{"title":"碳化物和碳氮化物薄膜在生物模拟流体中的电化学和摩擦学行为","authors":"Aysenur Keles Dayauc","doi":"10.1016/j.ijrmhm.2024.106827","DOIUrl":null,"url":null,"abstract":"<div><p>Application of hard coatings such as nitride, carbide, and nitrocarbide improves corrosion and wear resistance. In this work, an RF magnetron sputtering was used to coat TaC films with various target power values. Furthermore, TaCN films were deposited using nitrogen gas at the same target power values using the RF magnetron sputtering. Investigations were conducted on the mechanical, electrochemical, and tribological impacts of the carbide and carbonitride phases. Ta<img>N and Ta<img>C bonds were detected, and X-ray photoelectron spectroscopy (XPS) was used to analyze the chemical composition and bonding arrangement. TaCN films showed greater wear rate (2.06 × 10<sup>−7</sup>*mm<sup>3</sup>/Nm), corrosion resistance (44.811 × 10<sup>−6</sup>, mm·yr-1) in Ringer solution, and a lower friction coefficient (0.236) compared with TaC films.</p></div>","PeriodicalId":14216,"journal":{"name":"International Journal of Refractory Metals & Hard Materials","volume":"124 ","pages":"Article 106827"},"PeriodicalIF":4.2000,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The electrochemical and tribological behavior of carbide and carbonitride films in bio-simulated fluid\",\"authors\":\"Aysenur Keles Dayauc\",\"doi\":\"10.1016/j.ijrmhm.2024.106827\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Application of hard coatings such as nitride, carbide, and nitrocarbide improves corrosion and wear resistance. In this work, an RF magnetron sputtering was used to coat TaC films with various target power values. Furthermore, TaCN films were deposited using nitrogen gas at the same target power values using the RF magnetron sputtering. Investigations were conducted on the mechanical, electrochemical, and tribological impacts of the carbide and carbonitride phases. Ta<img>N and Ta<img>C bonds were detected, and X-ray photoelectron spectroscopy (XPS) was used to analyze the chemical composition and bonding arrangement. TaCN films showed greater wear rate (2.06 × 10<sup>−7</sup>*mm<sup>3</sup>/Nm), corrosion resistance (44.811 × 10<sup>−6</sup>, mm·yr-1) in Ringer solution, and a lower friction coefficient (0.236) compared with TaC films.</p></div>\",\"PeriodicalId\":14216,\"journal\":{\"name\":\"International Journal of Refractory Metals & Hard Materials\",\"volume\":\"124 \",\"pages\":\"Article 106827\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2024-08-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Refractory Metals & Hard Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0263436824002750\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Refractory Metals & Hard Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0263436824002750","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
氮化物、碳化物和碳氮化物等硬质涂层的应用可提高耐腐蚀性和耐磨性。在这项工作中，使用了射频磁控溅射技术，以不同的目标功率值对 TaC 薄膜进行镀膜。此外，在使用射频磁控溅射的相同靶功率值下，使用氮气沉积了 TaCN 薄膜。对碳化物和碳氮化物相的机械、电化学和摩擦学影响进行了研究。检测了 TaN 和 TaC 键，并使用 X 射线光电子能谱（XPS）分析了化学成分和键合排列。与 TaC 薄膜相比，TaCN 薄膜的磨损率（2.06 × 10-7*mm3/Nm）更高，在林格溶液中的耐腐蚀性（44.811 × 10-6, mm-yr-1）更强，摩擦系数（0.236）更低。
The electrochemical and tribological behavior of carbide and carbonitride films in bio-simulated fluid
Application of hard coatings such as nitride, carbide, and nitrocarbide improves corrosion and wear resistance. In this work, an RF magnetron sputtering was used to coat TaC films with various target power values. Furthermore, TaCN films were deposited using nitrogen gas at the same target power values using the RF magnetron sputtering. Investigations were conducted on the mechanical, electrochemical, and tribological impacts of the carbide and carbonitride phases. TaN and TaC bonds were detected, and X-ray photoelectron spectroscopy (XPS) was used to analyze the chemical composition and bonding arrangement. TaCN films showed greater wear rate (2.06 × 10−7*mm3/Nm), corrosion resistance (44.811 × 10−6, mm·yr-1) in Ringer solution, and a lower friction coefficient (0.236) compared with TaC films.
期刊介绍：
The International Journal of Refractory Metals and Hard Materials (IJRMHM) publishes original research articles concerned with all aspects of refractory metals and hard materials. Refractory metals are defined as metals with melting points higher than 1800 °C. These are tungsten, molybdenum, chromium, tantalum, niobium, hafnium, and rhenium, as well as many compounds and alloys based thereupon. Hard materials that are included in the scope of this journal are defined as materials with hardness values higher than 1000 kg/mm2, primarily intended for applications as manufacturing tools or wear resistant components in mechanical systems. Thus they encompass carbides, nitrides and borides of metals, and related compounds. A special focus of this journal is put on the family of hardmetals, which is also known as cemented tungsten carbide, and cermets which are based on titanium carbide and carbonitrides with or without a metal binder. Ceramics and superhard materials including diamond and cubic boron nitride may also be accepted provided the subject material is presented as hard materials as defined above.
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