三维打印 MOF 单片：制造策略和环境应用。

IF 26.6 1区材料科学 Q1 Engineering Nano-Micro Letters Pub Date : 2024-08-15 DOI:10.1007/s40820-024-01487-1

Hossein Molavi, Kamyar Mirzaei, Mahdi Barjasteh, Seyed Yahya Rahnamaee, Somayeh Saeedi, Aliakbar Hassanpouryouzband, Mashallah Rezakazemi

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引用次数: 0

摘要

金属有机框架（MOFs）具有比表面积大、孔隙率高、结构和组成可定制、功能多样、孔隙/尺寸分布控制良好等特点，被广泛认为是最有前途的多孔和结晶有机无机材料之一。然而，大多数已开发的 MOFs 都是粉末状的，仍然存在一些技术难题，包括磨损、粉尘、堆积密度低、堵塞、传质/传热限制、环境污染以及堆积过程中的机械不稳定性等，限制了它们在工业应用中的适用性。因此，近年来，人们将注意力集中在将 MOF 粉末转化为珠子、膜、单片、凝胶/海绵和纳米纤维等宏观材料的技术上，以克服这些挑战。三维（3D）打印技术可以根据数字模型生产出许多具有复杂形状和几何结构的高分辨率宏观框架，因此备受关注。因此，本综述总结了不同三维打印策略与 MOFs 和 MOF 基材料的结合，用于制造三维打印 MOF 单体及其环境应用，重点是水处理和气体吸附/分离应用。本文结合相关实例，介绍了制造三维打印MOF单体的各种策略，如直接墨水写入、种子辅助原位生长、固体前驱体配位复制、基质掺入、选择性激光烧结和数字光处理等。最后，还介绍了三维打印 MOF 单体的未来发展方向和挑战，以便更好地规划未来 MOF 材料的成型轨迹，改进对三维打印 MOF 单体的结构、组成和纹理特性的控制。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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3D-Printed MOF Monoliths: Fabrication Strategies and Environmental Applications

Highlights

Challenges and future directions for 3D-printed metal-organic frameworks (MOFs) monoliths in environmental applications are discussed.
Various strategies for fabrication of 3D-printed MOF monoliths are summarized.
Advancements in 3D printing enable customizable and high-performance MOF monoliths.
3D orienting of MOFs opens avenues for applications in water treatment and gas adsorption.

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来源期刊

Nano-Micro Letters NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY

CiteScore

32.60

自引率

4.90%

发文量

981

审稿时长

1.1 months

期刊介绍： Nano-Micro Letters is a peer-reviewed, international, interdisciplinary, and open-access journal published under the SpringerOpen brand. Nano-Micro Letters focuses on the science, experiments, engineering, technologies, and applications of nano- or microscale structures and systems in various fields such as physics, chemistry, biology, material science, and pharmacy.It also explores the expanding interfaces between these fields. Nano-Micro Letters particularly emphasizes the bottom-up approach in the length scale from nano to micro. This approach is crucial for achieving industrial applications in nanotechnology, as it involves the assembly, modification, and control of nanostructures on a microscale.