrical Insulation
IEEE Transactions on Dielectrics and Electrical Insulation 工程技术-工程:电子与电气
CiteScore
6.00
自引率
22.60%
发文量
309
审稿时长
5.2 months
期刊介绍: Topics that are concerned with dielectric phenomena and measurements, with development and characterization of gaseous, vacuum, liquid and solid electrical insulating materials and systems; and with utilization of these materials in circuits and systems under condition of use.
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