Risks of stannous chloride without filtration for hexavalent chromium treatment

With increasing interest in using stannous chloride without filtration to achieve hexavalent chromium maximum contaminant level compliance in California, there is new urgency to quantify its effects on water quality and risks to public health manifested in distribution and premise plumbing systems. Accordingly, a 12-week groundwater pilot study was completed using ubiquitous premise plumbing materials under flowing (to waste) and stagnating conditions of hexavalent chromium-containing groundwater following stannous chloride addition without filtration. Results quantified the accumulation and release of chromium and tin, with total chromium concentrations exceeding regulatory or acceptable levels under stagnating conditions. Sediment with elevated chromium, tin, arsenic, and manganese concentrations was also observed. Given these observations would likely occur and worsen over time in distribution systems that cumulatively serve large populations, the use of stannous chloride without filtration represents an unacceptable risk to public health compared to other, more well-established, best available technologies.