优化芥酸提取物,作为液体安全粘度检测的天然探针

IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Arabian Journal of Chemistry Pub Date : 2024-08-07 DOI:10.1016/j.arabjc.2024.105954
Lingfeng Xu , Lili Zeng , Ting Ouyang , Xinmin Deng , Xinya Liu , Runlin Han
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引用次数: 0

摘要

作为参与液体变质过程的主要亚态,微环境黏度的异常与客观环境退化的发生和发展密切相关。因此,建立便捷的粘度监测检测方法具有重要意义。这项工作的重点是提取一种基于芥酸的分子探针(EAd),用于感知液体中的粘度波动。电子供体酚羟基和受体羧基通过巧合的途径在该分子结构中建立起来。形成了扭曲的分子内电荷转移(TICT),并利用可旋转的共轭结构作为识别位点。由于可旋转部分的限制,在高粘度微环境中可以发现更高的发射荧光信号。此外,EAd 还具有较大的斯托克斯位移(甘油中为 83.3 nm)、较窄的能带、较高的选择性(x = 0.56)、适应性强、灵敏度高、光稳定性好等特点,可以在复杂的液体体系中实现信号释放应用。此外,这种天然探针 EAd 还能以无创模式识别增稠效率,特别是通过分析信号强度来筛选粘度波动和区分变质样品。我们希望天然支架能为液体质量和安全检测提供新的参考。
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Optimized erucic acid-based extract as a natural probe for viscosity detection of liquid safety

As the main substate participating during the liquid metamorphism processes, the abnormal micro-environmental viscosity is closely associated with the occurrence and development of objective circumstance degradation. Thus, it is of great importance to establish the convenient detection method toward viscosity monitoring. This work is focused on extracting one kind of erucic acid-based molecular probe (EAd) for sensing viscosity fluctuations in liquids. The electron donor phenolic hydroxyl group and acceptor carboxyl have established in this molecular structure via a coincidental pathway. Twisted intramolecular charge transfer (TICT) was formed, and the rotatable conjugate structure was utilized as the recognition site. Due to the restriction of rotatable parts, higher emission fluorescent signal can be found in the high-viscosity micro-environment. And a large Stokes shift (83.3 nm in glycerol), narrower energy band, high selectivity (x = 0.56), adaptability, sensitivity, and good photo-stability, the applications of signal releasing in the complex liquid system can be achieved. Moreover, this natural probe EAd can identify the thickening efficiency in a non-invasively mode, in particular, viscosity fluctuations have been screened and spoiled samples can be distinguished by analyzing signal intensities. We hope that natural scaffold will provide a new reference toward liquid quality and safety inspection.

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来源期刊
Arabian Journal of Chemistry
Arabian Journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
10.80
自引率
3.30%
发文量
763
审稿时长
63 days
期刊介绍: The Arabian Journal of Chemistry is an English language, peer-reviewed scholarly publication in the area of chemistry. The Arabian Journal of Chemistry publishes original papers, reviews and short reports on, but not limited to: inorganic, physical, organic, analytical and biochemistry. The Arabian Journal of Chemistry is issued by the Arab Union of Chemists and is published by King Saud University together with the Saudi Chemical Society in collaboration with Elsevier and is edited by an international group of eminent researchers.
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